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Phenyl trifluoromethanesulfonate

Phenyl trifluoromethanesulfonate Structure
Phenyl trifluoromethanesulfonate structure
CAS No.
17763-67-6
Chemical Name:
Phenyl trifluoromethanesulfonate
Synonyms
Phenol triflate;PHENYL TRIFLATE;Phenol trifluoromethanesulfonate;PHENYL TRIFLUOROMETHANESULFONATE;Trifluoromethylsulfonyloxybenzene;Phenyl rifluoromehanesulfonae, 98%;PhenylTrifluoromethanesulfonate>Phenyl trifluoromethanesulfonate 98%;Trifluoromethanesulfonic acid phenyl ester;Methanesulfonic acid, 1,1,1-trifluoro-, phenyl ester
CBNumber:
CB5369083
Molecular Formula:
C7H5F3O3S
Molecular Weight:
226.17
MDL Number:
MFCD00192399
MOL File:
17763-67-6.mol
Last updated:2023-06-08 17:06:37
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Phenyl trifluoromethanesulfonate Properties

Boiling point 99-100 °C/60 mmHg (lit.)
Density 1.396 g/mL at 25 °C (lit.)
refractive index n20/D 1.435(lit.)
Flash point 160 °F
storage temp. Inert atmosphere,Room Temperature
form clear liquid
color Colorless to Almost colorless

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS05,GHS06
Signal word  Danger
Hazard statements  H301+H311-H314
Precautionary statements  P270-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P361+P364
Hazard Codes  T
Risk Statements  36/37/38-34-24/25
Safety Statements  26-36-45-36/37/39
RIDADR  UN 2927 6.1/PG 2
WGK Germany  3
HS Code  29049090
NFPA 704
2
2 0

Phenyl trifluoromethanesulfonate price More Price(20)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 423939 Phenyl trifluoromethanesulfonate 98% 17763-67-6 5ml $178 2024-03-01 Buy
TCI Chemical P1829 Phenyl Trifluoromethanesulfonate >98.0%(GC) 17763-67-6 1g $28 2024-03-01 Buy
TCI Chemical P1829 Phenyl Trifluoromethanesulfonate >98.0%(GC) 17763-67-6 5g $102 2024-03-01 Buy
TRC P337555 Phenyl Trifluoromethanesulfonate 17763-67-6 50mg $45 2021-12-16 Buy
TRC P337555 Phenyl Trifluoromethanesulfonate 17763-67-6 500mg $75 2021-12-16 Buy
Product number Packaging Price Buy
423939 5ml $178 Buy
P1829 1g $28 Buy
P1829 5g $102 Buy
P337555 50mg $45 Buy
P337555 500mg $75 Buy

Phenyl trifluoromethanesulfonate Chemical Properties,Uses,Production

Chemical Properties

Colorless Liquid.

Uses

Phenyl trifluoromethanesulfonate (phenyl triflate) may be used in the following studies:
As an arylating agent for the asymmetric α-arylation of ketones catalyzed by Pd(dba)2 and difluorphos.
As a reactant in the one pot synthesis of carbazoles by palladium-catalyzed N-arylation of anilines with phenyl triflate followed by oxidative coupling.
Synthesis of N-(2,6-diarylbenzoyl)anilines by diarylation of benzanilides with phenyl triflate in the presence of palladium-based catalyst.
As an arylating agent in the synthesis of (R)-2-phenyl-2,3-dihydrofuran by the arylation of 2,3-dihydrofuran.

Preparation

Synthesis of Phenyl trifluoromethanesulfonate: The reaction of phenol (1.00 g, 10.6 mmol) with triflic anhydride as outlined in the general procedure provided phenyl trifluoromethanesulfonate as colorless oil (0.73 g, 30%).
1H NMR (400 MHz, CDCl3) δ 7.50 – 7.42 (m, 2H), 7.41 – 7.36 (m, 1H), 7.32 – 7.24 (m, 2H).

General Description

Phenyl trifluoromethanesulfonate (phenyl triflate) is an aryl fluorosulphonate. It has been synthesized by the reaction of phenol with fluorosulphonic anhydride.

