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ChemicalBook >> CAS DataBase List >>Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II)

Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II)

Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II) Structure
Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II) structure
CAS No.
1702744-45-3
Chemical Name:
Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II)
Synonyms
Nicl(O-Tolyl)(Tmeda);chloro(2-methylphenyl)(N,N,N`,N`-tetramethyl-1,2-ethylenediamine)nickel;Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II);Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II);Chloro(2-methylphenyl)(N,N,N'',N''-tetramethyl-1,2-ethylenediamine)nickel(II);CHLORO(2-METHYLPHENYL)(N,N,N',N'-TETRAMETHYL-1,2-ETHYLENEDIAMINE)NICKEL(II),99%(CONTAINSABOUT5%O-CHLOROTOLUENE)NICL(O-TOLYL)(TMEDA);Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II), 99% (contains about 10% o-chlorotoluene) NiCl(o-tolyl)(TMEDA)
CBNumber:
CB63357073
Molecular Formula:
C13H23ClN2Ni
Molecular Weight:
301.48152
MDL Number:
MFCD29037017
MOL File:
1702744-45-3.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06
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Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II) Properties

form Powder
color dark-orange
Sensitive air sensitive

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS07,GHS08
Signal word  Danger
Hazard statements  H317-H334-H350
Precautionary statements  P201-P261-P280-P308+P313
Risk Statements  45-42/43
Safety Statements  53-22-36/37/39-45
TSCA  No

Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II) price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 804398 [(TMEDA)Ni(o-tolyl)Cl] 95% 1702744-45-3 100MG $88.3 2023-06-20 Buy
Strem Chemicals 28-0165 Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II), 99% (contains about 5% o-chlorotoluene) NiCl(o-tolyl)(TMEDA) 1702744-45-3 500mg $114 2024-03-01 Buy
Strem Chemicals 28-0165 Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II), 99% (contains about 5% o-chlorotoluene) NiCl(o-tolyl)(TMEDA) 1702744-45-3 2g $342 2024-03-01 Buy
Strem Chemicals 28-0165 Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II), 99% (contains about 5% o-chlorotoluene) NiCl(o-tolyl)(TMEDA) 1702744-45-3 10g $1369 2024-03-01 Buy
ChemSupplyAustralia 300971 N,N,N’,N’-Tetramethylethylenediaminechloro(2-methylphenyl)nickel(II), 97% 1702744-45-3 250mg $60.5 2021-12-16 Buy
Product number Packaging Price Buy
804398 100MG $88.3 Buy
28-0165 500mg $114 Buy
28-0165 2g $342 Buy
28-0165 10g $1369 Buy
300971 250mg $60.5 Buy

Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II) Chemical Properties,Uses,Production

Reaction

  1. Air-Stable Nickel precatalyst for cross-coupling
  2. Precatalyst allowing various ligands to be used (monoand bidendate phosphines, diimines and NHCs)
Reactions of 1702744-45-3

Uses

Effective precatalyst for a variety of nickel-catalyzed transformations, including Suzuki-Miyaura, Buchwald-Hartwig and other cyclizations and oxidative couplings.

Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II) Preparation Products And Raw materials

Raw materials

Preparation Products

Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II) Suppliers

Global( 18)Suppliers
Supplier Tel Email Country ProdList Advantage
Bide Pharmatech Ltd. 400-164-7117 13681763483 product02@bidepharm.com China 41462 60
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51456 80
Alfa Chemistry 1-516-6625404 support@alfa-chemistry.com United States 9171 60
Tianjin Kailiqi Biotechnology Co., Ltd. 15076683720 klq@cw-bio.com China 5931 55
Aikon International Limited 025-66113011 18112977050 sales01@aikonchem.com China 16027 58
Beijing Jin Ming Biotechnology Co., Ltd. 010-60605840 15801484223; psaitong@jm-bio.com China 29774 58
Bide Pharmatech Ltd. 400-6005915 sales@picasso-e.com China 39653 58
Wuhan Shenxinda Chemical Technology Co., Ltd. 27-87509949 13419524390 sdg9136@163.com China 118 58
Baoji Funuokang Industrial Co., Ltd 13220096790 1754423088@qq.com China 2993 58
Shanghai Haohong Scientific Co., Ltd. 400-400-8210725 malulu@leyan.com China 39990 58
Supplier Advantage
Bide Pharmatech Ltd. 60
Sigma-Aldrich 80
Alfa Chemistry 60
Tianjin Kailiqi Biotechnology Co., Ltd. 55
Aikon International Limited 58
Beijing Jin Ming Biotechnology Co., Ltd. 58
Bide Pharmatech Ltd. 58
Wuhan Shenxinda Chemical Technology Co., Ltd. 58
Baoji Funuokang Industrial Co., Ltd 58
Shanghai Haohong Scientific Co., Ltd. 58
CHLORO(2-METHYLPHENYL)(N,N,N',N'-TETRAMETHYL-1,2-ETHYLENEDIAMINE)NICKEL(II),99%(CONTAINSABOUT5%O-CHLOROTOLUENE)NICL(O-TOLYL)(TMEDA) Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II), 99% (contains about 10% o-chlorotoluene) NiCl(o-tolyl)(TMEDA) Nicl(O-Tolyl)(Tmeda) Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II) chloro(2-methylphenyl)(N,N,N`,N`-tetramethyl-1,2-ethylenediamine)nickel Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II) Chloro(2-methylphenyl)(N,N,N'',N''-tetramethyl-1,2-ethylenediamine)nickel(II) 1702744-45-3 C13H23ClN2Ni