TRIBUTYLSTANNYLTRIMETHYLSILANE
- CAS No.
- 17955-46-3
- Chemical Name:
- TRIBUTYLSTANNYLTRIMETHYLSILANE
- Synonyms
- SKL1120;(TRIMETHYLSILYL)TRIBUTYLTIN;TRIMETHYLSILYLTRI-N-BUTYLTIN;TRIBUTYLSTANNYLTRIMETHYLSILANE;(TRIMETHYLSILYL)TRIBUTYLSTANNANE;TRIMETHYL(TRIBUTYLSTANNYL)SILANE;Trimethylsilyltri-n-butyltin 97%;Tributyl(trimethylsilyl)stannane;TRI-n-BUTYLSTANNYLTRIMETHYLSILANE;Stannane, tributyl(trimethylsilyl)-
- CBNumber:
- CB6322630
- Molecular Formula:
- C15H36SiSn
- Molecular Weight:
- 363.24
- MDL Number:
- MFCD00054903
- MOL File:
- 17955-46-3.mol
- MSDS File:
- SDS
Boiling point | 102-103 °C0.5 mm Hg(lit.) |
---|---|
Density | 1.04 g/mL at 25 °C(lit.) |
refractive index |
n |
Flash point | >230 °F |
storage temp. | Store under Argon |
solubility | soluble in THF, ether, CH2Cl2, MeOH, hexane, insoluble in water. |
Specific Gravity | 1.040 |
Hydrolytic Sensitivity | 1: no significant reaction with aqueous systems |
BRN | 4127163 |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS06,GHS08,GHS09 |
---|---|
Signal word | Danger |
Hazard statements | H301-H312-H315-H319-H360FD-H372-H410 |
Precautionary statements | P202-P273-P280-P301+P310-P302+P352+P312-P305+P351+P338 |
Hazard Codes | T,N |
Risk Statements | 21-25-36/38-48/23/25-50/53 |
Safety Statements | 35-36/37/39-45-60-61 |
RIDADR | UN 2788 6.1/PG 3 |
WGK Germany | 3 |
F | 10-21 |
TSCA | No |
HazardClass | 6.1(b) |
PackingGroup | III |
HS Code | 29319090 |
TRIBUTYLSTANNYLTRIMETHYLSILANE price More Price(11)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 367265 | Trimethyl(tributylstannyl)silane 97% | 17955-46-3 | 5g | $260 | 2024-03-01 | Buy |
TRC | T896365 | Tributyl(trimethylsilyl)stannane | 17955-46-3 | 100mg | $75 | 2021-12-16 | Buy |
Matrix Scientific | 115409 | Tributylstannyltrimethylsilane 96% | 17955-46-3 | 5g | $198 | 2021-12-16 | Buy |
AK Scientific | Y8036 | (Tributylstannyl)trimethylsilane | 17955-46-3 | 5g | $327 | 2021-12-16 | Buy |
American Custom Chemicals Corporation | TIN0000946 | TRIBUTYLSTANNYLTRIMETHYLSILANE 95.00% | 17955-46-3 | 1G | $431.6 | 2021-12-16 | Buy |
TRIBUTYLSTANNYLTRIMETHYLSILANE Chemical Properties,Uses,Production
Physical properties
colorless liquid. bp 88 °C (0.2 mmHg).
Uses
Trimethylsilyltributylstannane is used for the vicinal bis-functionalization of alkynes, dienes, allenes, activated olefins, 1,1-addition to isonitriles, for generation of metal-free aryl and vinyl anions, for generation of benzynes and quinonedimethanes; stereoselective bis-functionalization-cyclization of diynes, eneynes, bis-allenes, alleneynes, and allenealdehydes; silylation of allylic, propargylic derivatives, and aryl bromides; formation of silyl and stannyl cuprates.It takes part in the reactions of Addition to Alkynes, Synthetic Applications of β-Trialkylsilylvinylstannanes, Addition to Isonitriles, Addition to Alkenes and 1,3-Dienes, Addition to Activated Double Bonds, Addition to Allenes, etc.
Preparation
By treating freshly distilled tri-n-butylstannane with LDA followed by quenching with chlorotrimethylsilane.
TRIBUTYLSTANNYLTRIMETHYLSILANE Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18777 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39894 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49374 | 58 |
career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29811 | 58 |
Shaanxi Dideu Medichem Co. Ltd | +86-029-89586680 +86-18192503167 | 1026@dideu.com | China | 7724 | 58 |
Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | info@dycnchem.com | China | 52849 | 58 |
Alfa Chemistry | Info@alfa-chemistry.com | United States | 24072 | 58 | |
Jiangxi Huihe Chemical Co., Ltd. | +86-19189228086 +8618858568638 | wuzhouding@huihecrop.com | China | 886 | 58 |
Hebei Weibang Biotechnology Co., Ltd | +8617732866630 | bess@weibangbio.com | China | 18153 | 58 |
PT CHEM GROUP LIMITED | peter68@ptchemgroup.com | China | 35425 | 58 |
View Lastest Price from TRIBUTYLSTANNYLTRIMETHYLSILANE manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2020-01-15 | TRIBUTYLSTANNYLTRIMETHYLSILANE
17955-46-3
|
US $9.80 / KG | 1g | ≥99% | 100kg | Career Henan Chemical Co |
- TRIBUTYLSTANNYLTRIMETHYLSILANE
17955-46-3
- US $9.80 / KG
- ≥99%
- Career Henan Chemical Co