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9,10-Dibromoanthracene

9,10-Dibromoanthracene structure

CAS No.: 523-27-3

Chemical Name:: 9,10-Dibromoanthracene

Synonyms: 9,10-Dibromoanthracene99%;NSC 6263;9,10-anthracene;ms-Dibromoanthracene;9, 10-Dibromoanthrac;9,I O-Dibromanthracen;9,1-Dibromoanthracene;9,1O-dibromoanthracene;9,10-DIRBOMOANTHRACENE;9,10-DIBROMOANTHRACENE

CBNumber:: CB6318033

Molecular Formula:: C14H8Br2

Molecular Weight:: 336.02

MDL Number:: MFCD00001244

MOL File:: 523-27-3.mol

MSDS File:: SDS

Last updated:2023-12-24 21:24:35

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9,10-Dibromoanthracene Properties

Melting point	223-224 °C (lit.)
Boiling point	342.21°C (rough estimate)
Density	1.7167 (estimate)
refractive index	1.6300 (estimate)
storage temp.	Sealed in dry,Room Temperature
solubility	Chloroform
form	Fluffy Powder
color	Yellow to yellow-green
Water Solubility	Soluble in water.
Merck	14,3018
BRN	1912109
InChIKey	BRUOAURMAFDGLP-UHFFFAOYSA-N
CAS DataBase Reference	523-27-3(CAS DataBase Reference)
FDA UNII	61CP7C5Y82
NIST Chemistry Reference	Anthracene, 9,10-dibromo-(523-27-3)
EPA Substance Registry System	Anthracene, 9,10-dibromo- (523-27-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS09

Signal word

Warning

Hazard statements

H410

Precautionary statements

Hazard Codes

Risk Statements

Safety Statements

RIDADR

UN 3077

WGK Germany

TSCA

Yes

HS Code

29039990

NFPA 704

	1
2		0

9,10-Dibromoanthracene price More Price(36)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	D38855	9,10-Dibromoanthracene 98%	523-27-3	10g	$84.6	2024-03-01	Buy
Sigma-Aldrich	D38855	9,10-Dibromoanthracene 98%	523-27-3	50g	$149.4	2024-03-01	Buy
TCI Chemical	D0166	9,10-Dibromoanthracene >98.0%(GC)	523-27-3	25g	$107	2024-03-01	Buy
TCI Chemical	D0166	9,10-Dibromoanthracene >98.0%(GC)	523-27-3	100g	$236	2024-03-01	Buy
Alfa Aesar	L12680	9,10-Dibromoanthracene, 98%	523-27-3	5g	$32.65	2024-03-01	Buy

Product number	Packaging	Price	Buy
D38855	10g	$84.6	Buy
D38855	50g	$149.4	Buy
D0166	25g	$107	Buy
D0166	100g	$236	Buy
L12680	5g	$32.65	Buy

9,10-Dibromoanthracene Chemical Properties,Uses,Production

Description

9,10-Dibromoanthracene is an organic chemical compound containing anthracene with two bromine atoms substituted on its central ring. As a symmetrically brominated anthracene derivative, it is bearing functional groups to extend its conjugation further mainly via C-C bond forming i.e. Stille and Suzuki coupling reactions. It is notable in that it was the first single molecule to have a chemical reaction observed by an atomic force microscope and scanning tunneling microscopy. It is a low-molecular-weight organic semiconductor. It can used as an initiator in visible-spectrum solar-light-mediated benzylic C–H oxygenation through solar light or the blue LED activate[1-2].

Chemical Properties

Yellow to yellow-green fluffy powder. Melting point 226°C. It can be sublimated and oxidized to generate anthraquinone. It is soluble in hot benzene and hot toluene, but only slightly soluble in alcohol, ether, and cold benzene. It is insoluble in water.

Uses

9,10-Dibromoanthracene is a dibrominated polycyclic aromatic hydrocarbon (PAH). 9,10-Dibromoanthracene is often used as an energy acceptor and activator in reactions that produce chemiluminescence.

Preparation

9,10-Dibromoanthracene is synthesized by the bromination of anthracene. The bromination reaction is carried out at room temperature using carbon tetrachloride as a solvent. Using 80-85% anthracene as raw material, adding bromine to react for half an hour, the yield is 83-88%.

Origin

9,10-Dibromoanthracene was first synthesized in 1923 by Ian (formerly Isidor) M. Heilbron and John S. Heaton, chemists working at the University of Liverpool.

Purification Methods

Recrystallise it from toluene, xylene or CCl4 (yellow needles), and sublime it in a vacuum [Johnston et al. J Am Chem Soc 109 1291 1987]. [Heilbron & Heaton Org Synth Coll Vol I 207 1941, Beilstein 5 H 665.]

References

[1] Santra S, et al. Visible-Spectrum Solar-Light-Mediated Benzylic C–H Oxygenation Using 9,10-Dibromoanthracene As an Initiator. The Journal of Organic Chemistry, 2020; 86: 1164–1171.
[2] Watanabe M. Formation of aligned needle-like crystals of 9,10-dibromoanthracene in small droplets. Journal of Applied Polymer Science, 2023; 140: e54515.

