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Methyl 2-iodobenzoate

CAS No.
610-97-9
Chemical Name:
Methyl 2-iodobenzoate
Synonyms
IBM;2-Iodobenzoate;2-Iodo Methyl Benzoate;methyl iodobenzoate;Methy1;O-Methyl iodide;Methyl 2-iodobenzo;RARECHEM AL BF 0562;METHYL 2-IODOBENZOATE;METHYL O-IODOBENZOATE
CBNumber:
CB5468414
Molecular Formula:
C8H7IO2
Molecular Weight:
262.04
MDL Number:
MFCD00016351
MOL File:
610-97-9.mol
Last updated:2024-12-18 14:15:30

Methyl 2-iodobenzoate Properties

Melting point 64°C
Boiling point 149-150 °C/10 mmHg (lit.)
Density 1.784 g/mL at 25 °C (lit.)
refractive index n20/D 1.604(lit.)
Flash point >230 °F
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Chloroform, Ethyl Acetate (Slightly), Methanol
form Crystalling or Flaky Powder
color White
Water Solubility INSOLUBLE
Sensitive Light Sensitive
BRN 2206859
Stability Light Sensitive
InChIKey BXXLTVBTDZXPTN-UHFFFAOYSA-N
CAS DataBase Reference 610-97-9(CAS DataBase Reference)
FDA UNII HCW7KL2LZN
NIST Chemistry Reference Methyl-2-iodobenzoate(610-97-9)
EPA Substance Registry System Benzoic acid, 2-iodo-, methyl ester (610-97-9)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P305+P351+P338-P280a-P304+P340-P405-P501a
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36-24/25
WGK Germany  3
TSCA  T
HazardClass  IRRITANT
HS Code  29163990
NFPA 704
0
2 0

Methyl 2-iodobenzoate price More Price(36)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 532851 Methyl 2-iodobenzoate 97% 610-97-9 50g $80.6 2024-03-01 Buy
Sigma-Aldrich 532851 Methyl 2-iodobenzoate 97% 610-97-9 250g $185 2023-06-20 Buy
TCI Chemical I0586 Methyl 2-Iodobenzoate >98.0%(GC) 610-97-9 25g $50 2024-03-01 Buy
TCI Chemical I0586 Methyl 2-Iodobenzoate >98.0%(GC) 610-97-9 250g $196 2024-03-01 Buy
Alfa Aesar A13204 Methyl 2-iodobenzoate, 98% 610-97-9 10g $32.65 2024-03-01 Buy
Product number Packaging Price Buy
532851 50g $80.6 Buy
532851 250g $185 Buy
I0586 25g $50 Buy
I0586 250g $196 Buy
A13204 10g $32.65 Buy

Methyl 2-iodobenzoate Chemical Properties,Uses,Production

Chemical Properties

CLEAR YELLOW LIQUID

Uses

Methyl 2-iodobenzoate may be used in the preparation of:

  • N-substituted 4-methylene-3,4-dihydro-1(2H)-isoquinolin-1-ones
  • methyl diphenylacetylene-2-carboxylate
  • methyl 2-heptynylphenylbenzoate
  • (E)-2-[3-[3-[2-(7-chloro-2-quinolinyl)ethenyl]phenyl]-3-oxopropyl]benzoic acid methyl ester
  • 4-(2-carbomethoxyphenyl)-3-(1-methylethoxy)cyclobut-3-ene-1,2-dione
  • 3-(2-carbomethoxyphenyl)-4-methylcyclobuten-3-ene-1,2-dione 2-(ethylene acetal)

Synthesis Reference(s)

Journal of the American Chemical Society, 93, p. 4845, 1971 DOI: 10.1021/ja00748a030

General Description

Methyl 2-iodobenzoate can be prepared from 2-iodobenzoic acid via esterification. It undergoes cobalt-catalyzed cyclization with aldehydes to form phthalide derivatives. The microbial dihydroxylation of methyl 2-iodobenzoate forms a nonracemic iodocyclohexene carboxylate intermediate. This intermediate forms the precursor for preparing kibdelone C.

67-56-1
88-67-5
610-97-9
Synthesis of Methyl 2-iodobenzoate from Methanol and 2-Iodobenzoic acid
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View Lastest Price from Methyl 2-iodobenzoate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Methyl 2-Iodobenzoate pictures 2024-12-20 Methyl 2-Iodobenzoate
610-97-9
US $10.00 / kg 1kg 99% 20 ton Hebei Zhuanglai Chemical Trading Co Ltd
Methyl 2-iodobenzoate pictures 2024-10-25 Methyl 2-iodobenzoate
610-97-9
US $0.00 / kg 1kg 0.99 20tons Hebei Yanxi Chemical Co., Ltd.
Methyl 2-iodobenzoate pictures 2024-10-24 Methyl 2-iodobenzoate
610-97-9
US $30.00-10.00 / KG 50KG 99% 500000kg Hebei Weibang Biotechnology Co., Ltd
Methyl 2-iodobenzo Iodine benzoic acid Methyl ester 2-(Methoxycarbonyl)-1-iodobenzene O-Methyl iodide Methyl 2-iodobenzoate, 99+% 25ML Methyl 2-iodobenzoate≥ 99% (GC) 2-IODOBENZOIC ACID METHYL ESTER METHYL O-IODOBENZOATE METHYL 2-IODOBENZOATE BENZOIC ACID, 2-IODO-, METHYL ESTER O-IODOBENZOIC ACID METHYL ESTER RARECHEM AL BF 0562 2-iodo-benzoicacimethylester Benzoic acid, o-iodo-, methyl ester 2-IODOBENZOIC AICD METHYLESTER Methyl2-Iodobenzoate(2-IodobenzoicAcidMethylEster) 2-IodobenzoicAcidMethylEsterC8H7IO2 4-Methyl 2-Iodobenzoate (2-Iodobenzoic Acid Methyl Ester) C8H7Io2 Methyl2-iodobenzoate,98% Methyl 2-iodobenzoate, 99+% Methy1 Methyl 2-iodobenzoate 98% Methyl2-Iodobenzoate> 610-97-9 Methyl 2-iodobenzoate 2-Iodobenzoate IBM methyl iodobenzoate 2-Iodo Methyl Benzoate 2-Iodo Methyl Benzoate OR Methyl-2-Iodobenzoate OR 2- Iodobenzoic acid methyl Ester. Methyl orthoiodobenzoate Methyl-2-lodobenzoate 610-97-9 Organic Building Blocks Esters Building Blocks C8 to C9 Carbonyl Compounds Iodine Compounds C8 to C9 Carbonyl Compounds Esters Aromatic Esters Acids & Esters bc0001 610-97-9