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5,10-tetraMethylindeno[2,1-a]indene

CAS No.
89057-44-3
Chemical Name:
5,10-tetraMethylindeno[2,1-a]indene
Synonyms
5,10-tetraMethylindeno[2,1-a]indene;1,2,5,10-Tetramethylindeno[2,1-a]indene;5,5,10,10-tetramethyl-Inden[2,1-a]Indene;5,5,10,10-tetramethylindeno[2,1-a]indene;5,5,10,10-TetraMethyl-5,10-dihydroindeno<2,1-a>inden;5,5,10,10-Tetramethyl-5,10-dihydroindeno[2,1-a]indene;Indeno[2,1-a]indene, 5,10-dihydro-5,5,10,10-tetramethyl-
CBNumber:
CB62640396
Molecular Formula:
C20H20
Molecular Weight:
260.37
MDL Number:
MFCD26403658
MOL File:
89057-44-3.mol
Last updated:2025-07-24 18:13:54

5,10-tetraMethylindeno[2,1-a]indene Properties

Melting point 214℃
Boiling point 343.6±42.0 °C(Predicted)
Density 1.10±0.1 g/cm3 (20 ºC 760 Torr)
storage temp. Sealed in dry,Room Temperature

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H317-H319
Precautionary statements  P280-P305+P351+P338

5,10-tetraMethylindeno[2,1-a]indene price

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
American Custom Chemicals Corporation CHM0390496 5,5,10,10-TETRAMETHYL-5,10-DIHYDROINDENO[2,1-A]INDENE 95.00% 89057-44-3 5MG $496.41 2021-12-16 Buy
AK Scientific 5743CU 5,5,10,10-Tetramethyl-5,10-dihydroindeno[2,1-a]indene 89057-44-3 1g $1835 2021-12-16 Buy
Crysdot CD43000055 5,5,10,10-Tetramethyl-5,10-dihydroindeno[2,1-a]indene 95+% 89057-44-3 1g $1129 2021-12-16 Buy
Alichem 89057443 5,5,10,10-Tetramethyl-5,10-dihydroindeno[2,1-a]indene 89057-44-3 1g $1244.16 2021-12-16 Buy
Arctom SY148053 5,5,10,10-Tetramethyl-5,10-dihydroindeno[2,1-a]indene ≥95% 89057-44-3 1g $1315 2021-12-16 Buy
Product number Packaging Price Buy
CHM0390496 5MG $496.41 Buy
5743CU 1g $1835 Buy
CD43000055 1g $1129 Buy
89057443 1g $1244.16 Buy
SY148053 1g $1315 Buy

5,10-tetraMethylindeno[2,1-a]indene Chemical Properties,Uses,Production

Synthesis

INDENO[2,1-A]INDENE,5,10-DIHY

6543-29-9

Iodomethane

74-88-4

5,10-tetraMethylindeno[2,1-a]indene

89057-44-3

At about -78 °C, 2.04 g (10 mmol) of 5,10-tetrahydrodianaphthene (Intermediate I-3) and 37.5 mL (60 mmol) of n-butyllithium (1.60 M hexane solution) were gradually reacted in tetrahydrofuran. Subsequently, 3.8 mL (60 mmol) of iodomethane was added and the reaction mixture was stirred at room temperature for about 3 hours. Upon completion of the reaction, 5 mL of aqueous 1N hydrochloric acid was added to the mixture to quench the reaction. The organic phase was separated and the aqueous phase was extracted with dichloromethane (2 x 100 mL). The organic phases were combined and dried over magnesium sulfate, followed by evaporation of the solvent. The residue was separated and purified by silica gel column chromatography to afford 2.03 g of 5,10-tetramethyldiindene (Intermediate I-4) in 78% yield. The compound was characterized by mass spectrometry/fast atom bombardment mass spectrometry (MS/FAB). The calculated molecular weight of the molecular formula C20H20 was 260.37 and the measured value was 260.45.

References

[1] Patent: US2014/27721, 2014, A1. Location in patent: Paragraph 0127; 0131
[2] Patent: KR2016/56315, 2016, A. Location in patent: Paragraph 0197; 0198; 0205; 0206
[3] Patent: US9537104, 2017, B2. Location in patent: Page/Page column 77; 78; 79
[4] Patent: US2017/12205, 2017, A1. Location in patent: Paragraph 0223; 0230;0321

5,10-tetraMethylindeno[2,1-a]indene Preparation Products And Raw materials

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5,10-tetraMethylindeno[2,1-a]indene 5,5,10,10-TetraMethyl-5,10-dihydroindeno<2,1-a>inden 1,2,5,10-Tetramethylindeno[2,1-a]indene 5,5,10,10-Tetramethyl-5,10-dihydroindeno[2,1-a]indene 5,5,10,10-tetramethylindeno[2,1-a]indene 5,5,10,10-tetramethyl-Inden[2,1-a]Indene Indeno[2,1-a]indene, 5,10-dihydro-5,5,10,10-tetramethyl- 89057-44-3