9,10-Dibromoanthracene synthesis

Synthesis of 9,10-Dibromoanthracene from 1,3-Dibromo-5,5-dimethylhydantoin and Anthracene

9,10-Dibromoanthracene Preparation Products And Raw materials

Raw materials

Carbon tetrachloride Anthracene

Preparation Products

9,10-ANTHRACENEDICARBOXALDEHYDE 9-Bromoanthracene 10-(2-Naphthyl)anthracene-9-boronic acid 9-Bromo-10-(2-naphthyl)anthracene Diphenylethyne- 3, 3', 5, 5'-tetracarboxylic acid (PCN-14)

TIPS-anthracene

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9,10-Dibromoanthracene Suppliers

Global( 450)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Jiangsu Nata Opto-electronic Material Co.,Ltd.	+86-0512-62520998 +86-15030927757	gaoym@natachem.com	China	229	58
Hebei Xinsheng New Material Technology Co., LTD.	+86-16632316109	xinshengkeji@xsmaterial.com	China	1085	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	20287	58
Springchem New Material Technology Co.,Limited	+86-021-62885108 +8613917661608	info@spring-chem.com	China	2068	57
Capot Chemical Co.,Ltd.	+86-（0）57185586718 +86-13336195806	sales@capot.com	China	29791	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	18779	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21634	55
China Synchem Technology Co.,Ltd.	+86-0552-4929304 +86-18055277008	wangxuhui1985@126.com	China	57	55
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32957	60
Speranza Chemical Co., Ltd.	+86-86-075521030354 +8618688942810	sophieliu@speranzachem.com	China	802	55

Supplier	Advantage
Jiangsu Nata Opto-electronic Material Co.,Ltd.	58
Hebei Xinsheng New Material Technology Co., LTD.	58
Henan Fengda Chemical Co., Ltd	58
Springchem New Material Technology Co.,Limited	57
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
China Synchem Technology Co.,Ltd.	55
ATK CHEMICAL COMPANY LIMITED	60
Speranza Chemical Co., Ltd.	55

View Lastest Price from 9,10-Dibromoanthracene manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-11-21	9,10-Dibromoanthracene 523-27-3	US $0.00 / KG	1KG	98%min	30tons/month	WUHAN FORTUNA CHEMICAL CO., LTD
2024-11-21	9,10-Dibromoanthracene 523-27-3	US $450.00 / KG	1KG	98%+	300MT/year	Speranza Chemical Co., Ltd.
2023-12-24	9,10-Dibromoanthracene 523-27-3	US $100.00-1.00 / KG	1KG	99%	g-kg-tons, free sample is available	Henan Fengda Chemical Co., Ltd

9,10-Dibromoanthracene
523-27-3
US $0.00 / KG
98%min
WUHAN FORTUNA CHEMICAL CO., LTD

9,10-Dibromoanthracene
523-27-3
US $450.00 / KG
98%+
Speranza Chemical Co., Ltd.

9,10-Dibromoanthracene
523-27-3
US $100.00-1.00 / KG
99%
Henan Fengda Chemical Co., Ltd

9,10-Dibromoanthracene Spectrum

9,10-Dibromoanthracene(523-27-3)MS 9,10-Dibromoanthracene(523-27-3)¹HNMR 9,10-Dibromoanthracene(523-27-3)¹³CNMR 9,10-Dibromoanthracene(523-27-3)IR1 9,10-Dibromoanthracene(523-27-3)IR2 9,10-Dibromoanthracene(523-27-3)IR3 9,10-Dibromoanthracene(523-27-3)Raman

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9,I O-Dibromanthracen 9,10-DIBROMO ANTHRACENEN 9,10-Dibromoanthracene,96% Anthracene,9,10-dibromo- ms-Dibromoanthracene 9,10-DIBROMOANTHRACENE 9,10-DIRBOMOANTHRACENE 9,1O-dibromoanthracene NSC 6263 9,10-DibroMoanthracene, 96% 10GR 9,10-DibroMoanthracene, 96% 50GR 9, 10-Dibromoanthrac 9,10-Dibromoanthracene ,95% 9,10-DibroMo-anthracene (9,10-DBA) 9,10-anthracene 9,10-DibroMoanthracene, 98%+ 9,1-Dibromoanthracene 9,10-dibromoananthracene 9,10-dibromo-anthracen 9,10-Dibromoanthracene > 9,10-Dibromoanthracene ISO 9001：2015 REACH 9,10-Dibromoanthracene99% 9,10-Dibromoanthracene, ≥ 98.0% 9,10-Dibromoanthracene in toluene 523-27-3 C14H8Br2 C6H4CBr2C6H4 C13 to C37+ Aryl Building Blocks Anthracenes Organic Building Blocks Halogenated Hydrocarbons Miscellaneous Aromatic Compounds Electronic Chemicals Anthracenes Anthracene series Aryl C13 to C37+ Halogenated Hydrocarbons OLED materrials C13 to C37+ Building Blocks Chemical Synthesis Halogenated Hydrocarbons Organic Building Blocks OLED