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ChemicalBook >> CAS DataBase List >>(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE

(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE

(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Structure
(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE structure
CAS No.
164931-83-3
Chemical Name:
(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE
Synonyms
(R,R)Jacbosen;(r,r)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexan;RR,R)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III)chloride;(r,r)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(iii) chloride;(R,R)-N,N'-BIs(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III) chloride;（1R,2R）-(－)-〔1，2-Cyclohexanediamino-N,N-bis(3,5-di-t-butylsalicylidene)〕chromium(Ⅲ) Chloride;(1R,2R)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)chromium(III) chloride;(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE;(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene)]chromium(III)chloride;(R,R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III) chloride Catalytic reagent
CBNumber:
CB5761982
Molecular Formula:
C36H52ClCrN2O2
Molecular Weight:
632.27
MDL Number:
MFCD02684555
MOL File:
164931-83-3.mol
Last updated:2023-04-23 13:52:06
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(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Properties

Melting point >350 °C(lit.)
form Powder
color brown

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302+H312+H332
Precautionary statements  P261-P264-P280-P301+P312-P302+P352+P312-P304+P340+P312
Hazard Codes  Xn
Risk Statements  20/21/22
Safety Statements  26-36
WGK Germany  3

(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 531944 (R,R)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III) chloride 164931-83-3 1g $85.3 2024-03-01 Buy
Sigma-Aldrich 531944 (R,R)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III) chloride 164931-83-3 5g $144.6 2024-03-01 Buy
Strem Chemicals 24-0850 (1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]chromium(III) chloride 164931-83-3 1g $64 2024-03-01 Buy
Strem Chemicals 24-0850 (1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]chromium(III) chloride 164931-83-3 5g $239 2024-03-01 Buy
American Custom Chemicals Corporation OGM0000040 (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE 95.00% 164931-83-3 1G $294 2021-12-16 Buy
Product number Packaging Price Buy
531944 1g $85.3 Buy
531944 5g $144.6 Buy
24-0850 1g $64 Buy
24-0850 5g $239 Buy
OGM0000040 1G $294 Buy

(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Chemical Properties,Uses,Production

Reactions

  1. Catalyst for the asymmetric ring-opening of meso-epoxides and for the kinetic resolution of terminal epoxides.
  2. Precatalyst for asymmetric Diels-Alder and hetero Diels-Alder reactions.
  3. Catalyst for copolymerization of CO2 and epoxides.
  4. Catalyst for enantioselective alkylation of tributyltin enolates.
  5. Enantioselective addition of Me2Zn to aldehydes.
  6. Enantioselective intramolecular addition of tertiary enamides to ketones.
  7. Asymmetric iodocyclization.
  8. Catalytic intermolecular linear allylic C-H animation.
Reactions of 164931-83-3_1
Reactions of 164931-83-3_2

Uses

Catalyst used for:

  • Asymmetric anti-Mannich reactions
  • Coupling reactions
  • Ring-opening and Diels-Alder reactions
  • Allylic C-H oxidation of terminal alkenes

(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Suppliers

Global( 51)Suppliers
Supplier Tel Email Country ProdList Advantage
CONIER CHEM AND PHARMA LIMITED 		+8618523575427 sales@conier.com China 49374 58
Zhengzhou Alfa Chemical Co.,Ltd 		+8618530059196 sale04@alfachem.cn China 11818 58
VladaChem GmbH 		+49-7246-3082843 info@vladachem.de Germany 1859 58
GIHI CHEMICALS CO.,LIMITED 		+8618058761490 info@gihichemicals.com China 49978 58
Shaoxin Catsyn Co., Ltd. 		+undefined-0575-82040869 +86-0575-82040869; sales@catsyn.com China 6114 58
LEAPCHEM CO., LTD. 		+86-852-30606658 market18@leapchem.com China 43340 58
Shanghai Acmec Biochemical Technology Co., Ltd. 		+undefined18621343501 product@acmec-e.com China 33338 58
SHANGHAI KEAN TECHNOLOGY CO., LTD. 		+8613817748580 cooperation@kean-chem.com China 40066 58
Chemwill Asia Co.,Ltd. 86-21-51086038 chemwill_asia@126.com CHINA 23912 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 94657 76
Supplier Advantage
CONIER CHEM AND PHARMA LIMITED 		58
Zhengzhou Alfa Chemical Co.,Ltd 		58
VladaChem GmbH 		58
GIHI CHEMICALS CO.,LIMITED 		58
Shaoxin Catsyn Co., Ltd. 		58
LEAPCHEM CO., LTD. 		58
Shanghai Acmec Biochemical Technology Co., Ltd. 		58
SHANGHAI KEAN TECHNOLOGY CO., LTD. 		58
Chemwill Asia Co.,Ltd. 58
J & K SCIENTIFIC LTD. 76

164931-83-3((1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE)Related Search:

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE CHROMIUM(II) CHLORIDE Chromium(III) chloride Chromium (1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE
(1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE N,N'-BIS(SALICYLIDENE)-1,6-HEXANEDIAMINE (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE N-benzylidenecyclohexylamine
N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINE N,N'-BIS(SALICYLIDENE)-1,2-PROPANEDIAMINE (R,R)-(-)-1,2-DIAMINOCYCLOHEXANE HYDROCHLORIDE CIS/TRANS-DISALYCYLIDENE-1,2-CYCLOHEXYLIDENEDIAMINE

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(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE （1R,2R）-(－)-〔1，2-Cyclohexanediamino-N,N-bis(3,5-di-t-butylsalicylidene)〕chromium(Ⅲ) Chloride (1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene)]chromium(III)chloride (r,r)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(iii) chloride (r,r)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexan Chromium,chloro[[2,2'-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-kN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-kO]](2-)]-, (SP-5-13)- (R,R)Jacbosen RR,R)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III)chloride (R,R)-N,N'-BIs(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III) chloride Catalytic reagent (R,R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III) chloride Catalytic reagent (1R,2R)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)chromium(III) chloride (R,R)-N,N'-BIs(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III) chloride 164931-83-3 Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents Cycloaddition Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents CycloadditionChiral Catalysts, Ligands, and Reagents Privileged Ligands and Complexes SALENs