Phenyl trifluoromethanesulfonate Preparation Products And Raw materials

Raw materials

Preparation Products

4-Nitrophenylboronic acid pinacol ester N-PHENYL-3-BIPHENYLAMINE R-3,3'-Bis(phenyl)-1,1'-bi-2-naphthol 4-PHENYL-3-BUTYN-1-OL 1-PHENYLCYCLOPENTENE
3-HYDROXYBENZOPHENONE Methyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate Phenylpentane

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Phenyl trifluoromethanesulfonate Suppliers

Global( 93)Suppliers
Supplier Tel Email Country ProdList Advantage
Changzhou Ansciep Chemical Co., Ltd. 		+86 519 86305871 sales@ansciepchem.com CHINA 4241 58
career henan chemical co 		+86-0371-86658258 +8613203830695 factory@coreychem.com China 29811 58
Zhengzhou Alfa Chemical Co.,Ltd 		+8618530059196 sale04@alfachem.cn China 13482 58
Hefei TNJ Chemical Industry Co.,Ltd. 		+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34553 58
Dayang Chem (Hangzhou) Co.,Ltd. 		571-88938639 +8617705817739 info@dycnchem.com China 52849 58
Aromsyn Co., Ltd. 		+86-0571-85585865 +8613336024896 CB@aromsyn.com China 19183 58
Hebei Weibang Biotechnology Co., Ltd 		+8617732866630 bess@weibangbio.com China 18153 58
PT CHEM GROUP LIMITED 		peter68@ptchemgroup.com China 35425 58
GIHI CHEMICALS CO.,LIMITED 		+8618058761490 info@gihichemicals.com China 49979 58
Aceschem Inc. 		+1-817863-6948 +1-（817）863-6948 sales@aceschem.com United States 19632 58
Supplier Advantage
Changzhou Ansciep Chemical Co., Ltd. 		58
career henan chemical co 		58
Zhengzhou Alfa Chemical Co.,Ltd 		58
Hefei TNJ Chemical Industry Co.,Ltd. 		58
Dayang Chem (Hangzhou) Co.,Ltd. 		58
Aromsyn Co., Ltd. 		58
Hebei Weibang Biotechnology Co., Ltd 		58
PT CHEM GROUP LIMITED 		58
GIHI CHEMICALS CO.,LIMITED 		58
Aceschem Inc. 		58

View Lastest Price from Phenyl trifluoromethanesulfonate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
PHENYL TRIFLUOROMETHANESULFONATE pictures 2020-02-06 PHENYL TRIFLUOROMETHANESULFONATE
17763-67-6
 US $3.00 / KG 1KG 98% 100KG Career Henan Chemical Co

Phenyl trifluoromethanesulfonate Spectrum

Phenyl trifluoromethanesulfonate(17763-67-6)IR

17763-67-6(Phenyl trifluoromethanesulfonate)Related Search:

4-BROMOPHENYL TRIFLUOROMETHANESULFONATE Trimethylsilyl trifluoromethanesulfonate TRIFLUOROMETHYL SULFINYL CHLORIDE SILVER TRIFLUOROMETHANESULFONATE Trifluoromethanesulfonyl chloride
Ethyl trifluoromethanesulfonate Trifluoromethanesulfonic anhydride Sodium trifluoromethanesulfonate Trifluoromethanesulfonic acid Lithium trifluoromethanesulfonate
Methyl trifluoromethanesulfonate 4-METHYL-2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE,98.0+%(GC),4-METHYL-2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE P-TOLYL TRIFLATE 1-NAPHTHYL TRIFLATE 4-NITROPHENYL TRIFLUOROMETHANESULFONATE
2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE METHYL 2-TRIFLUOROMETHANESULFONYLOXY-1-NAPHTHOATE (R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate)

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PHENYL TRIFLUOROMETHANESULFONATE PHENYL TRIFLATE Phenol triflate Phenol trifluoromethanesulfonate Trifluoromethanesulfonic acid phenyl ester Trifluoromethylsulfonyloxybenzene Trifluoromethanesulfonic Acid Phenyl Ester Phenyl Triflate Phenyl trifluoromethanesulfonate 98% PhenylTrifluoromethanesulfonate> Methanesulfonic acid, 1,1,1-trifluoro-, phenyl ester Phenyl rifluoromehanesulfonae, 98% 17763-67-6 C6H5SO3CF3 Building Blocks Organic Building Blocks Organic Triflates Sulfur Compounds