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4,4'-Oxydiphthalic anhydride

4,4'-Oxydiphthalic anhydride structure

CAS No.: 1823-59-2

Chemical Name:: 4,4'-Oxydiphthalic anhydride

Synonyms: ODPA;ODPA;s-ODPA;FCK;5,5'-Oxybis(isobenzofuran-1,3-dione);FFCF;Bis-(3-phthalyl anhy;oxydiphthalicanhydride;Oxydiphthalic anhydrid;4,4'-Oxydiphthalic Acid

CBNumber:: CB6372079

Molecular Formula:: C16H6O7

Molecular Weight:: 310.21

MDL Number:: MFCD00039144

MOL File:: 1823-59-2.mol

Last updated:2024-11-13 18:13:23

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4,4'-Oxydiphthalic anhydride Properties

Melting point	225-229 °C(lit.)
Boiling point	410.39°C (rough estimate)
Density	1.4942 (rough estimate)
refractive index	1.6380 (estimate)
storage temp.	Inert atmosphere,Room Temperature
solubility	very slightly in Toluene,Acetone
form	powder to crystal
color	White to Light yellow to Light orange
InChI	InChI=1S/C16H6O7/c17-13-9-3-1-7(5-11(9)15(19)22-13)21-8-2-4-10-12(6-8)16(20)23-14(10)18/h1-6H
InChIKey	QQGYZOYWNCKGEK-UHFFFAOYSA-N
SMILES	O(C1C=CC2C(=O)OC(=O)C=2C=1)C1C=CC2C(=O)OC(=O)C=2C=1
CAS DataBase Reference	1823-59-2(CAS DataBase Reference)
EWG's Food Scores	1
FDA UNII	G58E17X7VE
NIST Chemistry Reference	Bis-(3-phthalyl anhydride) ether(1823-59-2)
EPA Substance Registry System	1,3-Isobenzofurandione, 5,5'-oxybis- (1823-59-2)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS05

Signal word

Danger

Hazard statements

H412

Precautionary statements

P273

Risk Statements

52/53

Safety Statements

WGK Germany

HS Code

29189900

NFPA 704

	0
1		0

4,4'-Oxydiphthalic anhydride price More Price(17)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	524492	4,4′-Oxydiphthalic anhydride 97%	1823-59-2	25g	$127.2	2024-03-01	Buy
TCI Chemical	O0237	4,4'-Oxydiphthalic Anhydride >98.0%(HPLC)	1823-59-2	25g	$59	2024-03-01	Buy
TCI Chemical	O0237	4,4'-Oxydiphthalic Anhydride >98.0%(HPLC)	1823-59-2	100g	$192	2024-03-01	Buy
TCI Chemical	O0423	4,4'-Oxydiphthalic Anhydride (purified by sublimation) >99.0%(HPLC)	1823-59-2	5g	$194	2024-03-01	Buy
TRC	O870823	5,5''-Oxybis(isobenzofuran-1,3-dione)	1823-59-2	250mg	$45	2021-12-16	Buy

Product number	Packaging	Price	Buy
524492	25g	$127.2	Buy
O0237	25g	$59	Buy
O0237	100g	$192	Buy
O0423	5g	$194	Buy
O870823	250mg	$45	Buy

4,4'-Oxydiphthalic anhydride Chemical Properties,Uses,Production

Description

4,4'-Oxydiphthalic anhydride/ODPA(CAS:1823-59-2) is a solid, melts in the range of 225-229 °C and was first introduced in the mid-1980s, offering a greater degree of flexibility than other commercial dianhydrides. It also is somewhat less reactive than BTDA. ODPA has largely been used in polyimides and much less so in epoxies. It imparts special performance properties in free films and in FCCL production for high-end personal electronic devices.

Chemical Properties

off-white to white powder

Uses

4,4'-oxydiphthalic anhydride be used for the preparation of a polyimide material.

Preparation

The preparation of 4,4'-Oxydiphthalic anhydride is as follows:Chlorophthalic anhydride (30g, 160mmol), tetraphenyl phosphonium bromide (0.3g, 0.7mmol), and 2,5-dichlorobenzoic acid (0.08g, 0.4mmol) were heated to approximately 220℃. Potassium carbonate (7.95g, 58mmol) was added over 45 minutes. The reaction was sampled after addition of the potassium carbonate and showed a 24.9% conversion to 4,4'-oxydiphthalic anhydride. The reaction was heated for an additional 45 minutes. The reaction mixture was diluted with 1,2,4-trichlorobenzene (90g) and filtered. The 4,4'-oxydiphthalic anhydride was allowed to crystallize and was collected, washed with 1,2,4-trichlorobenzene followed by hexane, and dried in an air circulating oven at 120℃. to give crude 4,4'-oxydiphthalic anhydride, 12.9g.

