(2-bromo-1,1,2,2-tetrafluoroethyl)(phenyl)sulfane
- CAS No.
- 83015-33-2
- Chemical Name:
- (2-bromo-1,1,2,2-tetrafluoroethyl)(phenyl)sulfane
- Synonyms
- (2-bromo-1,1,2,2-tetrafluoroethyl)(phenyl)sulfane;(2-bromo-1,1,2,2-tetrafluoroethylsulfanyl)benzene;Benzene, [(2-bromo-1,1,2,2-tetrafluoroethyl)thio]-
- CBNumber:
- CB64189705
- Molecular Formula:
- C8H5BrF4S
- Molecular Weight:
- 289.09
- MDL Number:
- MFCD27996155
- MOL File:
- 83015-33-2.mol
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H319-H413 |
| Precautionary statements | P273-P305+P351+P338 |
(2-bromo-1,1,2,2-tetrafluoroethyl)(phenyl)sulfane price
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | CF0014 | Phenylsulfanyltetrafluorobromoethane | 83015-33-2 | 1g | $645 | 2024-03-01 | Buy |
| American Custom Chemicals Corporation | HCH0418701 | (2-BROMO-1,1,2,2-TETRAFLUOROETHYL)(PHENYL)SULFANE 95.00% | 83015-33-2 | 5MG | $497.43 | 2021-12-16 | Buy |
(2-bromo-1,1,2,2-tetrafluoroethyl)(phenyl)sulfane Chemical Properties,Uses,Production
Uses
Phenylsulfanyltetrafluoroethyl bromide is a fluoroalkylbromide that is a radical source of the phenylsulfanyltetrafluoroethyl moiety. Alternatively, it can also be selectively metallated at the fluorinated carbon with Turbo Grignard reagent at low temperatures resulting in a thermally unstable anion that can act as a nucleophilic fluoroalkylation reagent towards a wide variety of electrophiles, such as aldehydes, ketones or sulfonylimines. A phenylsulfanyltetrafluoroethyl moiety incorporated in the substrate can be treated with tributyltin hydride and generate the corresponding fluoroalkyl radical. If the substrate lacks any olefins, it can be reduced to tetrafluoroethyl group whereas if the substrate contains an olefin in a correct spatial orientation, it can lead to an intramolecular cyclization affording tetrafluorinated cyclic structures.
reaction suitability
reaction type: C-C Bond Formation
(2-bromo-1,1,2,2-tetrafluoroethyl)(phenyl)sulfane Preparation Products And Raw materials
Raw materials
Preparation Products
(2-bromo-1,1,2,2-tetrafluoroethyl)(phenyl)sulfane Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Bide Pharmatech Ltd. | 400-164-7117 13681763483 | product02@bidepharm.com | China | 41457 | 60 |
| Henan Weituxi Chemical Technology Co., Ltd. | 0371-63284658 18135795563 | 2885349392@qq.com | China | 9978 | 58 |
| Dalian Shuanghang Chemical Co., LTD | +86-411-66858498 +86-13941194417 | sales@dl-bykj.cn | China | 1977 | 58 |
| TCI (Shanghai) Chemical Trading Co., Ltd. | 021-021-61109150 | sales@tcisct.com | China | 31121 | 58 |
| Bide Pharmatech Ltd. | 400-6005915 | sales@picasso-e.com | China | 39665 | 58 |
| Merck KGaA | 21-20338288 | ordercn@merckgroup.com | China | 292394 | 58 |