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Lithium bis(trifluoromethanesulphonyl)imide

Lithium bis(trifluoromethanesulphonyl)imide structure

CAS No.: 90076-65-6

Chemical Name:: Lithium bis(trifluoromethanesulphonyl)imide

Synonyms: LITFSI;LITHIUM BIS(TRIFLUOROMETHANESULFONYL)IMIDE;LITHIUM BIS(TRIFLUOROMETHANESULFONIMIDE);LiTFSA;LithiuM bis;BISTRIFLUOROMETHANESULFONIMIDE LITHIUM SALT;LiN（SO2CF3）2;LITHIUM TRIFLUOROMETHANESULFONIMIDE;Bistrifluoromethanesulfonimide lithium;LITHIUM BIS(TRIFLUOROMETHANESULFONYL)AMIDE

CBNumber:: CB6311504

Molecular Formula:: C2F6LiNO4S2

Molecular Weight:: 287.09

MDL Number:: MFCD00210017

MOL File:: 90076-65-6.mol

MSDS File:: SDS

Last updated:2024-11-06 18:33:45

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Lithium bis(trifluoromethanesulphonyl)imide Properties

Melting point	234-238 °C(lit.)
Density	1,334 g/cm³
vapor pressure	0Pa at 25℃
Flash point	>100°C (>212°F)
storage temp.	Inert atmosphere,Room Temperature
solubility	H₂O: 10 mg/mL, clear, colorless
form	Hygroscopic Powder
Specific Gravity	1.334
color	White
Water Solubility	Soluble in water.
Sensitive	Moisture Sensitive
BRN	6625414
InChIKey	QSZMZKBZAYQGRS-UHFFFAOYSA-N
LogP	-1.46
CAS DataBase Reference	90076-65-6(CAS DataBase Reference)
FDA UNII	9Y730392A5
EPA Substance Registry System	Methanesulfonamide, 1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]-, lithium salt (90076-65-6)
Boiling point	234-238?°C (lit.)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS05,GHS06,GHS08

Signal word

Danger

Hazard statements

H301+H311-H314-H373-H412

Precautionary statements

P260-P273-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338

Hazard Codes

T,C

Risk Statements

24/25-34-52/53-48/22

Safety Statements

22-26-36/37/39-45-61

RIDADR

UN 2923 8/PG 2

WGK Germany

Hazard Note

Harmful/Corrosive/Moisture Sensitive

TSCA

Yes

HazardClass

PackingGroup

HS Code

29309090

NFPA 704

	1
3		0

Lithium bis(trifluoromethanesulphonyl)imide price More Price(32)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	449504	Bis(trifluoromethane)sulfonimide lithium salt	90076-65-6	250G	$1280	2024-03-01	Buy
Sigma-Aldrich	15224	Bis(trifluoromethane)sulfonimide lithium salt puriss., ≥99.0% (19F-NMR)	90076-65-6	10G	$126	2024-03-01	Buy
Sigma-Aldrich	15224	Bis(trifluoromethane)sulfonimide lithium salt puriss., ≥99.0% (19F-NMR)	90076-65-6	50G	$326	2024-03-01	Buy
TCI Chemical	B2542	Lithium Bis(trifluoromethanesulfonyl)imide >98.0%(T)	90076-65-6	25g	$87	2024-03-01	Buy
TCI Chemical	B2542	Lithium Bis(trifluoromethanesulfonyl)imide	90076-65-6	5G	$26	2021-12-16	Buy

Product number	Packaging	Price	Buy
449504	250G	$1280	Buy
15224	10G	$126	Buy
15224	50G	$326	Buy
B2542	25g	$87	Buy
B2542	5G	$26	Buy

Lithium bis(trifluoromethanesulphonyl)imide Chemical Properties,Uses,Production

Description

Lithium bis(trifluoromethylsulphonyl)imide (LiTFSI) is normally used as a p-dopant to enhance the conductivity and hole mobility of the Spiro-OMeTAD for perovskite solar cells. It is believed that The function of LiTFSI in PSCs is similar to that in solid-state dye-sensitised solar cells.

Chemical Properties

White hygroscopic powder

Uses

Lithium bis(trifluoromethylsulfonyl)imide is used in the preparation of chiral imidazolium salt through an anion metathesis of the corresponding triflate organic electrolyte-based lithium batteries. It finds application in the preparation of rare-earth Lewis acid catalysts. It is also useful in primary and secondary lithium cells using organic liquid electrolytes and polymer batteries.

General Description

Bis(trifluoromethane)sulfonimide lithium salt is a synthetic reagent.

Flammability and Explosibility

Non flammable

Synthesis

5.91 g of anhydrous lithium fluoride and N-butyl-bistrifluoromethylsulfonimide 51.26 g. Add to 250 g of isopropyl acetate and reflux for 10 hours. It was filtered after being cooled to room temperature, and the filtrate was concentrated to dryness under reduced pressure.200 g of dichloromethane was added dropwise, and the mixture was stirred at 20 ° C for 2 hours and then filtered. Wash with dichloromethane. The filter cake was dried at 80 ° C to obtain 39.57 g of Lithium bis(trifluoromethanesulphonyl)imide. The yield is 90.7%.

