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Methyl 4-methoxyacetoacetate

Methyl 4-methoxyacetoacetate Structure
Methyl 4-methoxyacetoacetate structure
CAS No.
41051-15-4
Chemical Name:
Methyl 4-methoxyacetoacetate
Synonyms
4-Methoxyacetoacetate;Methyl4-methoxyacetate;Methyl 4-methoxy-3-oxobu;Methyl methoxyacetoacetate;Methyl 4-Methoxyacetoacetat;Dolutegravir Intermediates2;METHYL 4-METHOXYACETOACETATE;Methyl 3-oxo-4-methoxybutyrate;METHYL 4-METHOXYACETOXYACETATE;methyl 4-methoxy-3-oxobutyrate
CBNumber:
CB5291234
Molecular Formula:
C6H10O4
Molecular Weight:
146.14
MDL Number:
MFCD00010183
MOL File:
41051-15-4.mol
MSDS File:
SDS
Last updated:2025-04-01 17:57:16
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Methyl 4-methoxyacetoacetate Properties

Melting point -80℃
Boiling point 89 °C/8.5 mmHg (lit.)
Density 1.129 g/mL at 25 °C (lit.)
refractive index n20/D 1.431(lit.)
Flash point 193 °F
storage temp. Sealed in dry,Room Temperature
pka 9.88±0.46(Predicted)
form clear liquid
color Colorless to Light yellow to Light orange
Specific Gravity 1.129
BRN 1761215
InChIKey QGBPKJFJAVDUNC-UHFFFAOYSA-N
LogP 0.340 (est)
CAS DataBase Reference 41051-15-4(CAS DataBase Reference)
NIST Chemistry Reference Methyl 4-methoxyacetoacetate(41051-15-4)
EPA Substance Registry System Methyl 4-methoxyacetoacetate (41051-15-4)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
F  10
HS Code  29189900
NFPA 704
2
0 0

Methyl 4-methoxyacetoacetate price More Price(30)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 281506 Methyl 4-methoxyacetoacetate 97% 41051-15-4 5g $58.56 2024-03-01 Buy
Sigma-Aldrich 281506 Methyl 4-methoxyacetoacetate 97% 41051-15-4 25g $201 2024-03-01 Buy
TCI Chemical M1031 Methyl 4-Methoxyacetoacetate >97.0%(GC) 41051-15-4 5g $50 2024-03-01 Buy
TCI Chemical M1031 Methyl 4-Methoxyacetoacetate >97.0%(GC) 41051-15-4 25g $139 2024-03-01 Buy
TRC M320845 Methyl 4-Methoxyacetoacetate 41051-15-4 10g $165 2021-12-16 Buy
Product number Packaging Price Buy
281506 5g $58.56 Buy
281506 25g $201 Buy
M1031 5g $50 Buy
M1031 25g $139 Buy
M320845 10g $165 Buy

Methyl 4-methoxyacetoacetate Chemical Properties,Uses,Production

Chemical Properties

colorless to yellow liquid

Uses

Methyl 4-methoxyacetoacetate has been used in generation of a small focused library of diversely functionalized dihydropyrimidine derivatives via one-pot three-component Biginelli cyclocondensation of β-ketoesters, aldehydes and (thio)ureas.

Uses

Methyl 4-Methoxyacetoacetate is a reactant in the formation of an abiotic poorphyrinogen in aqueous solution.

Preparation

The preparation method of a 4-methoxyl group methyl acetoacetate: add solvents tetrahydrofurane in a kettle. and pass into rare gas element, the temperature in the kettle arranging reactor is 15-25℃, industrial sodium hydride and metal alkaline compound is added under whipped state, add solvents tetrahydrofurane again, the mixed solution reaction 4-6h of methyl alcohol and 4-chloro methyl acetoacetate is dripped in less than 20℃, then be warming up to 20-25℃ and continue reaction 4-15h, TLC detection reaction is complete, reduce system temperature to 6-10℃, add the hydrochloric acid soln regulation system pH=5-7 that volumetric molar concentration is 2mol/L, stratification, after separatory, upper strata is concentrated is spin-dried for removing solvents tetrahydrofurane, then colorless product 4-methoxyl group methyl acetoacetate is obtained by wiped film molecular distillation.

Methyl 4-methoxyacetoacetate synthesis

67-56-1
32807-28-6
41051-15-4
Synthesis of Methyl 4-methoxyacetoacetate from Methanol and Methyl 4-chloro-3-oxo-butanoate

Methyl 4-methoxyacetoacetate Preparation Products And Raw materials

Raw materials

Butanoic acid, 2,4-dimethoxy-3-oxo-, methyl ester Butanoic acid, 3-hydroxy-4-methoxy-, methyl ester Butanoic acid, 4-methoxy-3-oxo- Ethanone, 1-(1H-imidazol-1-yl)-2-methoxy- methyl 4-bromo-3-oxo-butanoate
Methyl 4-chloro-3-oxo-butanoate

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Preparation Products

4(1H)-Pyrimidinone, 6-(methoxymethyl)- (9CI) 5-Thiazolecarboxylicacid,2-amino-4-(methoxymethyl)-,methylester(9CI) 2-Dimethylaminomethylene-4-methoxy-3-oxo-butyric acid methyl ester

