ChemicalBook >> CAS DataBase List >>(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE
(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE
- CAS No.
- 185449-86-9
- Chemical Name:
- (S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE
- Synonyms
- 3,4-a'']dinaphthalen-4-yl)dimethylamine;3,4-a']dinaphthalen-4-yl)dimethylamine,98%;3,4-a']dinaphthalen-4-yl)dimethylamine,min.98%;3,4-a']dinaphthalen-4-yl)dimethylamine, min. 98%;(S)-(+)-(2,6-Dimethyl-3,5-dioxa-4-phospha-cyclohepta[2,1-a;N,N,2,6-Tetramethyldinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine;(11bS)-N,N,2,6-Tetramethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine;(11bS)-N,N,2,6-tetraMethyl-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-aMine;Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N,N,2,6-tetramethyl-, (11bS)-;(11bS)-N,N,2,6-Tetramethyl-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine,99%e.e.
- CBNumber:
- CB6487814
- Molecular Formula:
- C24H22NO2P
- Molecular Weight:
- 387.41
- MDL Number:
- MFCD04117683
- MOL File:
- 185449-86-9.mol
Last updated:2023-05-04 15:16:43
(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE Properties
Melting point | 228-229°C |
---|---|
Boiling point | 571.0±53.0 °C(Predicted) |
alpha | +636° (c 0.30, CH2Cl2) |
storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
pka | 1.32±0.20(Predicted) |
form | Powder |
color | off-white |
Sensitive | moisture sensitive |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
---|---|
Signal word | Warning |
Hazard statements | H319-H335-H315 |
Precautionary statements | P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P |
Hazard Codes | Xn |
Risk Statements | 36/37/38-22 |
Safety Statements | 26-36/37/39 |
(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE price More Price(13)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Strem Chemicals | 15-1255 | (S)-(+)-(2,6-Dimethyl-3,5-dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine, min. 98% | 185449-86-9 | 100mg | $195 | 2024-03-01 | Buy |
Strem Chemicals | 15-1255 | (S)-(+)-(2,6-Dimethyl-3,5-dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine, min. 98% | 185449-86-9 | 500mg | $779 | 2024-03-01 | Buy |
American Custom Chemicals Corporation | ING0001353 | (S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE 95.00% | 185449-86-9 | 500MG | $1127.86 | 2021-12-16 | Buy |
Matrix Scientific | 090119 | N,N,2,6-Tetramethyldinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 95+% | 185449-86-9 | 1g | $1647 | 2021-12-16 | Buy |
AK Scientific | 9701AA | N,N,2,6-Tetramethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine | 185449-86-9 | 1g | $2273 | 2021-12-16 | Buy |
(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE Chemical Properties,Uses,Production
Description
1. Ligand used in the enantioselective, rhodium-catalyzed hydrogenation of substituted olefins, such as N-acetyldihydroamino acids, enamides, and unsaturated acids.
2. Ligand used in the enantioselective, iridium-catalyzed allylic substitution of allyl acetates containing only a single substituent in the 1 or 3 position.
3. Ligand use in the rhodium-catalyzed, amide directed, asymmetric hydroboration reaction.
4. Ligand used in asymmetric conjugate addition of aryl boronic acids to dihydronitronaphthalenes.
5. Ligand used in the rhodium-catalyzed asymmetric intramolecular 1,4 addition.
(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE Preparation Products And Raw materials
Raw materials
Preparation Products
(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE Suppliers
Global( 39)Suppliers
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18774 | 58 |
Hangzhou MolCore BioPharmatech Co.,Ltd. | +86-057181025280; +8617767106207 | sales@molcore.com | China | 49734 | 58 |
Shaoxin Catsyn Co., Ltd. | +undefined-0575-82040869 +86-0575-82040869; | sales@catsyn.com | China | 6114 | 58 |
Aladdin Scientific | +1-+1(833)-552-7181 | sales@aladdinsci.com | United States | 57505 | 58 |
J & K SCIENTIFIC LTD. | 010-82848833 400-666-7788 | jkinfo@jkchemical.com | China | 96815 | 76 |
Meryer (Shanghai) Chemical Technology Co., Ltd. | 021-61259108 18621169109 | market03@meryer.com | China | 40228 | 62 |
Daicel Chiral Technologies (China)CO.,LTD | 021-50460086-9 15921403865 | han_yajun@dctc.daicel.com | China | 7191 | 65 |
Tianjin Derchemist Science & Technology Co., Ltd. | 22-58627059 13920586291 | zdcomcon@126.com | China | 3461 | 50 |
Shanghai Incat Chemtech Co.,Ltd. | 021-57603038 13601791340 | 307593986@qq.com | China | 475 | 58 |
Bide Pharmatech Ltd. | 400-164-7117 13681763483 | product02@bidepharm.com | China | 41462 | 60 |
185449-86-9((S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE)Related Search:
(R)-MONOPHOS
(11bS)-N,N-dimethyl-2,6-diphenyl-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-
4-amine
3,4-a']dinaphthalen-4-yl)dipropylaMine
(11bS)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
(11bS)-8,9,10,11,12,13,14,15-octahydro-N,N-bis[(1S)-1-phenylethyl]-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-aMine
1of2
(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE
(S)-(+)-(2,6-Dimethyl-3,5-dioxa-4-phospha-cyclohepta[2,1-a
3,4-a']dinaphthalen-4-yl)dimethylamine,min.98%
3,4-a']dinaphthalen-4-yl)dimethylamine, min. 98%
N,N,2,6-Tetramethyldinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
(11bS)-N,N,2,6-tetraMethyl-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-aMine
3,4-a']dinaphthalen-4-yl)dimethylamine,98%
(11bS)-N,N,2,6-Tetramethyl-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine,99%e.e.
(S)-(+)-(2,6-Dimethyl-3,5-dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine, min. 98%
(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A;3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE,MIN.98%
Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N,N,2,6-tetramethyl-, (11bS)-
(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE
3,4-a'']dinaphthalen-4-yl)dimethylamine
(11bS)-N,N,2,6-Tetramethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
185449-86-9
C24H22NO2P
Chiral Phosphine
CPN