Properties and Applications

Lithium bis(trifluoromethanesulphonyl)imide (LiTFSI) is a hydrophilic organic salt with many uses in electric and electronic systems. Its bis(trifluoromethane)sulfonimide anion, often called bistriflimide, is helpful in coordinating weakly with cations. LiTFSI's other important property is its extremely high solubility in water: 21 molal or ≈6 kg/L of solution. LiTFSI is safer than the formerly used salt, lithium hexafluorophosphate (LiPF6). To improve the cells' ability to transport electrical charges, researchers are doped with a combination of LiTFSI and a semiconductor called Spiro-OMeTAD1; however, this process is extremely slow. Taylor and his fellow researchers solved the problem by bubbling carbon dioxide into a solution of spiro-OMeTAD and LiTFSI while irradiating the mixture with ultraviolet light. They then cast a film from the solution onto the perovskite light absorber. The process can be completed in ≈1 minute, compared with the older, hours-long doping procedure.

Lithium bis(trifluoromethanesulphonyl)imide Preparation Products And Raw materials

Raw materials

Preparation Products

1-ETHYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE 1-BUTYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOR TRIHEXYL(TETRADECYL)PHOSPHONIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE 1-BUTYL-3-METHYLPYRIDINIUM BIS(TRIFLUORM 1-DODECYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE

ETHYL-DIMETHYL-PROPYLAMMONIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE TETRAMETHYLAMMONIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE 1,2-Dimethyl-3-octyl-1H-imidazolium salt with 1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamide

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Lithium bis(trifluoromethanesulphonyl)imide Suppliers

Global( 511)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Jinan Finer Chemical Co., Ltd	+86-531-88989536 +86-15508631887	sales@finerchem.com	China	2963	58
JIANGXI TIME PHARMACEUTICAL CO.,LTD	+86-0794-7183888 +86-13155888520	sales@groupchem.com	China	27	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21634	55
Hebei Brisk New Material Technology Co. , Ltd.	+8613393045540	yilia@brisknm.com	China	99	58
Aladdin Scientific	+1-+1(833)-552-7181	sales@aladdinsci.com	United States	57505	58
HebeiShuoshengImportandExportco.,Ltd	+86-18532138899 +86-18532138899	L18532138899@163.com	China	939	58
Hebei Weibang Biotechnology Co., Ltd	+8615531157085	abby@weibangbio.com	China	8810	58
Shaanxi Dideu Medichem Co. Ltd	+86-29-81148696 +86-15536356810	1022@dideu.com	China	3882	58
Hebei Yanxi Chemical Co., Ltd.	+8617531190177	peter@yan-xi.com	China	5857	58
Shanghai UCHEM Inc.	+862156762820 +86-13564624040	sales@myuchem.com	China	7514	58

Supplier	Advantage
Jinan Finer Chemical Co., Ltd	58
JIANGXI TIME PHARMACEUTICAL CO.,LTD	58
Henan Tianfu Chemical Co.,Ltd.	55
Hebei Brisk New Material Technology Co. , Ltd.	58
Aladdin Scientific	58
HebeiShuoshengImportandExportco.,Ltd	58
Hebei Weibang Biotechnology Co., Ltd	58
Shaanxi Dideu Medichem Co. Ltd	58
Hebei Yanxi Chemical Co., Ltd.	58
Shanghai UCHEM Inc.	58

Lithium Bis(trifluoromethanesulphonyl)imide: Applications in Battery Technologies and Toxicity
Lithium bis(trifluoromethanesulfonyl)imide, often simply referred to as LiTFSI, is a hydrophilic salt with the chemical formul....
Oct 28，2024

The brief introduction of Lithium bis(trifluoromethanesulfonimide)
Lithium bis(trifluoromethanesulfonimide) is an organic compound with the chemical formula C2F6LiNO4S2
Apr 20，2022

View Lastest Price from Lithium bis(trifluoromethanesulphonyl)imide manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-11-28	Lithium bis(trifluoromethanesulphonyl)imide 90076-65-6	US $99.00-80.00 / ton	1ton	99%	5000	HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
2024-11-28	Lithium bis(trifluoromethanesulphonyl)imide 90076-65-6	US $6.00 / kg	1kg	99%	2000KG/Month	HebeiShuoshengImportandExportco.,Ltd
2024-11-28	Lithium bis(trifluoromethanesulphonyl)imide 90076-65-6	US $60.00 / kg	1kg	99%	5000kg/week	Hebei Zhuanglai Chemical Trading Co.,Ltd

