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(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl

(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl structure

CAS No.: 135139-00-3

Chemical Name:: (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl

Synonyms: Xylbinap;(S)-DM-BINAP;RAC-XYLYL-BINAP;(S)-3,5-XYLYL-BINAP;(S)-(-)-XyL;98% (S)-XylBINAP;(S)-(-)-XylBINAP;(S)-3,5-Xyl-BINAP;RAC-3,5-Xylyl-Binap;(R)-3,5-Xylyl-binap ,98%

CBNumber:: CB5381548

Molecular Formula:: C52H48P2

Molecular Weight:: 734.89

MDL Number:: MFCD01630821

MOL File:: 135139-00-3.mol

MSDS File:: SDS

Last updated:2025-02-23 21:28:46

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(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl Properties

Melting point	203-206°C
alpha	-172 º (c=1 in chloroform)
Boiling point	825.3±65.0 °C(Predicted)
storage temp.	Inert atmosphere,Room Temperature
Water Solubility	Insoluble in water
form	crystal
color	white to pale yellow
optical activity	[α]/D -172°, 20, c =1 in chloroform
UNSPSC Code	12352005

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P280a-P304+P340-P305+P351+P338-P405-P501a

Risk Statements

36/37/38

Safety Statements

26-37

TSCA

HS Code

2931.90.6000

NFPA 704

	1
2		0

(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl price More Price(23)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
TCI Chemical	X0071	(S)-(-)-XylBINAP >97.0%(HPLC)	135139-00-3	200mg	$68	2024-03-01	Buy
TCI Chemical	X0071	(S)-(-)-XylBINAP >97.0%(HPLC)	135139-00-3	1g	$207	2024-03-01	Buy
Alfa Aesar	H26970	(S)-(-)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl, 98%	135139-00-3	500mg	$301	2021-12-16	Buy
Alfa Aesar	H26970	(S)-(-)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl, 98%	135139-00-3	100mg	$93.3	2021-12-16	Buy
Strem Chemicals	15-0477	(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl, 98% (S)-(-)-XylBINAP	135139-00-3	250mg	$48	2024-03-01	Buy

Product number	Packaging	Price	Buy
X0071	200mg	$68	Buy
X0071	1g	$207	Buy
H26970	500mg	$301	Buy
H26970	100mg	$93.3	Buy
15-0477	250mg	$48	Buy

(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl Chemical Properties,Uses,Production

Reaction

Ligand used in copper-catalyzed asymmetric Mannich-type reactions of N-acylimino esters.
Ligand used in the enantioselective fluorination of oxindoles.
Ligand used in [2+2+2] cycloaddition of tetraynes and hexaynes.
Ligand used in the asymmetric reduction of ketone via ruthenium-catalyzed transfer hydrogenation.
Asymmetric hydroboration of unsaturated imines.

Uses

Catalyst for:

Asymmetric hydrogenation of benzophenone
Regio- and stereoselective preparation of axially chiral arylnaphthalene derivatives via rhodium-catalyzed [2+2+2] cycloaddition of diynes with naphthalenepropynoic acid derivatives in the presence of chiral biaryl bisphosphine ligands
Regiodivergent rhodium-catalyzed [(2+2)+2] carbocyclization of 1,6-enynes with Me propiolates
Ligand controlled regioselective and stereoselective desymmetrizing rhodium-catalyzed allylic arylation of meso cyclopentene dicarbonates with arylboronic acids to form regioisomeric arylcyclopentenols
Platinum(II) complex-catalyzed enantioselective aldol reaction with ketene silyl acetals in DMF at room temperature
Stereoselective preparation of chiral N,O-biaryls via Rh-catalyzed [2+2+2] cycloaddition of conjugate ynamides with diynes

(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl synthesis

Synthesis of (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl from Phosphine oxide, [1,1'-binaphthalene]-2,2'-diylbis[bis(3,5-dimethylphenyl)-, (+)- (9CI)

(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl Preparation Products And Raw materials

Raw materials

Phosphine oxide, [1,1'-binaphthalene]-2,2'-diylbis[bis(3,5-dimethylphenyl)-, (+)- (9CI)

Preparation Products

(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl Suppliers

Global( 153)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
XINXIANG RUNYU MATERIAL CO., LTD.	+86-13592593621; +8613592593621	sales@runvmat.com	China	400	58
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	19885	58
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29869	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28172	58
Accela ChemBio Inc.	+1-858-6993322	info@accelachem.com	United States	18526	58
Chongqing Chemdad Co., Ltd	+86-023-6139-8061 +86-86-13650506873	sales@chemdad.com	China	39894	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49732	58
Richest Group Ltd	18017061086	oled@richest-group.com	CHINA	5600	58
Jinan Honest Pharm Co., Ltd	+8615318812076	zpy8217@163.com	China	286	58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.	+86-021-61551413 +8618813727289	contact@trustwe.com	China	5738	58