Flammability and Explosibility

Not classified

IC 50

HepG2: IC50 = 121 μM (human); SK-HEP1: IC50 = 199 μM (human); Hepatocyte: IC50 >200 μM (rat)

4,4'-Oxydiphthalic anhydride synthesis

Synthesis of 4,4'-Oxydiphthalic anhydride from 4-(3,4-dicarboxyphenoxy)benzene-1,2-dicarboxylic acid

4,4'-Oxydiphthalic anhydride Preparation Products And Raw materials

Raw materials

4-Chlorophthalic anhydride 4-(3,4-dicarboxyphenoxy)benzene-1,2-dicarboxylic acid

Preparation Products

4,4'-Oxydiphthalic anhydride Suppliers

Global( 426)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Heynova (Shanghai) New Material Technology CO., Ltd	+86-17821320848; +8617821320848	zoe@heynovachem.com	China	179	58
Shanghai Daeyeon Chemicals Co., Ltd	021-64478606 +8615900664856	daeyeon001@vip.163.com	China	2062	58
CHINATECH(TIANJIN) CHEMICAL CO.,LTD.	+86-18222493702 +86-18222272656	sales8@chinatechem.com	China	63	58
Shanghai UCHEM Inc.	+862156762820 +86-13564624040	sales@myuchem.com	China	7514	58
Henan Allgreen Chemical Co.,LTD	+86-37155567971 +86-13633837469	info@allgreenchem.com	China	5984	58
Hebei Mojin Biotechnology Co., Ltd	+86 13288715578 +8613288715578	sales@hbmojin.com	China	12841	58
Hebei Chuanghai Biotechnology Co,.LTD	+86-13131129325	sales1@chuanghaibio.com	China	5892	58
Hebei Weibang Biotechnology Co., Ltd	+8617732866630	bess@weibangbio.com	China	18153	58
Hebei Kingfiner Technology Development Co.Ltd	+86-15532196582 +86-15373005021	lisa@kingfinertech.com	China	3010	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	20285	58

Supplier	Advantage
Heynova (Shanghai) New Material Technology CO., Ltd	58
Shanghai Daeyeon Chemicals Co., Ltd	58
CHINATECH(TIANJIN) CHEMICAL CO.,LTD.	58
Shanghai UCHEM Inc.	58
Henan Allgreen Chemical Co.,LTD	58
Hebei Mojin Biotechnology Co., Ltd	58
Hebei Chuanghai Biotechnology Co,.LTD	58
Hebei Weibang Biotechnology Co., Ltd	58
Hebei Kingfiner Technology Development Co.Ltd	58
Henan Fengda Chemical Co., Ltd	58

Applications of 4,4'-Oxydiphthalic anhydride
4,4'-Oxydiphthalic anhydride (ODPA) is commonly used in the synthesis of polyimides.
May 24，2024

View Lastest Price from 4,4'-Oxydiphthalic anhydride manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-11-29	4,4'-Oxydiphthalic anhydride 1823-59-2	US $0.00 / KG	1KG	98%min	30tons/month	WUHAN FORTUNA CHEMICAL CO., LTD
2024-11-29	4,4'-Oxydiphthalic anhydride 1823-59-2	US $40.00 / kg	1kg	99%	5000kg/week	Hebei Zhuanglai Chemical Trading Co.,Ltd
2024-11-13	4,4'-Oxydiphthalic anhydride 1823-59-2	US $0.00 / kg	1kg	99.5%	As your request	Changzhou waston chemical technology Co.,Ltd

4,4'-Oxydiphthalic anhydride
1823-59-2
US $0.00 / KG
98%min
WUHAN FORTUNA CHEMICAL CO., LTD

4,4'-Oxydiphthalic anhydride
1823-59-2
US $40.00 / kg
99%
Hebei Zhuanglai Chemical Trading Co.,Ltd

4,4'-Oxydiphthalic anhydride
1823-59-2
US $0.00 / kg
99.5%
Changzhou waston chemical technology Co.,Ltd

4,4'-Oxydiphthalic anhydride Spectrum

4,4'-Oxydiphthalic anhydride(1823-59-2)MS 4,4'-Oxydiphthalic anhydride(1823-59-2)¹HNMR 4,4'-Oxydiphthalic anhydride(1823-59-2)¹³CNMR 4,4'-Oxydiphthalic anhydride(1823-59-2)IR1 4,4'-Oxydiphthalic anhydride(1823-59-2)IR2

