D(+)-10-Camphorsulfonyl chloride
- CAS No.
- 21286-54-4
- Chemical Name:
- D(+)-10-Camphorsulfonyl chloride
- Synonyms
- Camphor-10-suL;D(+)CAMPHOR SULFONYL CHLORIDE;D-CAMPHOR-10-SULFONYL CHLORIDE;S-(+)-caMphorsulfonyl chloride;D(+)-1-CaMphorsulfonyl chloride;(+)-10-Camphorsulfonyl Chloride;(+)-CAMPHOR-10-SULFONYL CHLORIDE;D(+)-10-CAMPHORSULFONYL CHLORIDE;D-CAMPHOR-10-SULFONYL CHLORIDE 96%;Dextro-10-camphorsulfonyl chloride
- CBNumber:
- CB5775185
- Molecular Formula:
- C10H15ClO3S
- Molecular Weight:
- 250.74
- MDL Number:
- MFCD00064156
- MOL File:
- 21286-54-4.mol
- MSDS File:
- SDS
Melting point | 67-68 °C |
---|---|
Boiling point | 349.4±15.0 °C(Predicted) |
alpha | 33 º (c=1, CHCl3 22 ºC) |
Density | 1.2078 (estimate) |
refractive index | 32 ° (C=1, CHCl3) |
storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
solubility | Chloroform (Slightly), Ethyl Acetate (Slightly) |
form | Crystalline Powder |
color | Off-white to beige |
optical activity | [α]22/D +33°, c = 1 in chloroform |
Sensitive | Moisture Sensitive |
BRN | 3205974 |
InChIKey | BGABKEVTHIJBIW-UHFFFAOYSA-N |
CAS DataBase Reference | 21286-54-4(CAS DataBase Reference) |
NIST Chemistry Reference | (+)-Camphor-10-sulfonyl chloride(21286-54-4) |
UNSPSC Code | 12352115 |
NACRES | NA.22 |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS05 |
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Signal word | Danger | |||||||||
Hazard statements | H314 | |||||||||
Precautionary statements | P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363 | |||||||||
Hazard Codes | C | |||||||||
Risk Statements | 34 | |||||||||
Safety Statements | 26-36/37/39-45 | |||||||||
RIDADR | UN 3261 8/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
F | 10-21 | |||||||||
HazardClass | 8 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29147000 | |||||||||
NFPA 704 |
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D(+)-10-Camphorsulfonyl chloride price More Price(22)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 219576 | (1S)-(+)-10-Camphorsulfonyl chloride 97% | 21286-54-4 | 5g | $43.7 | 2024-03-01 | Buy |
Sigma-Aldrich | 219576 | (1S)-(+)-10-Camphorsulfonyl chloride 97% | 21286-54-4 | 25g | $159 | 2024-03-01 | Buy |
TCI Chemical | C0998 | (+)-10-Camphorsulfonyl Chloride >97.0%(GC)(T) | 21286-54-4 | 5g | $26 | 2024-03-01 | Buy |
TCI Chemical | C0998 | (+)-10-Camphorsulfonyl Chloride >97.0%(GC)(T) | 21286-54-4 | 25g | $77 | 2024-03-01 | Buy |
Sigma-Aldrich | 219576 | (1S)-(+)-10-Camphorsulfonyl chloride 97% | 21286-54-4 | 100g | $587 | 2024-03-01 | Buy |
D(+)-10-Camphorsulfonyl chloride Chemical Properties,Uses,Production
Chemical Properties
white to light yellow crystal powde
Uses
As a useful synthetic intermediate, D(+)-10-Camphorsulfonyl chloride can be used for asymmetric hydroxylation
Uses
A chiral derivative of Camphor.
Purification Methods
If free from OH bands in the IR, then recrystallise it from Et2O or pet ether; otherwise treat it with SOCl2 at 50o for 30minutes, evaporate, dry the residue over KOH in a vacuum and recrystallise it. The (±)-acid chloride has m 85o [Bartlett & Knox Org Synth 45 14 1965]. Itis characterised as the amide (prisms from EtOH) m 132o, [ ] 17 (+) and (-) 1.5o (EtOH). On repeated recrystallisation from EtOH the anilide has m 120.5-121o, [] 25 +76o (c 1, CHCl3). [Read & Storey J Chem Soc 2761 1930, Sutherland & Shriner J Am Chem Soc 58 62 1936, Halterman et al. J Am Chem Soc 109 8105 1987, Bartlet & Knox Org Synth 45 55 1945, Beilstein 11 IV 650.]
D(+)-10-Camphorsulfonyl chloride Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Zibo Hangyu Biotechnology Development Co., Ltd | +86-0533-2185556 +8615965530500 | nickzhang@hangyubiotech.com | China | 10983 | 58 |
Capot Chemical Co.,Ltd. | +86-(0)57185586718 +86-13336195806 | sales@capot.com | China | 29730 | 60 |
Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49732 | 58 |
career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29808 | 58 |
SIMAGCHEM CORP | +86-13806087780 | sale@simagchem.com | China | 17365 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34563 | 58 |
AFINE CHEMICALS LIMITED | +86-0571-85134551 | sales@afinechem.com | China | 15395 | 58 |
Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | info@dycnchem.com | China | 52849 | 58 |
CD Chemical Group Limited | +8615986615575 | info@codchem.com | China | 20342 | 58 |
View Lastest Price from D(+)-10-Camphorsulfonyl chloride manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
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2025-04-22 | D(+)-10-Camphorsulfonyl chloride
21286-54-4
|
US $1.00 / kg | 1kg | 99% | 50000kg/month | Zibo Hangyu Biotechnology Development Co., Ltd | |
![]() |
2025-04-22 | D(+)-10-Camphorsulfonyl chloride
21286-54-4
|
US $1.00 / kg | 1kg | 99% | 50000kg/month | Zibo Hangyu Biotechnology Development Co., Ltd | |
![]() |
2022-01-27 | D(+)-10-Camphorsulfonyl chloride
21286-54-4
|
US $0.00 / KG | 1KG | 98.9% | 100 tons | Honest Joy Holdings Limited
|
-
- D(+)-10-Camphorsulfonyl chloride
21286-54-4
- US $1.00 / kg
- 99%
- Zibo Hangyu Biotechnology Development Co., Ltd
-
- D(+)-10-Camphorsulfonyl chloride
21286-54-4
- US $1.00 / kg
- 99%
- Zibo Hangyu Biotechnology Development Co., Ltd
-
- D(+)-10-Camphorsulfonyl chloride
21286-54-4
- US $0.00 / KG
- 98.9%
- Honest Joy Holdings Limited