4-Ethynylanisole
- CAS No.
- 768-60-5
- Chemical Name:
- 4-Ethynylanisole
- Synonyms
- 1-ETHYNYL-4-METHOXYBENZENE;4-METHOXYPHENYLACETYLENE;NSC 71091;Anisylacetylene;P-ETHYNYLANISOLE;4-ETHYNYLANISOLE;4-Ethynylanisode;4-Ethynylanisole>4-Ethynylanisole,97%;4-Ethynylanisole 97%
- CBNumber:
- CB5403244
- Molecular Formula:
- C9H8O
- Molecular Weight:
- 132.16
- MDL Number:
- MFCD00168815
- MOL File:
- 768-60-5.mol
- MSDS File:
- SDS
Melting point | 28-29 °C (lit.) |
---|---|
Boiling point | 87-91 °C/11 mmHg (lit.) |
Density | 1.019 g/mL at 25 °C (lit.) |
refractive index |
n |
Flash point | 180 °F |
storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
solubility | Acetontrile (Slightly), Chloroform (Slightly) |
form | Liquid or Low Melting Solid |
color | Clear colorless to deep yellow or brown |
Water Solubility | Insoluble in water. Soluble in chloroform, acetone, dichloromethane, and methanol. |
Sensitive | Light Sensitive |
Stability | Light and Temperature Sensitive |
InChIKey | KBIAVTUACPKPFJ-UHFFFAOYSA-N |
CAS DataBase Reference | 768-60-5(CAS DataBase Reference) |
NIST Chemistry Reference | 4-CH3O-C6H4-CCH(768-60-5) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Warning | |||||||||
Hazard statements | H302-H315-H319-H335 | |||||||||
Precautionary statements | P261-P280-P301+P312-P302+P352-P305+P351+P338 | |||||||||
Hazard Codes | Xn,F | |||||||||
Risk Statements | 22 | |||||||||
Safety Statements | 24/25 | |||||||||
RIDADR | UN 1325 4.1/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29093090 | |||||||||
NFPA 704 |
|
4-Ethynylanisole price More Price(47)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 206490 | 4-Ethynylanisole 97% | 768-60-5 | 1g | $113 | 2024-03-01 | Buy |
Sigma-Aldrich | 206490 | 4-Ethynylanisole 97% | 768-60-5 | 5g | $341 | 2024-03-01 | Buy |
TCI Chemical | E0603 | 4-Ethynylanisole >98.0%(GC) | 768-60-5 | 1g | $51 | 2024-03-01 | Buy |
TCI Chemical | E0603 | 4-Ethynylanisole >98.0%(GC) | 768-60-5 | 5g | $137 | 2024-03-01 | Buy |
Alfa Aesar | H26283 | 4-Methoxyphenylacetylene, 99% | 768-60-5 | 1g | $74 | 2024-03-01 | Buy |
4-Ethynylanisole Chemical Properties,Uses,Production
Chemical Properties
Pale Yellow Oil
Uses
1,3-dipolar cycloaddition of acceptor-cyclopropylmethylsilanes affords functionalized cyclopentenes in good yields.1
Uses
Intermediate in the synthesis of histamine H3-receptor antagonists. Also utilized to prepare its luminescent copper complex
Uses
4-Ethynylanisole was used in the synthesis of photo luminescent 1,2-dihydrophosphinines via a [4 + 2] cycloaddition. Along with an arylboronic acid and sodium azide in a copper-catalyzed, three-component synthesis of trisubstituted 1,2,4-triazoles. In a study of a gold (III)-catalyzed hydroamination of alkynes leading to N-vinylindoles3.
Uses
Intermediates of Liquid Crystals
Definition
ChEBI: 1-Eth-1-ynyl-4-methoxybenzene is a member of methoxybenzenes.
Synthesis Reference(s)
Organic Syntheses, Coll. Vol. 9, p. 230, 1998
Synthesis, p. 305, 1978
Tetrahedron, 62, p. 6673, 2006 DOI: 10.1016/j.tet.2005.12.077
General Description
4-Ethynylanisole forms the corresponding propargyl aldehyde in good yield directly from DMF-dimethyl acetal without the need for making an acetylide salt. 1,3-dipolar cycloaddition of acceptor-cyclopropylmethylsilanes affords functionalized cyclopentenes in good yields.
4-Ethynylanisole Preparation Products And Raw materials
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18751 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21634 | 55 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29880 | 58 |
Changzhou Ansciep Chemical Co., Ltd. | +86 519 86305871 | sales@ansciepchem.com | CHINA | 4241 | 58 |
HaBo Hong Kong Co., Limited. | +86-25-18512596065 | info@habotech.com | CHINA | 933 | 58 |
Wuhan Pengo Technology.,Ltd. | +86-27-81330736 +86-13628634921 | sunny.w@boronicgroup.com | CHINA | 171 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39894 | 58 |
Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49374 | 58 |
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd | +8613580539051 | joe@yuhengpharm.com | CHINA | 21142 | 58 |
View Lastest Price from 4-Ethynylanisole manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2021-07-13 | 4-Ethynylanisole
768-60-5
|
US $15.00-10.00 / KG | 1KG | 99%+ HPLC | Monthly supply of 1 ton | Zhuozhou Wenxi import and Export Co., Ltd | ||
2021-07-10 | 4-Ethynylanisole
768-60-5
|
US $15.00-10.00 / KG | 1KG | 99%+ HPLC | Monthly supply of 1 ton | Zhuozhou Wenxi import and Export Co., Ltd | ||
2019-07-06 | 4-Ethynylanisole
768-60-5
|
US $7.00 / KG | 1KG | 99% | 100KG | Career Henan Chemical Co |
- 4-Ethynylanisole
768-60-5
- US $15.00-10.00 / KG
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
- 4-Ethynylanisole
768-60-5
- US $15.00-10.00 / KG
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
- 4-Ethynylanisole
768-60-5
- US $7.00 / KG
- 99%
- Career Henan Chemical Co