mamanine

CAS No.
60394-92-5
Chemical Name:
mamanine
Synonyms
mamanine;6-[(1S,9aβ)-Octahydro-1β-(hydroxymethyl)-2H-quinolizine-3β-yl]pyridine-2(1H)-one;2(1H)-Pyridinone, 6-[(1R,3S,9aS)-octahydro-1-(hydroxymethyl)-2H-quinolizin-3-yl]-, rel-(+)-
CBNumber:
CB61371901
Molecular Formula:
C15H22N2O2
Molecular Weight:
262.35
MDL Number:
MOL File:
60394-92-5.mol

mamanine Properties

Melting point 17l-2°C

mamanine Chemical Properties,Uses,Production

Description

This novel alkaloid occurs in the bark of Sophora chrysophylla and is obtained in the form of colourless crystals of the dihydrate which have the above melting point after prior melting at 100-4°C followed by resolidification. The base has been characterized as the crystalline cyclohexylsulphonate, m.p. 245-252°C and the diacetate which forms colourless needles that decompose on standing at room temperature. The free base is optically active with a specific rotation of [α]24.3/sup>D + 31.7° (c 2.32, EtOH). Mamaine is an intermediate in a previously unknown biogenetic pathway of the Sophora alkaloids (cf. Pohakuline).

References

Kadooka et al., Tetrahedron, 32, 919 (1976)

mamanine Preparation Products And Raw materials

Raw materials

Preparation Products

mamanine Suppliers

Global( 1)Suppliers
Supplier Tel Email Country ProdList Advantage
TargetMol Chemicals Inc.
+1-781-999-5354 support@targetmol.com United States 19973 58
Supplier Advantage
TargetMol Chemicals Inc.
58
mamanine 6-[(1S,9aβ)-Octahydro-1β-(hydroxymethyl)-2H-quinolizine-3β-yl]pyridine-2(1H)-one 2(1H)-Pyridinone, 6-[(1R,3S,9aS)-octahydro-1-(hydroxymethyl)-2H-quinolizin-3-yl]-, rel-(+)- 60394-92-5