methyl 3-bromo-4-methyl-5-nitropicolinate
- CAS No.
- 1150618-07-7
- Chemical Name:
- methyl 3-bromo-4-methyl-5-nitropicolinate
- Synonyms
- methyl 3-bromo-4-methyl-5-nitropicolinate;methyl3-bromo-4-methyl-5-nitropyridine-2-carboxylate;methyl 3-bromo-4-methyl-5-nitropicolinate ISO 9001:2015 REACH;3-Bromo-4-methyl-5-nitro-2-pyridinecarboxylic acid methyl ester;2-Pyridinecarboxylic acid, 3-bromo-4-methyl-5-nitro-, methyl ester
- CBNumber:
- CB52474727
- Molecular Formula:
- C8H7BrN2O4
- Molecular Weight:
- 275.06
- MDL Number:
- MFCD12031253
- MOL File:
- 1150618-07-7.mol
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
---|---|
Signal word | Warning |
Hazard statements | H302 |
Precautionary statements | P280-P305+P351+P338 |
methyl 3-bromo-4-methyl-5-nitropicolinate price More Price(4)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
American Custom Chemicals Corporation | HCH0036420 | METHYL 3-BROMO-4-METHYL-5-NITROPICOLINATE 95.00% | 1150618-07-7 | 5G | $909.56 | 2021-12-16 | Buy |
Alichem | 1150618077 | Methyl3-bromo-4-methyl-5-nitropicolinate | 1150618-07-7 | 5g | $998 | 2021-12-16 | Buy |
Chemenu | CM178410 | Methyl3-bromo-4-methyl-5-nitropicolinate 95% | 1150618-07-7 | 5g | $1457 | 2021-12-16 | Buy |
Chemenu | CM178410 | Methyl3-bromo-4-methyl-5-nitropicolinate 95% | 1150618-07-7 | 1g | $485 | 2021-12-16 | Buy |
methyl 3-bromo-4-methyl-5-nitropicolinate Chemical Properties,Uses,Production
Preparation
Methyl-3-bromo-4-methyl-5-nitropicolinate synthesis: 3-bromo-2-iodo-4-methyl-5-nitropyridine (129.0 g, 0.38 mol) and (Ph3P)2PdCl2 (7.92 g, 3 mol%) were suspended in CH3CN (1300 mL) and MeOH (430 mL) and Et3N (79.3 mL, 1.5 eq) was added. The mixture was transferred to a steel 5000 mL pressure vessel, 4 bar of CO pressure was applied and the reaction mixture was slowly heated to 80 oC. Subsequently, it was stirred for 5 h at this temperature, then allowed to cool overnight. The volatiles were removed in vacuo, the residue was stirred in EtOAc (1000 mL) and filtered. The residue was extracted with EtOAc (2*250 mL) and the combined filtrates were washed with brine (1000 mL) and dried on Na2SO4. The volatiles were removed in vacuo, affording 120 g of a brown oil. This was coated on 120 g of silicagel and purified by column chromatography (3500 g of silica gel, EtOAc/heptane 1:3, KMnO4 staining). The appropriate fractions were combined and concentrated to give Methyl-3-bromo-4-methyl-5-nitropicolinate as a beige solid (63.5 g, 61%).
methyl 3-bromo-4-methyl-5-nitropicolinate Preparation Products And Raw materials
Raw materials
Preparation Products
methyl 3-bromo-4-methyl-5-nitropicolinate Suppliers
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
career henan chemical co | +86-0371-86658258 15093356674; | factory@coreychem.com | China | 29826 | 58 |
ANHUI WITOP BIOTECH CO., LTD | +8615255079626 | eric@witopchemical.com | China | 23556 | 58 |
Dideu Industries Group Limited | +86-29-89586680 +86-15129568250 | 1026@dideu.com | China | 26925 | 58 |
Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | info@dycnchem.com | China | 52861 | 58 |
Labnetwork lnc. | +86-27-50766799 +8618062016861 | contact@labnetwork.com | China | 19994 | 58 |
PT CHEM GROUP LIMITED | +86-85511178 +86-85511178 | peter68@ptchemgroup.com | China | 35451 | 58 |
GIHI CHEMICALS CO.,LIMITED | +8618058761490 | info@gihichemicals.com | China | 50000 | 58 |
Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131980 | 58 |
Shanghai Boc Chemical Co.,Ltd | 021-34975603-808 18721111801 | sales@bocpharma.com | China | 995 | 64 |
View Lastest Price from methyl 3-bromo-4-methyl-5-nitropicolinate manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2021-09-24 | methyl 3-bromo-4-methyl-5-nitropicolinate
1150618-07-7
|
US $1.10 / g | 1g | 99.00% | 100 Tons min | Dideu Industries Group Limited | ||
2020-01-09 | methyl 3-bromo-4-methyl-5-nitropicolinate
1150618-07-7
|
US $1.00 / KG | 1KG | 95-99% | 1ton | Career Henan Chemical Co |
- methyl 3-bromo-4-methyl-5-nitropicolinate
1150618-07-7
- US $1.10 / g
- 99.00%
- Dideu Industries Group Limited
- methyl 3-bromo-4-methyl-5-nitropicolinate
1150618-07-7
- US $1.00 / KG
- 95-99%
- Career Henan Chemical Co