Supplier	Advantage
XINXIANG RUNYU MATERIAL CO., LTD.	58
Shanghai Daken Advanced Materials Co.,Ltd	58
career henan chemical co	58
Hubei Jusheng Technology Co.,Ltd.	58
Accela ChemBio Inc.	58
Chongqing Chemdad Co., Ltd	58
CONIER CHEM AND PHARMA LIMITED	58
Richest Group Ltd	58
Jinan Honest Pharm Co., Ltd	58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.	58

View Lastest Price from (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2025-02-24	(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl 135139-00-3	US $0.00 / kg	1kg	99%	10000KGS	Shaanxi Dideu New Materials Co. Ltd
2020-06-02	(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl 135139-00-3	US $6.00 / kg	1kg	High quality Professional Factory	Ms Ella chemwill_asia@126.com www.chemwill.com	Chemwill Asia Co.,Ltd.
2019-07-06	(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl 135139-00-3	US $1.00 / kg	1kg	98%	100KG	Career Henan Chemical Co

(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl
135139-00-3
US $0.00 / kg
99%
Shaanxi Dideu New Materials Co. Ltd

(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl
135139-00-3
US $6.00 / kg
High quality Professional Factory
Chemwill Asia Co.,Ltd.

(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl
135139-00-3
US $1.00 / kg
98%
Career Henan Chemical Co

(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl Spectrum

(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl(135139-00-3)¹HNMR (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl(135139-00-3)³¹PNMR

135139-00-3((S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl)Related Search:

Dicyclohexylchlorophosphine (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (R)-DM-BINAP (R)-3,5-XYLYL-BINAP Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II)

Chloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II)chloride Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) Diacetato{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II)

Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II)chloride (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl Dimethylammoniumdichlorotri(mu-chloro)bis{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}diruthenate(II) Dimethylammoniumdichlorotri(mu-chloro)bis{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}diruthenate(II)

2,2'-BIS[BIS(3,5-DITRIFLUOROMETHYLPHENYL)PHOSPHINO]-1,1'-BINAPHTHYL (R)-(+)-2,2'-BIS[BIS(3,5-DITRIFLUOROMETHYLPHENYL)PHOSPHINO]-1,1'-BINAPHTHYL Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2μ-bis[di-(3,5-xylyl)phosphino]-1,1μ-binaphthyl]diruthenate(II)

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2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL 2,2'-BIS[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]-1,1'-BINAPHTHYL (S)-(-)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl , ((S)-Xylyl (S)-(-)-2,2'-Bis[bis(3,5-dimethylphenyl)phosphino]-1,1'-binaphthyl (S)-3,5-Xyl-BINAP PHOSPHINE, 1,1''-[(1S)-[1,1''-BINAPHTHALENE]-2,2''-DIYL]BIS[1,1-BIS(3,5-DIMETHYLPHENYL)- (S)-(-)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl , 98% ((S)-Xylyl-BINAP) (S)-3,5-Xylyl-BINAP, (S)-(-)-2,2μ-Bis[di(3,5-xylyl)phoshino]-1,1μ-binaphthyl, (S)-(-)-2,2μ-Bis[bis(3,5-dimethylphenyl)phosphino]-1,1μ-binaphthyl 4-keto-2-(propylamino)furan-3-carboxylic acid ethyl ester ethyl 4-oxo-2-(propylamino)furan-3-carboxylate (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl, 98% (S)-(-)-XylBINAP (R)-3,5-Xylyl-binap ,98% RACEMIC-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,98%(S)-3,5-xylyl-BINAP (S)-(-)-2,2'-bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl (S)-(-)-2,2''-BIS(DI(3,5-XYLYL)PHOSPHINO)-1,1''-BINAPHTYL (S)-3,5-XYLYL-BINAP (S)-(-)-2,2''-BIS(DI(3,5-XYLYL)PHOSPHINO)-1,1''-BINAPHTHYL (S)-3,5-XYLYL-BINAP (S)-(-)-2,2'-Bis(di(3,5-xylyl)phosphino)-1,1'-binaphtyl 98% (S)-XylBINAP (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,98% (S)-(-)-XylBINAP (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,(S)-XylBINAP (S)-(-)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl , ((S)-Xylyl-BINAP) (R)-2,2'-Bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene (S)-2,2'-bis(bis(3,5-dimethylphenyl)phosphanyl)-1,1'-binaphthalene 1,1'-[(1S)-[1,1'-Binaphthalene]-2,2'-diyl]bis[1,1-bis(3,5-dimethylphenyl)-phosphine RAC-3,5-Xylyl-Binap (S)-(-)-XyL (S)-2,2'-Bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl [(S)-DM-Binap (S)-3,5-XYLYL-BINAP RAC-XYLYL-BINAP Xylbinap (S)-DM-BINAP (s)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl 2,2'-bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene 135139-00-3 C52H48P2 BINAP Series Chiral Phosphine