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ChemicalBook >> CAS DataBase List >>[1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene][1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN]gold

[1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene][1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN]gold

[1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene][1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN]gold Structure
[1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene][1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN]gold structure
CAS No.
951776-24-2
Chemical Name:
[1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene][1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN]gold
Synonyms
)imide]g;IPrAuNTf2;)imide]goL;idene][bis(trifL;1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidenegold(I) bis(trifluoromethanesulfonyl)imide;1,3-Bis(2,6-di-i-propylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(I);[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(I);[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene] [bis(trifluoromethanesulfonyl)imide]gold(I);[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE][BIS(TRIFLUOROMETHANESULFONYL)IMIDE]GOLD(I),MIN.95%;[1,3-Bis(2,6-di-i-propylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(I), min. 95%
CBNumber:
CB62750868
Molecular Formula:
C29H36AuF6N3O4S2
Molecular Weight:
865.7
MDL Number:
MFCD22572651
MOL File:
951776-24-2.mol
MSDS File:
SDS
Last updated:2023-06-27 19:29:00
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[1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene][1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN]gold Properties

Melting point 202-287°C (decomposition)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form solid
color white to pale yellow
Sensitive air sensitive

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26
WGK Germany  3

[1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene][1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN]gold price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 753343 [1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene] [bis(trifluoromethanesulfonyl)imide]gold(I) 95% 951776-24-2 100mg $45.6 2024-03-01 Buy
Sigma-Aldrich 753343 [1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene] [bis(trifluoromethanesulfonyl)imide]gold(I) 95% 951776-24-2 500mg $261 2024-03-01 Buy
Strem Chemicals 79-0245 [1,3-Bis(2,6-di-i-propylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(I), min. 95% 951776-24-2 100mg $64 2024-03-01 Buy
Strem Chemicals 79-0245 [1,3-Bis(2,6-di-i-propylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(I), min. 95% 951776-24-2 500mg $250 2024-03-01 Buy
Arctom AS624114 [1,3-Bis(2,6-di-i-propylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(I) 98% 951776-24-2 1g $325 2021-12-16 Buy
Product number Packaging Price Buy
753343 100mg $45.6 Buy
753343 500mg $261 Buy
79-0245 100mg $64 Buy
79-0245 500mg $250 Buy
AS624114 1g $325 Buy

[1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene][1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN]gold Chemical Properties,Uses,Production

Reaction

  1. Gold catalyst used for the hydroarylating cyclization of 1,2-bis(2-iodoethynyl)benzenes.
  2. Gold catalyst used for the carbocyclization of phenols with a terminal alkyne.
  3. Intermolecular C-H activation through the gold(I)-catalyzed reaction of iodoalkynes.
  4. Reaction of ynamide with benzyl azides.
Reactions of 951776-24-2_1
Reactions of 951776-24-2_2

Uses

Selective Au(I) catalyst for hydroaminations.

[1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene][1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN]gold Preparation Products And Raw materials

Raw materials

Preparation Products

[1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene][1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN]gold Suppliers

Global( 28)Suppliers
Supplier Tel Email Country ProdList Advantage
Hangzhou MolCore BioPharmatech Co.,Ltd. 		+86-057181025280; +8617767106207 sales@molcore.com China 49734 58
Aladdin Scientific 		+1-+1(833)-552-7181 sales@aladdinsci.com United States 52925 58
Beijing HwrkChemical Technology Co., Ltd 010-89508211 18501085097 sales.bj@hwrkchemical.com China 8415 55
Bide Pharmatech Ltd. 400-164-7117 13681763483 product02@bidepharm.com China 41462 60
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51456 80
Alfa Chemistry 1-516-6625404 support@alfa-chemistry.com United States 9171 60
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. 0371-65511006 18625597674 sales@kingorgchem.com China 953 55
LaaJoo 021-60702684 18516024827 huang.jiayi@sinocompound.com China 2654 58
Jiaxing Deyi Chemical Co., Ltd. 0573-86-0573-85866609 13325730825 945717149@qq.com China 8026 58
Aikon International Limited 025-66113011 18112977050 sales01@aikonchem.com China 16027 58
Supplier Advantage
Hangzhou MolCore BioPharmatech Co.,Ltd. 		58
Aladdin Scientific 		58
Beijing HwrkChemical Technology Co., Ltd 55
Bide Pharmatech Ltd. 60
Sigma-Aldrich 80
Alfa Chemistry 60
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. 55
LaaJoo 58
Jiaxing Deyi Chemical Co., Ltd. 58
Aikon International Limited 58
[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene] [bis(trifluoromethanesulfonyl)imide]gold(I) [1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(I) [1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene][1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN]gold IPrAuNTf2 [1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE][BIS(TRIFLUOROMETHANESULFONYL)IMIDE]GOLD(I),MIN.95% )imide]goL (1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene)((1,1,1-trifluoro-N-((trifluoromethyl)sulfonyl)methyl)sulfonamido)gold(I) [1,3-Bis(2,6-di-i-propylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(I), min. 95% 1,3-Bis(2,6-di-i-propylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(I) 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidenegold(I) bis(trifluoromethanesulfonyl)imide )imide]g idene][bis(trifL 951776-24-2 C29H36AuF6N3O4S2 AuC2F6NO4S2C27H36N2