D-(+)-Camphoric acid
- CAS No.
- 124-83-4
- Chemical Name:
- D-(+)-Camphoric acid
- Synonyms
- (1R,3S)-CAMPHORIC ACID;(1R)-1,2,2-trimethylcyclopentane-1,3-dicarboxylic acid;(1R,3S)-1,2,2-triMethylcyclopentane-1,3-dicarboxylic acid;1,3-Cyclopentanedicarboxylic acid, 1,2,2-trimethyl-, (1R-cis)-;D-caMphor acid;D-(+)-Camphoric;(+)-CAMPHORIC ACID;D-(+)-Camphoricaci;D-(+)-Camphoric acid;Dextro-camphoric acid
- CBNumber:
- CB5296789
- Molecular Formula:
- C10H16O4
- Molecular Weight:
- 200.23
- MDL Number:
- MFCD00001375
- MOL File:
- 124-83-4.mol
- MSDS File:
- SDS
Melting point | 186-189 °C |
---|---|
alpha | 46.5 º (c=10, C2H5OH) |
Boiling point | 297.96°C (rough estimate) |
Density | 1.1860 |
refractive index | 1.4459 (estimate) |
storage temp. | Sealed in dry,Room Temperature |
solubility | DMSO (Slightly), Ethanol (Slightly), Methanol (Slightly) |
form | Crystalline Powder |
pka | pK1: 4.57;pK2: 5.10 (25°C) |
color | White |
optical activity | [α]20/D 46°, c = 1 in ethanol |
Water Solubility | 0.8 g/100 mL |
Merck | 14,1733 |
BRN | 2050204 |
CAS DataBase Reference | 124-83-4(CAS DataBase Reference) |
FDA UNII | W77RM1CSD5 |
NIST Chemistry Reference | D-camphoric acid(124-83-4) |
EPA Substance Registry System | 1,3-Cyclopentanedicarboxylic acid, 1,2,2-trimethyl-, (1R,3S)- (124-83-4) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS07 |
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Signal word | Warning | |||||||||
Hazard statements | H302-H315-H319 | |||||||||
Precautionary statements | P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313 | |||||||||
Hazard Codes | Xn | |||||||||
Risk Statements | 22 | |||||||||
Safety Statements | 24/25 | |||||||||
WGK Germany | 2 | |||||||||
TSCA | Yes | |||||||||
HS Code | 29172090 | |||||||||
NFPA 704 |
|
D-(+)-Camphoric acid price More Price(23)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | C409 | (1R,3S)-(+)-Camphoric acid 99% | 124-83-4 | 5g | $49.6 | 2024-03-01 | Buy |
Sigma-Aldrich | C409 | (1R,3S)-(+)-Camphoric acid 99% | 124-83-4 | 100g | $101 | 2024-03-01 | Buy |
TCI Chemical | C0012 | (+)-Camphoric Acid >98.0%(GC)(T) | 124-83-4 | 25g | $85 | 2024-03-01 | Buy |
TCI Chemical | C0012 | (+)-Camphoric Acid >98.0%(GC)(T) | 124-83-4 | 100g | $233 | 2024-03-01 | Buy |
Alfa Aesar | B23106 | (1R,3S)-(+)-Camphoric acid, 98+% | 124-83-4 | 25g | $30.65 | 2024-03-01 | Buy |
D-(+)-Camphoric acid Chemical Properties,Uses,Production
Chemical Properties
white to light yellow crystal powde
Uses
D-(+)-Camphoric acid is used primarily as a reagent in syntheses of crystalline structures. It is used in the preparation of polymeric transition metal dipyridylamine D-camphorate complexes.
Uses
(1R,3S)-(+)-Camphoric acid may be used in the preparation (1R,2S,3R,5S)-2,3-dibenzyl-1,8,8-trimethyl-3-thianiumbicyclo[3.2.1]octane perchlorate. It reacts with uranyl nitrate in pyridine(py) or py/methanol(MeOH) to form novel uranyl-organic assemblages.
Definition
ChEBI: (?)-Camphoric acid is a dicarboxylic acid.
General Description
Camphoric acid is a diacid, generally prepared by the oxidation of terpene (+)-camphor. It can be used as a chirality inducing agent in some organic reactions.
storage
+4°C
Purification Methods
Purify the acid by re-precipitation from an alkaline solution by HCl, filter it off, and recrystallise it from water several times, rejecting the first crop. It forms leaflets from EtOH and Me2CO and H2O and is insoluble in CHCl3. Its solubility in H2O is 0.8% at 25o and 10% at 100o, 50% in EtOH and 5% in ethylene glycol. The (±)-acid has m 202-203o. The (+)-1-methyl ester has m 86o (from pet ether) [] 20 +45o (c 4, EtOH), and the (+)-3-methyl ester has m 77o (from pet ether) []17.5 +53.9o (c 3, EtOH). [Rupe & Thommen Helv Chim Acta 30 933
D-(+)-Camphoric acid Preparation Products And Raw materials
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29798 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 16914 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21668 | 55 |
Shanghai Time Chemicals CO., Ltd. | +86-021-57951555 +8617317452075 | jack.li@time-chemicals.com | China | 1807 | 55 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29894 | 58 |
Xi'an Kono chem co., Ltd., | 029-86107037 13289246953 | info@konochemical.com | China | 2995 | 58 |
Standardpharm Co. Ltd. | 86-714-3992388 | overseasales1@yongstandards.com | United States | 14336 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39916 | 58 |
Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63711 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49391 | 58 |
View Lastest Price from D-(+)-Camphoric acid manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
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2024-08-20 | D-(+)-Camphoric acid
124-83-4
|
US $300.00 / KG | 1KG | 98% | 10000KG | Baoji Guokang Bio-Technology Co., Ltd. | |
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2023-09-06 | D-(+)-Camphoric acid
124-83-4
|
US $0.00 / KG | 1KG | 99% | 500000kg | Hebei Guanlang Biotechnology Co., Ltd. | |
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2022-09-20 | D-(+)-Camphoric acid
124-83-4
|
US $0.00 / kg | 1kg | 99% | 1000kg | henan kanbei chemical co.,ltd |
-
- D-(+)-Camphoric acid
124-83-4
- US $300.00 / KG
- 98%
- Baoji Guokang Bio-Technology Co., Ltd.
-
- D-(+)-Camphoric acid
124-83-4
- US $0.00 / KG
- 99%
- Hebei Guanlang Biotechnology Co., Ltd.
-
- D-(+)-Camphoric acid
124-83-4
- US $0.00 / kg
- 99%
- henan kanbei chemical co.,ltd