Lithium bis(trifluoromethanesulphonyl)imide
90076-65-6
US $99.00-80.00 / ton
99%
HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD

Lithium bis(trifluoromethanesulphonyl)imide
90076-65-6
US $6.00 / kg
99%
HebeiShuoshengImportandExportco.,Ltd

Lithium bis(trifluoromethanesulphonyl)imide
90076-65-6
US $60.00 / kg
99%
Hebei Zhuanglai Chemical Trading Co.,Ltd

Lithium bis(trifluoromethanesulphonyl)imide Spectrum

Lithium bis(trifluoromethanesulphonyl)imide(90076-65-6)¹³CNMR Lithium bis(trifluoromethanesulphonyl)imide(90076-65-6)¹⁹FNMR Lithium bis(trifluoromethanesulphonyl)imide(90076-65-6)IR Lithium bis(trifluoromethanesulphonyl)imide(90076-65-6)FT-IR

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DIALIFOS Lithium Sulfamide

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Lithium bis(trifluoromethanesulfonyl)imide ,98.5% Bis(trifluoromethane)sulfonimide lithium salt,Bis(trifluoromethylsulfonyl)amine lithium salt, Lithium bistrifluoromethanesulfonimidate LithiuM bis(trifluor bistrifluoroMethanesulfoniMidate LithiuM-bis(frifluoroMethanesulfonyl)iMlde Lithium bis(trifluoromethanesulfonyl)imide ,98% LiNTF2(LiTFSI) Bis(trifluoroMethane)sulfoniMide lithiuM salt 99.95% trace Metals basis Bis(trifluoroMethane)sulfoniMide lithiuM salt puriss., >=99.0% (19F-NMR) Trifluoromethanesulfonimide Lithium Salt, TFSILi Bis(trifluoromethane)sulfonimide lithium salt≥ 99.95% Lithium Triflimide Lithium Bis(trifluoromethane)sulfonimide lithium salt N-LITHIOTRIFLUOROMETHANESULFONIMIDE lithiumbis(trifluoromethylsulfonyl)imide Methanesulfonamide,1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]-,lithiumsalt Lithium bis(trifluoromethylsulfonyl)imide, 98+% Lithium bis(trifluoromethanesulphonyl)imide 99% Lithiumbis(trifluoromethanesulphonyl)imide99% 1,1,1-Trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfon amide lithium salt Bis(trifluoromethylsulfonyl)amine lithium salt, Lithium bistrifluoromethanesulfonimidate BIS(TRIFLUOROMETHYLSULFONYL)AMINE LITHIUM SALT BIS(TRIFLUOROMETHANESULFONYL)IMIDE LITHIUM SALT LITHIUM BISTRIFLUOROMETHANESULFONIMIDATE LITHIUM BIS(TRIFLUOROMETHANESULPHONYL)IMIDE Lithium bis(trifluoromethanesulfonimide),99% Lithium bis(trifluoromethansulfon)imide 1,1,1-trifluoro-n-[(trifluoromethyl)sulfonyl]-methanesulfonamidlithiumsalt Bis[(trifluoromethyl)sulfonyl]imide lithium salt Lithium bis(trifluoromethanesulphonyl)imide Factory Bis(trifluoromethylsulfonyl)amine lithium salt Factory Lithium bis(trifluoromethanesulphonyl)imide COA Lithium Bis(trifluoromethanesulfonyl)imide > Lithium bis(trifluoromethanesulphonyl)imide>98% Li[(CF3SO2)2N]LiTFSI bis trifluoromethane sulfonyl amine lithium Lithium bis(trifluoromethanesulphonyl)imide (LiTFSI) ithium Bis(trifL Bistrifluoromethanesulfonimide lithium salt (LiTFSi) JACS-90076-65-6 Methanesulfonamide, 1,1,1-trifluoro-N-[ (trifluoromethyl)sulfonyl]-, lithium salt (1:1) LiTFSI(Lithiumbis(trifluoromethanesulfonyl)imide) LiTFSi/Lithium bis(trifluoromethanesulphonyl)imide Lithiumbis(trifluoromethanesulph Bis(trifluoromethane)sulphonimide lithium salt, 99.95% Lithium triflimide, 99%+ Bis(trifluoromethane)sulphonimide lithium salt LithiuM bis lithiuM bis((trifluoroMethyl)sulfonyl)aMide LITFSI bis(Trifluoromethanesulphonyl)imide, lithium salt Bis(trifluoromethane)sulfonimide lithium salt, 99.95% metals basis BISTRIFLUOROMETHANESULFONIMIDE LITHIUM SALT LITHIUM TRIFLUOROMETHANESULFONIMIDE LITHIUM BIS(TRIFLUOROMETHANESULFONIMIDE) LITHIUM BIS(TRIFLUOROMETHANESULFONYL)IMIDE LITHIUM BIS(TRIFLUOROMETHANESULFONYL)AMIDE Bistrifluoromethanesulfonimide lithium