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Trimethylsulfoxonium iodide

Trimethylsulfoxonium iodide structure

CAS No.: 1774-47-6

Chemical Name:: Trimethylsulfoxonium iodide

Synonyms: TMSOI;Trimethylsulfoxonium;TRIMETHYLSULPHOXONIUM IODIDE;Trimethyl sulfoxide iodide;trimethyloxosulphonium iodide;TriMethyloxosulfoniuM Iodide;NSC 71213;foxonium iodide;RARECHEM AQ A1 0066;Trimethyl sulfoxide

CBNumber:: CB5304873

Molecular Formula:: C3H9IOS

Molecular Weight:: 220.07

MDL Number:: MFCD00011899

MOL File:: 1774-47-6.mol

MSDS File:: SDS

Last updated:2024-11-01 18:09:03

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Trimethylsulfoxonium iodide Properties

Melting point	208-212 °C (dec.) (lit.)
Density	1.7074 (estimate)
storage temp.	Keep in dark place,Inert atmosphere,Room temperature
solubility	H₂O: 50 mg/mL, clear
form	Crystalline Powder
color	White to light yellow
PH	pH(50g/l, 25℃) : 4.8～6.0
Water Solubility	15 g/L (20 ºC)
Sensitive	Light Sensitive
BRN	3595854
InChI	InChI=1S/C3H9OS.HI/c1-5(2,3)4;/h1-3H3;1H/q+1;/p-1
InChIKey	BPLKQGGAXWRFOE-UHFFFAOYSA-M
SMILES	[S+](=O)(C)(C)C.[I-]
CAS DataBase Reference	1774-47-6(CAS DataBase Reference)
EPA Substance Registry System	Sulfoxonium, trimethyl-, iodide (1774-47-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P280a-P304+P340-P305+P351+P338-P405-P501a

Hazard Codes

Xn,Xi

Risk Statements

36/37/38-22

Safety Statements

37/39-26-36-24/25

WGK Germany

RTECS

WS3585000

TSCA

Yes

HS Code

29309070

NFPA 704

	1
1		0

Trimethylsulfoxonium iodide price More Price(36)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	T80500	Trimethylsulfoxonium iodide 98%	1774-47-6	100g	$49.14	2024-03-01	Buy
Sigma-Aldrich	T80500	Trimethylsulfoxonium iodide 98%	1774-47-6	25g	$60.7	2024-03-01	Buy
TCI Chemical	T1065	Trimethylsulfoxonium Iodide >98.0%(T)	1774-47-6	25g	$22	2024-03-01	Buy
TCI Chemical	T1065	Trimethylsulfoxonium Iodide >98.0%(T)	1774-47-6	100g	$60	2024-03-01	Buy
Alfa Aesar	A14589	Trimethylsulfoxonium iodide 98+%	1774-47-6	25g	$20.65	2024-03-01	Buy

Product number	Packaging	Price	Buy
T80500	100g	$49.14	Buy
T80500	25g	$60.7	Buy
T1065	25g	$22	Buy
T1065	100g	$60	Buy
A14589	25g	$20.65	Buy

Trimethylsulfoxonium iodide Chemical Properties,Uses,Production

Chemical Properties

WHITE TO LIGHT YELLOW CRYSTALLINE POWDER

Uses

Trimethylsulfoxonium iodide is a sulfoxonium salt. It is used to generate dimethyloxosulfonium methylide by reaction with sodium hydride. The latter compound is used as a methylene-transfer reagent, and is used to prepare epoxides.

Uses

Trimethylsulfoxonium Iodide is used to synthesize methylene-transfer reagents that are used in the preparation of epoxides.

Uses

Treatment with strong base yields the ylide which adds to the carbonyl group of ketones1 and aldehydes2,3 to give epoxides. Also adds preferentially to the double bond of α,β-unsaturated esters to give cyclopropyl esters.4,5

Synthesis

Trimethylsulfoxonium iodide is commonly prepared by a reaction of Dimethyl Sulfoxide with ≈2.5 equiv of Iodomethane. After refluxing for 24 h at 80?°C, the reaction mixture is cooled, and the crude solid product is filtered and washed with acetone to give the trimethylsulfoxonium iodide. Iodomethane has to be handled in a fume hood because of its high volatility and toxicity. Excess MeI is used to ensure the completion of the reaction.

storage

The iodide and chloride salts are hygroscopic and must be stored in a cool, dry place. They are incompatible with strong oxidizing agents and strong bases. The iodide salt is sensitive to light and needs to be protected from light as much as possible.

