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1-Pyrrolidino-1-cyclohexene

1-Pyrrolidino-1-cyclohexene Structure
1-Pyrrolidino-1-cyclohexene structure
CAS No.
1125-99-1
Chemical Name:
1-Pyrrolidino-1-cyclohexene
Synonyms
1-Pyrrolizinocyclohexene;1-Pyrrolidinocyclohexene;1-cyclohexenylpyrrolidine;1-PYRROLIDINO-2-CYCLOHEXENE;1-PYRROLIDINO-1-CYCLOHEXENE;N-Pyrrolidino-1-cyclohexene;1-Pyrrolizino-1-cyclohexene;1-pyrrolidine-1-cyclohexene;1-(1-PYRROLIDINO)CYCLOHEXENE;1-Pyrrolidinyl-1-cyclohexene
CBNumber:
CB5258286
Molecular Formula:
C10H17N
Molecular Weight:
151.25
MDL Number:
MFCD00003163
MOL File:
1125-99-1.mol
MSDS File:
SDS
Last updated:2025-01-27 09:38:02
Request For Quotation

1-Pyrrolidino-1-cyclohexene Properties

Melting point 113 °C
Boiling point 114-115 °C/15 mmHg (lit.)
Density 0.94 g/mL at 25 °C (lit.)
refractive index n20/D 1.5217(lit.)
Flash point 103 °F
storage temp. 2-8°C
pka 8.91±0.20(Predicted)
form Liquid
color Clear light yellow
Sensitive Air Sensitive
BRN 114797
CAS DataBase Reference 1125-99-1(CAS DataBase Reference)
NIST Chemistry Reference Pyrrolidine, 1-(1-cyclohexen-1-yl)-(1125-99-1)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07
Signal word  Warning
Hazard statements  H226-H315-H319-H335
Precautionary statements  P210-P302+P352-P305+P351+P338
Hazard Codes  Xi,Xn
Risk Statements  10-36/37/38-20/21/22
Safety Statements  16-26-36/37/39
RIDADR  UN 1993 3/PG 3
WGK Germany  3
HazardClass  3
PackingGroup  III
HS Code  29339980
NFPA 704
2
2 0

1-Pyrrolidino-1-cyclohexene price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich P74001 1-Pyrrolidino-1-cyclohexene 97% 1125-99-1 25g $187.2 2024-03-01 Buy
TCI Chemical P1020 1-Pyrrolidino-1-cyclohexene >97.0%(GC)(T) 1125-99-1 25mL $104 2024-03-01 Buy
Alfa Aesar B25622 1-(1-Cyclohexen-1-yl)pyrrolidine 97% 1125-99-1 5g $27.65 2024-03-01 Buy
Alfa Aesar B25622 1-(1-Cyclohexen-1-yl)pyrrolidine 97% 1125-99-1 25g $103.65 2024-03-01 Buy
Alfa Aesar B25622 1-(1-Cyclohexen-1-yl)pyrrolidine 97% 1125-99-1 100g $347.65 2024-03-01 Buy
Product number Packaging Price Buy
P74001 25g $187.2 Buy
P1020 25mL $104 Buy
B25622 5g $27.65 Buy
B25622 25g $103.65 Buy
B25622 100g $347.65 Buy

1-Pyrrolidino-1-cyclohexene Chemical Properties,Uses,Production

Chemical Properties

clear light yellow liquid

Uses

1-Pyrrolidino-1-cyclohexene is a cyclic enamine that is used as an electron-rich dienophile in synthetic reactions.

Synthesis Reference(s)

Chemical and Pharmaceutical Bulletin, 16, p. 1466, 1968 DOI: 10.1248/cpb.16.1466

Reactivity Profile

The enamine nitrogen and its β-carbon atom are nucleophilic, undergoing substitution or conjugate addition; they can take part in 1,2- or 1,4-cycloadditions; iminium salts act as electrophiles.

Synthesis

The most commonly used preparation method for these enamines is the acid-catalyzed condensation of a secondary amine with cyclohexanone. An example is the reaction of Pyrrolidine with cyclohexanone (eq 1). Using a preformed Titanium(IV) Chloride-amine complex with cyclohexanone greatly decreases the reaction time while maintaining high yields. This technique is also effective with functionalized cyclohexanones. When unsymmetrical tin(II) amides are allowed to react with cyclohexanone, good yields of enamines result.
1-Pyrrolidino-1-cyclohexene

Precautions

Readily reacts with water or atmospheric oxygen; should be stored under dry nitrogen.

1-Pyrrolidino-1-cyclohexene Preparation Products And Raw materials

Raw materials

2,2-DIMETHYL-1,3-DIOXAN-5-ONE Cyclohexanone

Preparation Products

ETHYL 3-METHYL-4,5,6,7-TETRAHYDRO-1H-INDOLE-2-CARBOXYLATE 4,5,6,7-TETRAHYDRO-1H-INDAZOLE-3-CARBOXYLIC ACID ETHYL ESTER 2-Allylcyclohexanone Cyclohexanone, 2-(2-propyn-1-yl)- 3-[1-[(2-methoxyphenyl)methyl]-2-oxo-cyclohexyl]propanoic acid
2-(2,4-DINITROPHENYL)CYCLOHEXANONE Ethanone, 1-[5,6,7,8-tetrahydro-1-(methylthio)-3-isoquinolinyl]- 2-(2-OXO-2-PHENYL-ETHYL)-CYCLOHEXANONE Pelubiprofen Impurity