Methyl 4-methoxyacetoacetate Suppliers

Global( 364)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mujin Biotechnology Co.,Ltd 		+86 13288715578 +8613288715578 sales@hbmojin.com China 12806 58
Hebei Yanxi Chemical Co., Ltd. 		+8617531153977 allison@yan-xi.com China 5854 58
Hebei Chuanghai Biotechnology Co,.LTD 		+86-13131129325 sales1@chuanghaibio.com China 5868 58
Shaanxi Didu New Materials Co. Ltd 		+86-89586680 +86-13289823923 1026@dideu.com China 8804 58
Hebei Chuanghai Biotechnology Co., Ltd 		+8615531151365 mina@chuanghaibio.com China 18137 58
Hangzhou ICH Biofarm Co., Ltd 		+86-0571-28186870; +undefined8613073685410 sales@ichemie.com China 1015 58
Anhui Ruihan Technology Co., Ltd 		+8617756083858 daisy@anhuiruihan.com China 973 58
Hebei Junhua Import and Export Co., LTD 		+86-18503288844 +86-18503288844 junhua1@hb-junhua.com China 978 58
Capot Chemical Co.,Ltd. 		+86-（0）57185586718 +86-13336195806 sales@capot.com China 29730 60
Shanghai Daken Advanced Materials Co.,Ltd 		+86-371-+86-371-66670886 info@dakenam.com China 19841 58
Supplier Advantage
Hebei Mujin Biotechnology Co.,Ltd 		58
Hebei Yanxi Chemical Co., Ltd. 		58
Hebei Chuanghai Biotechnology Co,.LTD 		58
Shaanxi Didu New Materials Co. Ltd 		58
Hebei Chuanghai Biotechnology Co., Ltd 		58
Hangzhou ICH Biofarm Co., Ltd 		58
Anhui Ruihan Technology Co., Ltd 		58
Hebei Junhua Import and Export Co., LTD 		58
Capot Chemical Co.,Ltd. 		60
Shanghai Daken Advanced Materials Co.,Ltd 		58

Related articles

View Lastest Price from Methyl 4-methoxyacetoacetate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Methyl 4-methoxyacetoacetate pictures 2025-04-29 Methyl 4-methoxyacetoacetate
41051-15-4
 US $0.00-0.00 / kg 1kg 99% 1000 Hebei Junhua Import and Export Co., LTD
Methyl 4-methoxyacetoacetate pictures 2025-04-15 Methyl 4-methoxyacetoacetate
41051-15-4
 US $0.00 / KG 1KG 99% 500000kg Hebei Chuanghai Biotechnology Co., Ltd
Methyl 4-methoxyacetoacetate pictures 2025-04-04 Methyl 4-methoxyacetoacetate
41051-15-4
 US $0.00-0.00 / KG 1KG 98% 1ton Henan Aochuang Chemical Co.,Ltd.

Methyl 4-methoxyacetoacetate Spectrum

Methyl 4-methoxyacetoacetate(41051-15-4)MSMethyl 4-methoxyacetoacetate(41051-15-4)1HNMRMethyl 4-methoxyacetoacetate(41051-15-4)13CNMRMethyl 4-methoxyacetoacetate(41051-15-4)IR1Methyl 4-methoxyacetoacetate(41051-15-4)Raman

41051-15-4(Methyl 4-methoxyacetoacetate)Related Search:

Methyl acetoacetate Methyl methoxyacetate tert-Butyl acetoacetate Methylparaben Acetoxyacetic acid
3beta-Hydroxy-5-cholestene 3-butyrate Methyl 4-chloro-3-oxo-butanoate Kresoxim-methyl Methyl acetate Ethyl 4,4,4-trifluoroacetoacetate
Ethyl acetoacetate Methyl levulinate METSULFURON METHYL Bensulfuron methyl Methyl acrylate
Thiophanate-methyl Methyl Parathion-methyl

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4-methoxy-3-oxo-butanoicacimethylester Butanoic acid, 4-methoxy-3-oxo-, methyl ester Methyl methoxyacetoacetate 4-METHOXYACETOACETIC ACID METHYL ESTER METHYL 4-METHOXYACETOACETATE METHYL 4-METHOXYACETOXYACETATE METHYL 4-METHOXY-3-OXO-BUTANOATE 3-Oxo-4-methoxybutanoic acid methyl ester 3-Oxo-4-methoxybutyric acid methyl ester Methyl 3-oxo-4-methoxybutyrate Methyl 4-methoxyacetoacetate,98% Methyl4-methoxy-acetoacetate,97% Methyl 4-Methoxyacetoacetate, 98% 10ML 4-METHOXYACETOACETIC ACID METHYL ESTER 97+% methyl 4-methoxy-3-oxobutyrate 4-methoxy-3-oxo-butanoic acid methyl ester 4-Methoxyacetoacetate Methyl 4-methoxy-3-oxobutanoate, Methyl 4-methoxy-3-oxobutyrate M4MAA，Methyl 4-methoxyacetoacetate Methyl4-Methoxyacetoacetate> Methyl 4-Methoxyacetoacetat Dolutegravir Intermediates2 N-(3-methylphenyl)-N-(phenylmethyl)-2-(1-piperidinyl)acetamide hydrochloride Methyl 4-methoxy-3-oxobu 4-Methoxyacetoacetate methyl ester Methyl4-methoxyacetate 41051-15-4 CH3OCH2COCH2COOCH3 Organic Building Blocks Esters Building Blocks Carbonyl Compounds C6 to C7 Acetics acid and esters C6 to C7 Carbonyl Compounds Esters