ChemicalBook >> CAS DataBase List >>[(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-η-2-propenylIr(III)

[(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-η-2-propenylIr(III)

[(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-η-2-propenylIr(III) structure

CAS No.: 1208092-27-6

Chemical Name:: [(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-η-2-propenylIr(III)

Synonyms: [(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-η-2-propenylIr(III);(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-n-2-propenyl]iridium(III);[(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-n-2-propenyl]iridium(III);[(R)-(+)-5,5''-Bis(diphenylphosphino)-4,4''-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-n-2-propenyl]iridium(III);[(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-η-2-propenylIr(III), Min. 98%;[(R)-(+)-5,5'-BIS(DIPHENYLPHOSPHINO)-4,4'-BI-1,3-BENZODIOXOLE][4-CYANO-3-NITROBENZENECARBOXYLATO][1,2,3-N-2-PROPENYL]IRIDIUM(III),MIN.97%;[(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-n-2-propenyl]iridium(III), min. 97%

CBNumber:: CB52709162

Molecular Formula:: C49H36IrN2O8P23*-

Molecular Weight:: 1034.983262

MDL Number:: MFCD20922908

MOL File:: 1208092-27-6.mol

Last updated:2023-05-04 15:16:52

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[(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-η-2-propenylIr(III) Properties

form	Powder
color	yellow

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H315-H319-H335
Precautionary statements	P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P

[(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-η-2-propenylIr(III) price More Price(2)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Strem Chemicals	77-5074	[(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-n-2-propenyl]iridium(III), min. 97%	1208092-27-6	100mg	$86	2024-03-01	Buy
Strem Chemicals	77-5074	[(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-n-2-propenyl]iridium(III), min. 97%	1208092-27-6	500mg	$344	2024-03-01	Buy

Product number	Packaging	Price	Buy
77-5074	100mg	$86	Buy
77-5074	500mg	$344	Buy

[(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-η-2-propenylIr(III) Chemical Properties,Uses,Production

Reactions

Catalyst used for the diastereo- and enantioselective carbonyl (trimethylsilyl)allylation from the alcohol, or aldehyde, oxidation level.
Catalyst used for the diastereo- and enantioselective carbonyl (hydroxy)allylation to form anti-1,2-diols.
Catalyst used for the diastereo- and enantioselective carbonyl (hydroxymethyl)allylation from the alcohol, or aldehyde, oxidation level.
Catalyst used for the diastereo- and enantioselective carbonyl tert-prenylation from the alcohol, or aldehyde, oxidation level.
Catalyst used for the diastereo- and enantioselective carbonyl double crotylation of 1,3-diols.
Catalyst used for the diastereo- and enantioselective carbonyl crotylation from the alcohol or aldehyde oxidation level

[(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-η-2-propenylIr(III) Preparation Products And Raw materials

Raw materials

Preparation Products

[(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-η-2-propenylIr(III) Suppliers

Global( 9)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Aladdin Scientific	+1-+1(833)-552-7181	sales@aladdinsci.com	United States	52927	58
J & K SCIENTIFIC LTD.	010-82848833 400-666-7788	jkinfo@jkchemical.com	China	96815	76
Alfa Chemistry	1-516-6625404	support@alfa-chemistry.com	United States	9171	60
Aikon International Limited	025-66113011 18112977050	cb6@aikonchem.com	China	15495	58
Shenzhen Polymeri Biochemical Technology Co., Ltd.	+86-400-002-6226 13028896684	sales@rrkchem.com	China	56070	58
Beijing Jin Ming Biotechnology Co., Ltd.	010-60605840 15801484223;	psaitong@jm-bio.com	China	29778	58
Shanghai Haohong Scientific Co., Ltd.	400-400-8210725	malulu@leyan.com	China	39990	58

Supplier	Advantage
Aladdin Scientific	58
J & K SCIENTIFIC LTD.	76
Alfa Chemistry	60
Aikon International Limited	58
Shenzhen Polymeri Biochemical Technology Co., Ltd.	58
Beijing Jin Ming Biotechnology Co., Ltd.	58
Shanghai Haohong Scientific Co., Ltd.	58

[(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-η-2-propenylIr(III), Min. 98% [(R)-(+)-5,5'-BIS(DIPHENYLPHOSPHINO)-4,4'-BI-1,3-BENZODIOXOLE][4-CYANO-3-NITROBENZENECARBOXYLATO][1,2,3-N-2-PROPENYL]IRIDIUM(III),MIN.97% [(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-n-2-propenyl]iridium(III), min. 97% [(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-η-2-propenylIr(III) [(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-n-2-propenyl]iridium(III) [(R)-(+)-5,5''-Bis(diphenylphosphino)-4,4''-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-n-2-propenyl]iridium(III) (R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato][1,2,3-n-2-propenyl]iridium(III) 1208092-27-6 C49H35IrN2O8P2