bis(methoxycarbonyl)methylidene-imino-azanium
- CAS No.
- 6773-29-1
- Chemical Name:
- bis(methoxycarbonyl)methylidene-imino-azanium
- Synonyms
- Nsc138651;Methyl diazomalonate;Dimethyl Diazomalonate;4,5,9,11-Pyrenetetrone;Dimethyl 2-diazomalonate;Diazomalonic acid dimethyl;2-Diazomalonic acid dimethyl;Dimethyl 2-diazopropanedioate;Diazomalonic acid methyl ester;1,3-DIMETHYL 2-DIAZOPROPANEDIOATE
- CBNumber:
- CB61569881
- Molecular Formula:
- C5H7N2O4+
- Molecular Weight:
- 158.11
- MDL Number:
- MFCD16877212
- MOL File:
- 6773-29-1.mol
bis(methoxycarbonyl)methylidene-imino-azanium Chemical Properties,Uses,Production
Synthesis Reference(s)
Synthetic Communications, 17, p. 1709, 1987 DOI: 10.1080/00397918708063988
Synthesis, p. 658, 1971 DOI: 10.1055/s-1971-21790
Synthesis
The Preparative Method of Dimethyl Diazomalonate: diazomalonates are generally prepared by diazo transfer reaction of malonates and sulfonyl azides. A recent modification employs polystyrene-supported trialkylammonium azide (generated in situ) under phase-transfer catalysis conditions and allows for facile isolation.
Precautions
Dimethyl diazomalonate has been utilized more extensively than has diethyl diazomalonate due to the explosion hazard of the latter. Nonetheless, care should be taken in the preparation and handling of dimethyl diazomalonate. Storage at low temperatures is recommended. The decomposition of dimethyl diazomalonate evolves nitrogen and can result in high pressures.
bis(methoxycarbonyl)methylidene-imino-azanium Preparation Products And Raw materials
Raw materials
Preparation Products
bis(methoxycarbonyl)methylidene-imino-azanium Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Chembon Pharmaceutical Co., Ltd. | +86-28-8425-2981 | CHINA | 722 | 55 | |
| Henan Alfa Chemical Co., Ltd | China | 12005 | 58 | ||
| Wuhan Topule Biopharmaceutical Co., Ltd | +8618327326525 | masar@topule.com | China | 8467 | 58 |
| Shanghai Acmec Biochemical Technology Co., Ltd. | +86-18621343501; +undefined18621343501 | product@acmec-e.com | China | 33338 | 58 |
| Aladdin Scientific | +1-+1(833)-552-7181 | sales@aladdinsci.com | United States | 57505 | 58 |
| SHANGHAI KEAN TECHNOLOGY CO., LTD. | +8613817748580 | cooperation@kean-chem.com | China | 40066 | 58 |
| XIAMEN AMITY INDUSTRY AND TRADE CO., LTD. | +8618950047208 | ellena@amitychem.com | China | 43416 | 58 |
| BeiJing Hwrk Chemicals Limted | 0757-86329057 18934348241 | sales4.gd@hwrkchemical.com | China | 14063 | 55 |
| Chembon Pharmaceutical Co., Ltd. | 028-84252981 | sales@chembon.com.cn | China | 814 | 64 |
| Shanghai AmasPharm Co., Ltd. | 021-54540637 18621091017 | sales@amaspharm.com | China | 751 | 62 |