ChemicalBook >> CAS DataBase List >>1-Ethylpiperidine

1-Ethylpiperidine

CAS No.
766-09-6
Chemical Name:
1-Ethylpiperidine
Synonyms
N-ETHYLPIPERIDINE;Ethylpiperidine;Piperidine, 1-ethyl-;NSC 2090;N-Ethylpiperidin;1-Ethylpiperidin;1-Ethylpiperidene;1-ethvlpiperidine;1-ETHYLPIPERIDINE;N-Aethylpiperidin
CBNumber:
CB6208602
Molecular Formula:
C7H15N
Molecular Weight:
113.2
MDL Number:
MFCD00006507
MOL File:
766-09-6.mol
MSDS File:
SDS
Last updated:2023-05-04 17:34:42

1-Ethylpiperidine Properties

Melting point -20 °C
Boiling point 131 °C(lit.)
Density 0.824 g/mL at 25 °C(lit.)
vapor pressure 12.76hPa at 20℃
refractive index n20/D 1.444(lit.)
Flash point 66 °F
storage temp. Flammables area
solubility 1-ethylpiperidine salt of benzylpenicillin is considerably less soluble in amyl acetate and acetone.
pka 10.45(at 23℃)
form Liquid
color Clear colorless to slightly yellow
PH 12.2 (50g/l, H2O, 20℃)
explosive limit 1.9-12.1%(V)
Water Solubility 50 G/L
BRN 102643
LogP 1.89 at 25℃
CAS DataBase Reference 766-09-6(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 7IE43L0926
NIST Chemistry Reference Piperidine, 1-ethyl-(766-09-6)
EPA Substance Registry System Piperidine, 1-ethyl- (766-09-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05,GHS06
Signal word  Danger
Hazard statements  H225-H301+H331-H312-H314
Precautionary statements  P210-P233-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  F,Xn
Risk Statements  11-20/22-36/37/38
Safety Statements  26-36/37/39
RIDADR  UN 2386 3/PG 2
WGK Germany  1
RTECS  TN0250000
10-23
TSCA  Yes
HazardClass  3
PackingGroup  II
HS Code  29333990
NFPA 704
0
0 0

1-Ethylpiperidine price More Price(9)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich E45708 1-Ethylpiperidine 99% 766-09-6 100ml $39.7 2024-03-01 Buy
Sigma-Aldrich E45708 1-Ethylpiperidine 99% 766-09-6 500ml $114 2024-03-01 Buy
TCI Chemical E0166 1-Ethylpiperidine >98.0%(GC)(T) 766-09-6 25mL $39 2024-03-01 Buy
TCI Chemical E0166 1-Ethylpiperidine >98.0%(GC)(T) 766-09-6 500mL $298 2024-03-01 Buy
Alfa Aesar A16294 1-Ethylpiperidine, 99% 766-09-6 500g $98.65 2024-03-01 Buy
Product number Packaging Price Buy
E45708 100ml $39.7 Buy
E45708 500ml $114 Buy
E0166 25mL $39 Buy
E0166 500mL $298 Buy
A16294 500g $98.65 Buy

1-Ethylpiperidine Chemical Properties,Uses,Production

Chemical Properties

CLEAR COLOURLESS TO SLIGHTLY YELLOWISH LIQUID

Uses

Reactant for: Synthesis of multiprotected kanosamine1 Selective acylation in peptide synthesis2Reagent for: Stereoselective aldol condensation reactions for synthesis of β-lactam antibiotics3 Diastereoselective synthesis of aldols4 Crossed Claisen ester condensation5

Uses

In Room temperature phosphorescence of α-bromonaphthalene induced by cyclodextrin in the presence of hexahydropyridine or 1-ethylpiperidine and its application is described. The highest yields of 5-Bromopyrimidine (37%) were obtained by using 1-ethylpiperidine or triethylamine as condensing agent. Tributyltin hydride and 1-ethylpiperidine hypophosphite were mediated intermolecular radical additions to 2, 4, 6-trichlorophenyl vinyl sulfonate.

Definition

ChEBI: N-ethylpiperidine is a member of piperidines.

Synthesis Reference(s)

Organic Syntheses, Coll. Vol. 5, p. 575, 1973
The Journal of Organic Chemistry, 28, p. 3259, 1963 DOI: 10.1021/jo01046a537

General Description

A colorless liquid with the odor of pepper. Less dense than water. Flash point 66°F. May irritate skin and eyes. Vapors heavier than air. Used as a solvent and to make other chemicals.

Air & Water Reactions

Highly flammable. Soluble in water.

Reactivity Profile

1-Ethylpiperidine neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Health Hazard

May cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Flammability and Explosibility

Highly flammable

Safety Profile

Poison by intravenous and subcutaneous routes. An eye irritant. A very dangerous fire hazard when exposed to heat or flame; can react vigorously with oxidizing materials. When heated to decomposition it emits toxic fumes of Nox.

618-42-8
766-09-6
Synthesis of 1-Ethylpiperidine from 1-ACETYLPIPERIDINE
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View Lastest Price from 1-Ethylpiperidine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1-Ethylpiperidine pictures 2020-01-10 1-Ethylpiperidine
766-09-6
US $9.80 / KG 1g ≥99% 100kg Career Henan Chemical Co
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