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3-Picoline-N-oxide

CAS No.
1003-73-2
Chemical Name:
3-Picoline-N-oxide
Synonyms
NSC 18254;3-picoline-oxide;β-Picoline Oxide;3-PICOLINE-N-OXIDE;B-Picoline-N-oxide;β-Picoline 1-oxide;3-Picoline, 1-oxide;BETA-PICOLINE-N-OXIDE;beta-Picoline 1-oxide;3-Methylpyrine-N-Oxide
CBNumber:
CB6688910
Molecular Formula:
C6H7NO
Molecular Weight:
109.13
MDL Number:
MFCD00006203
MOL File:
1003-73-2.mol
MSDS File:
SDS
Last updated:2024-07-25 20:04:51

3-Picoline-N-oxide Properties

Melting point 37-39 °C(lit.)
Boiling point 150 °C15 mm Hg(lit.)
Density 1.13
refractive index 1.5444 (estimate)
Flash point >230 °F
storage temp. Sealed in dry,Room Temperature
solubility >2000g/l
pka pK1:10.921(+1) (25°C)
form Crystalline Low Melting Mass
color Pale yellow to brown
Water Solubility soluble
Sensitive Hygroscopic
BRN 106327
CAS DataBase Reference 1003-73-2(CAS DataBase Reference)
FDA UNII YA9Q5YUG2M
NIST Chemistry Reference Pyridine, 3-methyl-, 1-oxide(1003-73-2)
EPA Substance Registry System Pyridine, 3-methyl-, 1-oxide (1003-73-2)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39-24/25-36
WGK Germany  1
RTECS  UT5799000
3-10
TSCA  Yes
HS Code  29333990
Toxicity mouse,LD50,intraperitoneal,1689mg/kg (1689mg/kg),Toxicon. Vol. 23, Pg. 815, 1985.
NFPA 704
1
2 0

3-Picoline-N-oxide price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical P0419 3-Methylpyridine N-Oxide >98.0%(GC) 1003-73-2 25g $132 2024-03-01 Buy
Alfa Aesar A12578 3-Picoline N-oxide, 98% 1003-73-2 100g $39 2021-12-16 Buy
Alfa Aesar A12578 3-Picoline N-oxide, 98% 1003-73-2 500g $121 2021-12-16 Buy
TRC P437215 3-Picoline1-Oxide 1003-73-2 10g $85 2021-12-16 Buy
TRC P437215 3-Picoline1-Oxide 1003-73-2 100g $105 2021-12-16 Buy
Product number Packaging Price Buy
P0419 25g $132 Buy
A12578 100g $39 Buy
A12578 500g $121 Buy
P437215 10g $85 Buy
P437215 100g $105 Buy

3-Picoline-N-oxide Chemical Properties,Uses,Production

Chemical Properties

PALE YELLOW TO BROWN CRYSTALLINE LOW MELTING MASS

Uses

An intermediate in the preparation of nicotine derivatives.

Purification Methods

Purify the N-oxide by careful fractionation in vacuo. The distillate remains supercooled for several days before solidifying. It is a slightly hygroscopic solid which could melt in the hand. The picrate has m 149-151o (from EtOH). [Taylor & Corvetti Org Synth Coll Vol IV 654 1963, IR: Katritzky et al. J Chem Soc 3680 1959, Jaffé & Doak J Am Chem Soc 77 4441, 4481 1955, Boekelheide & Linn J Am Chem Soc 76 1286 1954]. [Beilstein 20 III/IV 2719, 20/5 V 517.]

Global( 335)Suppliers
Supplier Tel Email Country ProdList Advantage
Shaanxi Dideu Medichem Co. Ltd
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Frapp's ChemicalNFTZ Co., Ltd.
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View Lastest Price from 3-Picoline-N-oxide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
3-Picoline-N-oxide pictures 2024-07-25 3-Picoline-N-oxide
1003-73-2
US $0.00-0.00 / KG 1KG 99.0% 1000KG Shaanxi Dideu Medichem Co. Ltd
3-Picoline-N-oxide pictures 2020-01-09 3-Picoline-N-oxide
1003-73-2
US $1.00 / KG 1KG 98% HPLC 10 tons/month Career Henan Chemical Co
3-Methylpyridin-N-oxid BETA-PICOLINE-N-OXIDE 3-Methylpyrine-N-Oxide 3-methyl-pyridin1-oxide 3-Picoline, 1-oxide 3-picoline-oxide beta-Picoline 1-oxide N-oxideof3-methylpyridine Pyridine,3-methyl-,1-oxide 3-METHYLPYRIDINE 1-OXIDE 3-METHYLPYRIDINE N-OXIDE 3-PICOLINE-N-OXIDE B-Picoline-N-oxide 3-PICOLINE-N-OXIDE 95+% BETA PICOLINE OXIDE, 97% Beta-picoline N-oxide, 3-Picoline N-oxide β-Picoline 1-oxide 3-Picoline-N-oxide,98% -methyl-pyridin1-oxide 3-Methyl-pyridine oxide NSC 18254 β-Picoline Oxide 3-Picoline N-oxide/ 3-Methylpyridine-n-oxide 3-Methylpyridine N-oxide 98% 3-Methylpyridine 1-oxide for synthesis 3-MethylpyridineN-Oxide> 1003-73-2 180-99-6 C6 Building Blocks Heterocyclic Building Blocks Pyridines Heterocyclic Compounds Pyridines Building Blocks C6 Chemical Synthesis Heterocyclic Building Blocks Aromatics Heterocycles Intermediates Pyridine