1823-59-2(4,4'-Oxydiphthalic anhydride)Related Search:

Phthaloyl dichloride Isatoic Anhydride CIS-BUTENEDIOIC ANHYDRIDE Trifluoromethanesulfonic anhydride Caronic anhydride

Succinic anhydride Dibutyl phthalate O-Phthalimide Glutaric anhydride Phthalic anhydride

PHTHALAMIDE 4-Tolyl ether 5-Methoxy-isobenzofuran-1,3-dione 3,4'-DIMETHYLDIPHENYL ETHER 3-Phenoxybenzaldehyde

Phthalates Acetic anhydride 4,4'-BIS(METHOXYMETHYL)DIPHENYL ETHER

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4,4'-Oxydiphthalic Anhydride (purified by subliMation) 4,4 '-diphenylether twoanhydride 1,3-Isobenzofurandione, 5,5'-oxybis- Bis-(3-phthalyl anhydride) ether SynonyMs 4,4'-Oxydiphthalic anhydride 4,4''-Oxybisdiphthalic a 5,5'-oxybis(2-benzofuran-1,3-dione) 4,4'-Oxydiphthalic dianhydride 5,5’-oxybis-3-isobenzofurandione oxydiphthalicanhydride 4-4'-OXYDIPHTHALIC ACID ANHYDRIDE 4,4'-OXYDIPHTHALIC ANHYDRIDE 4,4'-Oxydiphthalic Acid 4,4'-OXYDIPHTHALIC ANHYDRIDE 97% BIS-(3-PHTHALYL ANHYDRIDE) ETHER 4,4''-OXYBISDIPHTHALIC ANHYDRIDE 5,5'-oxybis-1,3-isobenzofurandione 3,3',4,4'-Diphenylether tetracarboxylic dianhydride 4,4'-Oxybis(1,2-benzenedicarboxylic acid)1,2:1',2'-dianhydride 4,4'-Oxybis(benzene-1,2-dicarboxylic acid)1,2:1',2'-dianhydride 4,4'-Oxybis(phthalic acid)1,2:1',2'-dianhydride 4,4'-Oxybisphthalic 1,2:1',2'-dianhydride 4,4'-Oxybisphthalic acid-1,2:1',2'-dianhydride 4,4'-oxydiphthalic Anhydride（ODPA) 5-(1,3-diketoisobenzofuran-5-yl)oxyisobenzofuran-1,3-quinone 5-[(1,3-dioxo-2-benzofuran-5-yl)oxy]-2-benzofuran-1,3-dione Bis-(3-phthalyl anhy 3,3',4,4'-Diphenyl ether tetracarboxylic aciddianhydride 4,4'-Oxydiphthalic dianhydride (ODPA) 5,5'-Ooxydiisobenzofuran-1,3-dione ODPA 4,4'-oxydiphthalic Anhydride Oxydiphthalic anhydrid Bis-(3-phthalyl anhydride) ether (ODPA) a-ODPA 2,3,3,4'-oxydiphthalic anhydride 4,4'-oxydiphthalic Anhydride in stock Factory 4,4'-Oxydiphthalic anhydride 1823-59-2 Bis-(3-phthalyl anhydride) ether 1823-59-2 Oxydiphthalicanhydride (s-ODPA) 4,4'-OxydiphthalicAnhydride> OXYDIPHTHALICANHYDRIDE (S-ODPA)CAS 1823-59-2 2-[3-Acetyl-2-methyl-1-(4-methylphenyl)indol-5-yl]oxyethyl-diethylazanium chloride Bis-(3-phthalyl anhydride) ether SynonyMs 4,4'-Oxydiphthalic FFCF s-ODPA ODPA 5,5'-Oxybis(isobenzofuran-1,3-dione) ODPA FCK 4,4'-Oxydiphthalic anhydride (s-ODPA) 4,4'-Oxydiphthalic anhydride,NA 4,4'-Oxydiphthalic anhydride 5,5'-Oxybis(isobenzofuran-1,3-dione) 4,4'-Oxydiphthalic Anhydride(ODPA) 3,3',4,4'-Diphenyl ether tetracarboxylic acid dianhydride 3,3'4,4'-Diphenylether tetracarboxylic dianhydride (s-ODPA) 1823-59-2 1823-58-2 C8H3O32O C16H6O7 Reagent for High-Performance Polymer Research