11-Methoxyschizogalan-14-one

CAS No.
2671-28-5
Chemical Name:
11-Methoxyschizogalan-14-one
Synonyms
Schizogalin;Schizogaline;11-Methoxyschizogalan-14-one;5H,13bH-13a,13c-Ethano-3H-indolo[3,2,1-de]pyrido[3,2,1-ij][1,5]naphthyridin-12(13H)-one, 6,6a-dihydro-9-methoxy-, (6aS,13aS,13bS,13cR)- (9CI)
CBNumber:
CB52373170
Molecular Formula:
C20H22N2O2
Molecular Weight:
322.4
MDL Number:
MOL File:
2671-28-5.mol

11-Methoxyschizogalan-14-one Properties

Melting point 156-7°C

11-Methoxyschizogalan-14-one Chemical Properties,Uses,Production

Description

The bark and roots of Schizozygia caffaeoidea (Boj.) Baill. yield a number of alkaloids which have been examined in detail by Renner and Kernweisz. This base yields colourless crystals from EtOH and has [α]25D + 28.8° (c 1.0, CHCI3). The ultraviolet spectrum in EtOH exhibits absorption maxima at 219, 255 and 295 mil with a shoulder at 300 mil. The structure is based primarily upon the NMR and mass spectral data.

References

Renner, Kernweisz., Experientia, 19,244 (1963)
Structure:
Renner., Lloydia, 27,406 (1964)

11-Methoxyschizogalan-14-one Preparation Products And Raw materials

Raw materials

Preparation Products

11-Methoxyschizogalan-14-one Schizogalin Schizogaline 5H,13bH-13a,13c-Ethano-3H-indolo[3,2,1-de]pyrido[3,2,1-ij][1,5]naphthyridin-12(13H)-one, 6,6a-dihydro-9-methoxy-, (6aS,13aS,13bS,13cR)- (9CI) 2671-28-5