ChemicalBook >> CAS DataBase List >>13,14-Dihydro-2',14β-dihydroxy-4'',5''-dimethoxylythran-12-one

13,14-Dihydro-2',14β-dihydroxy-4'',5''-dimethoxylythran-12-one

13,14-Dihydro-2',14β-dihydroxy-4'',5''-dimethoxylythran-12-one structure

CAS No.: 15299-77-1

Chemical Name:: 13,14-Dihydro-2',14β-dihydroxy-4'',5''-dimethoxylythran-12-one

Synonyms: Sinine;Lythridine;13,14-Dihydro-2',14β-dihydroxy-4'',5''-dimethoxylythran-12-one;13,14-Dihydro-2',14β-dihydroxy-4'',5''-dimethoxylythran-12-one;20H-6,20-Methano-11,15-metheno-1H,8H-benzo[g]pyrido[2,1-d][1,5]oxaazacyclohexadecin-8-one, 2,3,4,4a,5,6,9,10-octahydro-10,14-dihydroxy-17,18-dimethoxy-, stereoisomer

CBNumber:: CB62350680

Molecular Formula:: C26H31NO6

Molecular Weight:: 453.53

MDL Number:

MOL File:: 15299-77-1.mol

Last updated:2023-05-21 10:59:17

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13,14-Dihydro-2',14β-dihydroxy-4'',5''-dimethoxylythran-12-one Properties

Melting point	218-9°C
storage temp.	Store at -20°C
solubility	DMF: 20 mg/ml; DMSO: 20 mg/ml; Ethanol: 1 mg/ml
form	A crystalline solid

13,14-Dihydro-2',14β-dihydroxy-4'',5''-dimethoxylythran-12-one price More Price(2)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Cayman Chemical	25865	Lythridine ≥98%	15299-77-1	1mg	$121	2024-03-01	Buy
Cayman Chemical	25865	Lythridine ≥98%	15299-77-1	5mg	$543	2024-03-01	Buy

Product number	Packaging	Price	Buy
25865	1mg	$121	Buy
25865	5mg	$543	Buy

13,14-Dihydro-2',14β-dihydroxy-4'',5''-dimethoxylythran-12-one Chemical Properties,Uses,Production

Description

Both Heirnia rnyritifolia Cham. et Schl. and H. salicifolia Link & Otto yield this macrocyc1ic alkaloid which may be crystallized from a mixture of AcOEt, MeOH and light petroleum as glistening needles. Two somewhat different values for the specific rotation have been recorded, viz. [α]²⁵_D - 174.2° (c 0.3325, CHC13) by Blomster and [α]²⁵_D - 153.4° (c 0.3, CHCI3) by Douglas. The ultraviolet spectrum exhibits a broad absorption maximum at 292 mil and an inflexion at 250 mil. Two methoxyl groups, a secondary and a phenolic hydroxyl group are present. The hydrochloride yields colourless crystals from MeOH, m.p. 330°C (dec.). The structure has been determined mainly from the infrared and mass spectra.

References

Douglas et ai., L/oydia, 27, 25 (1964) Blomster, Schwarting, Bobbitt., ibid, 27, 15 (1964) Absolute configuration: Chu et ai., Chern. Ind., 1795 (1966) Mass spectrum: Appel, Achenbach., Tetrahedron Lett., 5789 (1966) Structure: Ferris, Boyce, Briner., J. Arner. Chern. Soc., 93, 2942 (1971) Ferris et ai., ibid, 93, 2963 (1971)

13,14-Dihydro-2',14β-dihydroxy-4'',5''-dimethoxylythran-12-one Preparation Products And Raw materials

Raw materials

Preparation Products

13,14-Dihydro-2',14β-dihydroxy-4'',5''-dimethoxylythran-12-one Suppliers

Global( 3)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shanghai Hongye Biotechnology Co. Ltd	400-9205774	sales@glpbio.cn	China	6870	58
Shanghai Yifei Biotechnology Co. , Ltd.	021-65675885 18964387627	customer_service@efebio.com	China	8739	58

Supplier	Advantage
Shanghai Hongye Biotechnology Co. Ltd	58
Shanghai Yifei Biotechnology Co. , Ltd.	58

13,14-Dihydro-2',14β-dihydroxy-4'',5''-dimethoxylythran-12-one Lythridine Sinine 20H-6,20-Methano-11,15-metheno-1H,8H-benzo[g]pyrido[2,1-d][1,5]oxaazacyclohexadecin-8-one, 2,3,4,4a,5,6,9,10-octahydro-10,14-dihydroxy-17,18-dimethoxy-, stereoisomer 13,14-Dihydro-2',14β-dihydroxy-4'',5''-dimethoxylythran-12-one 15299-77-1