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2-(trimethylsilyl)-2-cyclohexen-1-one

2-(trimethylsilyl)-2-cyclohexen-1-one Structure
2-(trimethylsilyl)-2-cyclohexen-1-one structure
CAS No.
72162-99-3
Chemical Name:
2-(trimethylsilyl)-2-cyclohexen-1-one
Synonyms
2-(trimethylsilyl)-2-cyclohexen-1-one;2-Cyclohexen-1-one, 2-(trimethylsilyl)-
CBNumber:
CB63150920
Molecular Formula:
C9H16OSi
Molecular Weight:
168.31
MDL Number:
MFCD11502410
MOL File:
72162-99-3.mol
Last updated:2023-04-23 13:52:06
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2-(trimethylsilyl)-2-cyclohexen-1-one Properties

Melting point 40-41.5 °C(Solv: ligroine (8032-32-4))
Boiling point 206.2±39.0 °C(Predicted)
Density 0.8680 g/mL at 25 °C
refractive index n20/D1.4524
Flash point -9℃
storage temp. -20°C
form liquid

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07
Signal word  Warning
Hazard statements  H228-H302
Precautionary statements  P210-P301+P312+P330-P370+P378
RIDADR  UN1325 - class 4.1 - PG 3 - Flammable solids, organic, n.o.s., HI: all

2-(trimethylsilyl)-2-cyclohexen-1-one price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich T293024 2-(TRIMETHYLSILYL)-2-CYCLOHEXEN-1-ONE AldrichCPR 72162-99-3 100MG $110 2024-03-01 Buy
Sigma-Aldrich 805041 2-(trimethylsilyl)-2-cyclohexen-1-one 72162-99-3 500mg $65.2 2024-03-01 Buy
Product number Packaging Price Buy
T293024 100MG $110 Buy
805041 500mg $65.2 Buy

2-(trimethylsilyl)-2-cyclohexen-1-one Chemical Properties,Uses,Production

Uses

The following silyl enone can be converted into a highly useful cyclohexyne precursor as reported by the Garg and DuBois groups. The resulting silyltriflate adduct can be subjected to various dienes and dipolarophiles in the presence of Cesium Fluoride.

General Description

2-(Trimethylsilyl)-2-cyclohexen-1-one is a silyl enone.

2-(trimethylsilyl)-2-cyclohexen-1-one Preparation Products And Raw materials

Raw materials

Preparation Products

2-(trimethylsilyl)-2-cyclohexen-1-one Suppliers

Global( 2)Suppliers
Supplier Tel Email Country ProdList Advantage
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
Supplier Advantage
Sigma-Aldrich 80
2-(trimethylsilyl)-2-cyclohexen-1-one 2-Cyclohexen-1-one, 2-(trimethylsilyl)- 72162-99-3