Trimethylsulfoxonium iodide synthesis

Synthesis of Trimethylsulfoxonium iodide from Dimethyl sulfoxide and Iodomethane

Trimethylsulfoxonium iodide Preparation Products And Raw materials

Raw materials

Preparation Products

Styrene oxide 1-BOC-4-HYDROXY-4-(HYDROXYMETHYL)-PIPERIDINE 2-(1-Adamantyl)oxirane 10-methoxy-1,6-dimethylergoline-8beta-methanol Methanone, [2-(4-methoxyphenyl)cyclopropyl]phenyl-

2,3-dihydro-6-Methoxy-3-Methylene-1H-Isoindol-1-one 3-Methylnorcaran-2-one tetrahydro-3-(2-oxiranyl)Furan 2-Methyl-1-(p-tolylsulfonyl)azetidine Spiro[2.5]octane-1-carboxylic acid, 6-cyclohexyl-, methyl ester

Benzofuran, 7-oxiranyl- (9CI) 7-Bromo-2,3-dihydrobenzofuran-3-ol Ethyl 2-phenyl-4-(2,2,2-trifluoroethyl)-4,5-dihydrooxazole-4-carboxylate 2-Propyloxetane

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Trimethylsulfoxonium iodide Suppliers

Global( 639)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Joyochem Co.,Ltd	+86-0531-82687558 +8613290333633	sales@joyochem.com	China	31	58
Jinan Dexinjia Bio&Tech Co., Ltd	+86-0531-82375893 +86-15064117275	sales@jndxj.com	China	1267	58
Shaanxi Dideu Medichem Co. Ltd	+86-29-81148696 +86-15536356810	1022@dideu.com	China	3882	58
Hebei Mojin Biotechnology Co., Ltd	+86 13288715578 +8613288715578	sales@hbmojin.com	China	12837	58
Hebei Weibang Biotechnology Co., Ltd	+8617732866630	bess@weibangbio.com	China	18194	58
Hebei Jingbo New Material Technology Co., Ltd	+8619931165850	hbjbtech@163.com	China	1000	58
airuikechemical co., ltd.	+undefined86-15315557071	sales02@sdzhonghuimaterial.com	China	983	58
Hebei Saisier Technology Co., LTD	+86-18400010335 +86-18034520335	admin@hbsaisier.cn	China	1015	58
Hebei Zhuanglai Chemical Trading Co.,Ltd	+8613343047651	admin@zlchemi.com	China	3002	58
Hebei Longbang Technology Co., LTD	+86-18633929156 +86-18633929156	admin@hblongbang.com	China	941	58

Supplier	Advantage
Joyochem Co.,Ltd	58
Jinan Dexinjia Bio&Tech Co., Ltd	58
Shaanxi Dideu Medichem Co. Ltd	58
Hebei Mojin Biotechnology Co., Ltd	58
Hebei Weibang Biotechnology Co., Ltd	58
Hebei Jingbo New Material Technology Co., Ltd	58
airuikechemical co., ltd.	58
Hebei Saisier Technology Co., LTD	58
Hebei Zhuanglai Chemical Trading Co.,Ltd	58
Hebei Longbang Technology Co., LTD	58

View Lastest Price from Trimethylsulfoxonium iodide manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-11-02	Trimethylsulfoxonium iodide 1774-47-6	US $0.00 / KG	1KG	98%min	30tons/month	WUHAN FORTUNA CHEMICAL CO., LTD
2024-11-01	Trimethylsulfoxonium iodide 1774-47-6	US $60.00 / kg	1kg	99%	5000kg/week	Hebei Zhuanglai Chemical Trading Co.,Ltd
2024-11-01	Trimethylsulfoxonium iodide 1774-47-6	US $6.00 / kg	1kg	99%	2000KG/Month	HebeiShuoshengImportandExportco.,Ltd

Trimethylsulfoxonium iodide
1774-47-6
US $0.00 / KG
98%min
WUHAN FORTUNA CHEMICAL CO., LTD

Trimethylsulfoxonium iodide
1774-47-6
US $60.00 / kg
99%
Hebei Zhuanglai Chemical Trading Co.,Ltd

Trimethylsulfoxonium iodide
1774-47-6
US $6.00 / kg
99%
HebeiShuoshengImportandExportco.,Ltd

Trimethylsulfoxonium iodide Spectrum

Trimethylsulfoxonium iodide(1774-47-6)MS Trimethylsulfoxonium iodide(1774-47-6)¹HNMR Trimethylsulfoxonium iodide(1774-47-6)¹³CNMR Trimethylsulfoxonium iodide(1774-47-6)IR1 Trimethylsulfoxonium iodide(1774-47-6)IR2 Trimethylsulfoxonium iodide(1774-47-6)Raman

1774-47-6(Trimethylsulfoxonium iodide)Related Search:

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