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1-Pyrrolidino-1-cyclohexene Suppliers

Global( 129)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Fengda Chemical Co., Ltd 		+86-371-86557731 +86-13613820652 info@fdachem.com China 20267 58
Hubei Jusheng Technology Co.,Ltd. 		18871490254 linda@hubeijusheng.com CHINA 28172 58
CONIER CHEM AND PHARMA LIMITED 		+8618523575427 sales@conier.com China 49374 58
Career Henan Chemica Co 		+86-0371-86658258 +8613203830695 laboratory@coreychem.com China 30236 58
Hefei TNJ Chemical Industry Co.,Ltd. 		+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34563 58
Shaanxi Dideu Medichem Co. Ltd 		+86-029-89586680 +86-18192503167 1026@dideu.com China 7724 58
Dayang Chem (Hangzhou) Co.,Ltd. 		571-88938639 +8617705817739 info@dycnchem.com China 52849 58
GLR Innovations 		+91 9891111994 info@glrgroup.in India 4535 58
Hebei Weibang Biotechnology Co., Ltd 		+8617732866630 bess@weibangbio.com China 18148 58
PT CHEM GROUP LIMITED 		+86-85511178; +86-85511178; peter68@ptchemgroup.com China 35425 58
Supplier Advantage
Henan Fengda Chemical Co., Ltd 		58
Hubei Jusheng Technology Co.,Ltd. 		58
CONIER CHEM AND PHARMA LIMITED 		58
Career Henan Chemica Co 		58
Hefei TNJ Chemical Industry Co.,Ltd. 		58
Shaanxi Dideu Medichem Co. Ltd 		58
Dayang Chem (Hangzhou) Co.,Ltd. 		58
GLR Innovations 		58
Hebei Weibang Biotechnology Co., Ltd 		58
PT CHEM GROUP LIMITED 		58

View Lastest Price from 1-Pyrrolidino-1-cyclohexene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1-Pyrrolidino-1-cyclohexene pictures 2023-12-26 1-Pyrrolidino-1-cyclohexene
1125-99-1
 US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
1-Pyrrolidino-1-cyclohexene pictures 2022-10-10 1-Pyrrolidino-1-cyclohexene
1125-99-1
 US $0.00-0.00 / KG 1KG 98% 1ton Henan Aochuang Chemical Co.,Ltd.

1-Pyrrolidino-1-cyclohexene Spectrum

1-Pyrrolidino-1-cyclohexene(1125-99-1)MS1-Pyrrolidino-1-cyclohexene(1125-99-1)1HNMR1-Pyrrolidino-1-cyclohexene(1125-99-1)IR11-Pyrrolidino-1-cyclohexene(1125-99-1)Raman

1125-99-1(1-Pyrrolidino-1-cyclohexene)Related Search:

Pyrrolidine Povidone iodine N-Methyl-2-pyrrolidone Polyvinylpyrrolidone N-Vinyl-2-pyrrolidone
Cyclohexene 1-Methylpyrrolidine Triethylamine N,N-DIETHYLBUTYLAMINE 1-Butylpyrrolidine
N,N-DIMETHYLHEXYLAMINE N-METHYLHEXYLAMINE N,N-Dimethylaminobutane N-Methyldipropylamine Dipropylamine
4-(2-Pyridinyl)benzaldehyde Dibutylamine N-ETHYLPYRROLIDINE

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Cyclohexanone pyrrolidine enamine N-(1-Cyclohexenyl)pyrrolidine N-Pyrrolidino-1-cyclohexene N-(1-CYCLOHEXEN-1-YL)-PYRROLIDIN N-(1-CYCLOHEXEN-1-YL)PYRROLIDINE 1-PYRROLIDINO-1-CYCLOHEXENE 1-PYRROLIDINO-2-CYCLOHEXENE 1-(1-PYRROLIDINO)CYCLOHEXENE 1-(1-CYCLOHEXEN-1-YL)PYRROLIDINE 1-(CYCLOHEXEN-1-YL)PYRROLIDINE N-(cyclohex-1-en-1-yl)pyrrolidine 1-(1-PYRROLIDINO)CYCLOHEXENE 97% n-(cyclohexen-1-yl)pyrrolidine 1-Cyclohex-1-en-1-ylpyrrolidine 1-cyclohexenylpyrrolidine 1-(1-Pyrrolidyl)-1-cyclohexene 1-Pyrrolizino-1-cyclohexene 1-Pyrrolizinocyclohexene 1-(Pyrrolidino)-1-cyclohexene,97% 1-Pyrrolidino-1-cyclohexene,95% 1-Pyrrolidino-1-cyclohexene 97% 1-(1-Cyclohexenyl)pyrrolidine 1-(1-Pyrrolidino)-1-cyclohexene 1-(1-Pyrrolidinyl)cyclohexene 1-Pyrrolidinocyclohexene 1-Pyrrolidinyl-1-cyclohexene 1-Pyrrolidino-1-cyclohexene> 1-pyrrolidine-1-cyclohexene Pyrrolidine, 1-(1-cyclohexen-1-yl)- 1-Pyrrolidino-1-cyclohexene ISO 9001：2015 REACH 1125-99-1 Building Blocks Pyrrolidines Heterocyclic Building Blocks API intermediates Miscellaneous