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Methyl 2-methylbutyrate

CAS No.
868-57-5
Chemical Name:
Methyl 2-methylbutyrate
Synonyms
METHYL-2-METHYLBUTANOATE;METHYL-2-METHYL BUTYRATE, NATURAL;2-METHYLBUTYRIC ACID METHYL ESTER;2-Methylbutanoic acid methyl ester;FEMA 2719;METHYLFRAGOLAN;Methyl 2-Methyl Buty;Methyl-2-methylbutyrat;METHYL 2-METHYLBUTYRATE;2-Methylbutyrate Methyl
CBNumber:
CB5265440
Molecular Formula:
C6H12O2
Molecular Weight:
116.16
MDL Number:
MFCD00009335
MOL File:
868-57-5.mol
MSDS File:
SDS
Last updated:2024-05-20 14:01:34

Methyl 2-methylbutyrate Properties

Melting point -91°C (estimate)
Boiling point 115 °C (lit.)
Density 0.88 g/mL at 25 °C (lit.)
FEMA 2719 | METHYL 2-METHYLBUTYRATE
refractive index n20/D 1.393(lit.)
Flash point 90 °F
storage temp. Sealed in dry,Room Temperature
solubility Very slightly soluble in water, soluble in alcohol and oils.
form Liquid
color Colorless to Almost colorless
Odor at 10.00 % in dipropylene glycol. ethereal estery fruity tutti frutti green apple lily of the valley powdery fatty
Odor Type fruity
JECFA Number 205
BRN 1720409
LogP 1.59
CAS DataBase Reference 868-57-5(CAS DataBase Reference)
Substances Added to Food (formerly EAFUS) METHYL 2-METHYLBUTYRATE
FDA 21 CFR 172.515
FDA UNII OLG4D4939V
NIST Chemistry Reference Butanoic acid, 2-methyl-, methyl ester(868-57-5)
EPA Substance Registry System Butanoic acid, 2-methyl-, methyl ester (868-57-5)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS02
Signal word  Warning
Hazard statements  H226
Precautionary statements  P210-P233-P240-P241-P242-P243
Risk Statements  10-11
Safety Statements  16-23-33-29-7/9
RIDADR  UN 3272 3/PG 3
WGK Germany  2
TSCA  Yes
HazardClass  3
PackingGroup  II
HS Code  29159000
NFPA 704
3
2 0

Methyl 2-methylbutyrate price More Price(24)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich W271926 Methyl 2-methylbutyrate natural, ≥98%, FCC, FG 868-57-5 100g $87.7 2024-03-01 Buy
Sigma-Aldrich W271926 Methyl 2-methylbutyrate natural, ≥98%, FCC, FG 868-57-5 1kg $441 2024-03-01 Buy
Sigma-Aldrich W271926 Methyl 2-methylbutyrate natural, ≥98%, FCC, FG 868-57-5 4kg $1360 2024-03-01 Buy
Sigma-Aldrich W271918 Methyl 2-methylbutyrate ≥98%, FCC, FG 868-57-5 100g $68.9 2024-03-01 Buy
Sigma-Aldrich W271918 Methyl 2-methylbutyrate ≥98%, FCC, FG 868-57-5 1kg $97 2024-03-01 Buy
Product number Packaging Price Buy
W271926 100g $87.7 Buy
W271926 1kg $441 Buy
W271926 4kg $1360 Buy
W271918 100g $68.9 Buy
W271918 1kg $97 Buy

Methyl 2-methylbutyrate Chemical Properties,Uses,Production

Description

Methyl 2-methylbutyrate has a pungent, fruity odor with a sweet, fruity, apple-like taste at low levels. May be prepared from a mixture of esters including methyl 2-methylbutyrate; is obtained from isobutene, CO, and methanol under pressure, or from butene, CO, and an acid catalyst under pressure.

Chemical Properties

Methyl-2-methylbutyrate has a sweet, fruity, apple-like odor and an apple-like taste at low concentrations.

