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1-Naphthol-4-sulfonic acid

CAS No.
84-87-7
Chemical Name:
1-Naphthol-4-sulfonic acid
Synonyms
Niven acid;Neville acid;1,4-Oxy Acid;Nevile-Winther acid;Nevile-Winthers acid;1-Naphthol-4-sulfoni;HIGH-PURITY N.W. ACID;Nevileandwinther’sacid;Neville and winther acid;Naphthol-4-sulfonic acid
CBNumber:
CB5743566
Molecular Formula:
C10H8O4S
Molecular Weight:
224.23
MDL Number:
MFCD00065324
MOL File:
84-87-7.mol
MSDS File:
SDS
Last updated:2024-12-18 14:15:30

1-Naphthol-4-sulfonic acid Properties

Melting point 170℃
Boiling point 335.63°C (rough estimate)
Density 1.4643 (rough estimate)
refractive index 1.7040 (estimate)
pka 0.73±0.40(Predicted)
form solid
form solid
color white to yellow
InChI InChI=1S/C10H8O4S/c11-9-5-6-10(15(12,13)14)8-4-2-1-3-7(8)9/h1-6,11H,(H,12,13,14)
InChIKey HGWQOFDAUWCQDA-UHFFFAOYSA-N
SMILES C1(S(O)(=O)=O)=C2C(C=CC=C2)=C(O)C=C1
CAS DataBase Reference 84-87-7(CAS DataBase Reference)
FDA UNII 6W41U3C9YN
EPA Substance Registry System 1-Naphthalenesulfonic acid, 4-hydroxy- (84-87-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338

1-Naphthol-4-sulfonic acid price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
AK Scientific G342 1-Naphthol-4-sulfonicacid 84-87-7 1g $247 2021-12-16 Buy
American Custom Chemicals Corporation CHM0018266 1-NAPHTHOL-4-SULFONIC ACID 95.00% 84-87-7 5G $1127.86 2021-12-16 Buy
Alichem 84877 4-Hydroxynaphthalene-1-sulfonicacid 84-87-7 25g $1129.94 2021-12-16 Buy
Arctom AS028098 4-Hydroxynaphthalene-1-sulfonicacid 97% 84-87-7 25g $1130 2021-12-16 Buy
Chemenu CM140112 1-Naphthol-4-sulfonicacid 97% 84-87-7 25g $1198 2021-12-16 Buy
Product number Packaging Price Buy
G342 1g $247 Buy
CHM0018266 5G $1127.86 Buy
84877 25g $1129.94 Buy
AS028098 25g $1130 Buy
CM140112 25g $1198 Buy

1-Naphthol-4-sulfonic acid Chemical Properties,Uses,Production

Chemical Properties

Transparent flake crystal. soluble in water. 1-Hydroxynaphthalene- 4 -sulfonic acid [84-87-7]. (4-hydroxynaphthalene-1-sulfonic acid), Nevile and Winther’s acid, NW acid, C10H8O4S, Mr 224.23, and its salts are water soluble, but the sodium salt may be precipitated from solution by salting out. Coupling with diazo compounds takes place in the 2-position. Nitration yields 2,4-dinitro-1-naphthol, whereas nitrosation gives 2-nitroso-1-hydroxynaphthalene-4-sulfonic acid. Sulfonation leads to a mixture of 1-hydroxynaphthalene-2,4-di- and 2,4,7- trisulfonic acids.

Uses

1-Naphthol-4-sulfonic acid is used as an intermediate of azo dyes to prepare dyes such as direct copper blue BR and 2R, direct violet RB, acid red B and acid medium jujube red B

Preparation

After drying under vacuum, the resulting filter cake contains 1-naphthol-4-sulphonic acid in a yield of 92% of theory and <0.5% 1-naphthol-2-sulphonic acid and 3% of 1-naphthol-2,4-disulphonic acid based on the weight of 1-naphthol-4-sulphonic acid.

84-87-7.png

Synthesis

1-Naphthol-4-sulfonic acid was synthesized by addition, hydrolysis and acid precipitation of sodium 1,4-aminonaphthalene sulfonate.

1-Naphthol-4-sulfonic acid Preparation Products And Raw materials

Raw materials

Preparation Products

1of5

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View Lastest Price from 1-Naphthol-4-sulfonic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1-Naphthol-4-sulfonic acid pictures 2024-12-23 1-Naphthol-4-sulfonic acid
84-87-7
US $45.00 / kg 1kg 99% 5000kg/week Hebei Zhuanglai Chemical Trading Co.,Ltd
1-Naphthol-4-sulfonic acid pictures 2024-12-13 1-Naphthol-4-sulfonic acid
84-87-7
US $0.00 / KG 1KG 98%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
1-Naphthol-4-sulfonic acid pictures 2024-10-25 1-Naphthol-4-sulfonic acid
84-87-7
US $0.00 / kg 1kg 65.00% 20tons Hebei Yanxi Chemical Co., Ltd.
1-Naphthalenesulfonicacid,4-hydroxy- 4-hydroxy-1-naphthalenesulfonicaci 4-hydroxynaphthalene-1-sulphonicacid Nevileandwinther’sacid N-(M-SULFOPHENYL) GAMMA ACID 4-Hydroxy-1-naphthalenesulfonic acid 1-NAPHTHOL-4-SULFONIC ACID Nevile-Winthers acid Meville-winter acid(1-naphthol-4-sulfonic acid,NW-acid) 4-hydroxynaphthalene-1-sulfonic acid NEVILLE-WINTHER ACID (NA SALT) 1-Hydroxy-4-sulfonaphthalene HIGH-PURITY N.W. ACID 1-Hydroxy-4-naphthalenesulfonic acid Neville acid Neville and winther acid 1,4-Oxy Acid a-Naphthol-4-sulfonic acid Nevile-Winther acid 1-Naphthol-4-sulfoni Naphthol-4-sulfonic acid 1-Naphthol-4-sulfonicaci 1-Naphthol-4-sulfonic acid ISO 9001:2015 REACH 4-Hydroxynaphthalene-1-sulfonicacid hydrate Niven acid 84-87-7 C10H8O4S Intermediates of Dyes and Pigments