Occurrence

The levorotatory and the racemic forms are known. Reported found in fresh strawberry juice, apple, apricot, sour cherry, melon, pineapple, peas, baked potato, peppermint oil, spearmint oil, thymus, durian (Durio zibethinus), olive, mushroom, starfruit, prickly pear, dill herb, cashew apple, cherimoya, loquat, mountain papaya, cape gooseberry and rooibus tea (Aspalathus linearis). bilberry, strawberry, and cheeses

Uses

DL-2-Methylbutyric Acid Methyl Ester is a volatile compound found in pineapples.
Methyl 2-methylbutyrate, only recerqly appearing on the market, finds limited use in perfumery and flavor compositions in the tedious work of reconstructing certain essential oils, mainly flavor oils. Its tremendous volatility and "lift" combined with effect of fresh greenness on a fruity base may give very attractive and natural aroma to the important topnotes of edible essential oils. It is also used as a trace component of various fruit flavors. Concentration varies from 5 to 10 ppm in the finished product.

Definition

ChEBI: Methyl (S)-2-Methylbutanoate is a fatty acid ester.

Preparation

A mixture of esters including methyl-2-methylbutyrate is obtained from isobutene, CO and methanol under pressure, or from butene, CO and an acid catalyst under pressure.

Aroma threshold values

Detection: 0.92 to 4.4 ppb

Taste threshold values

Taste characteristics at 7.5 ppm: sweet, berry, pineapple, etherial, lifting, fruity, tutti-fruitti and ripe with a fatty, green nuance

General Description

Methyl 2-methylbutyrate is an important odor-active constituent of pineapple, apple, cantaloupe, cucumber and strawberries.

17094-21-2
868-57-5
Synthesis of Methyl 2-methylbutyrate from methyl 2-methylacetoacetate

Methyl 2-methylbutyrate Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 253)Suppliers
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Hebei Zhuanglai Chemical Trading Co.,Ltd
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Career Henan Chemica Co
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View Lastest Price from Methyl 2-methylbutyrate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Methyl 2-methylbutyrate pictures 2024-11-22 Methyl 2-methylbutyrate
868-57-5
US $78.00-35.00 / kg 1kg 99% 20ton Hebei Zhuanglai Chemical Trading Co.,Ltd
Methyl 2-methylbutyrate pictures 2024-11-21 Methyl 2-methylbutyrate
868-57-5
US $0.00 / KG 25KG 99%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
Methyl 2-methylbutyrate 868-57-5 pictures 2023-02-27 Methyl 2-methylbutyrate 868-57-5
868-57-5
US $20.00 / Kg/Drum 1g 99.6% 20000 Hebei Aicrowe Biotech Co., Ltd
Butanoicacid,2-methyl-,methylester Butyric acid, 2-methyl-, methyl ester Methyl alpha-methylbutanoate Methyl alpha-methylbutyrate Methyl ester of 2-methyl-butanoic acid METHYL METHYLETHYLACETATE METHYL DL-2-METHYLBUTYRATE METHYL 2-METHYLBUTYRATE DL-METHYLBUTYRIC ACID METHYL ESTER DL-2-METHYLBUTYRIC ACID METHYL ESTER FEMA 2719 METHYL 2-METHYLBUTYRATE 98+% FCC METHYL 2-METHYLBUTYRATE 98+% NATURAL & Methyl2-methylbutyrate,98% methylmethylbutyrate,methyl2-methylbutanoate Methyl-2-methylbutyrat Methyl DL-2-Methylbutyrate METHYLFRAGOLAN 2-Methylbutyrate Methyl Methyl 2-methyl butyrate >=99.0% Methyl isovalerate ISO >=99.0% 2-methyl(methyl butanoate) 2-methyl-butanoicacimethylester Methyl 2-methylbutyrate 868-57-5 Natural D-Methyl 2-Methylbutyrate Natural Methyl 2-Methylbutyrate Methyl 2-Methyl Buty Active methyl 2-methylbutyrate Methyl 2-methylbutyrate(kosher) Methyl 2-methylbutyrate USP/EP/BP MethylDL-2-Methylbutyrate> D-Methyl 2-Methylbutyrate METHYL-2-METHYL BUTYRATE, NATURAL 2-Methylbutanoic acid methyl ester METHYL-2-METHYLBUTANOATE 2-METHYLBUTYRIC ACID METHYL ESTER 868-57-5 CH3CH2CHCH3COOCH3 Building Blocks Carbonyl Compounds C6 to C7 Organic Building Blocks Esters Flavors and Fragrances M-N Organics C6 to C7 Carbonyl Compounds Esters Certified Natural ProductsFlavors and Fragrances Alphabetical Listings