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TERT-BUTYL 4-BROMOBENZYLCARBAMATE

CAS No.
68819-84-1
Chemical Name:
TERT-BUTYL 4-BROMOBENZYLCARBAMATE
Synonyms
N-BOC-4-broMobenzylaMine;4-Bromo-N-BOC-benzylamine;TERT-BUTYL 4-BROMOBENZYLCARBAMATE;tert-Butyl N-(4-bromobenzyl)carbamate;tert-Butyl 4-bromobenzylcarbamate 98%;tert-butyl N-[(4-bromophenyl)methyl]carbamate;N-(4-Bromobenzyl)carbamic acid tert-butyl ester;(4-BROMO-BENZYL)-CARBAMIC ACID TERT-BUTYL ESTER;Carbamic acid, (4-bromophenyl)methyl-, 1,1-dimethylethyl ester;N-[(4-Bromophenyl)methyl]-carbamic acid 1,1-dimethylethyl ester
CBNumber:
CB6838195
Molecular Formula:
C12H16BrNO2
Molecular Weight:
286.16
MDL Number:
MFCD08703140
MOL File:
68819-84-1.mol
Last updated:2024-01-09 16:41:59

TERT-BUTYL 4-BROMOBENZYLCARBAMATE Properties

Melting point 86-88℃
Boiling point 374.3±25.0 °C(Predicted)
Density 1.319±0.06 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
form solid
pka 12.05±0.46(Predicted)
color Off-white

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H319-H335-H302+H312+H332-H315
Precautionary statements  P280-P301+P312-P362+P364
Hazard Codes  Xn
Risk Statements  22
HS Code  2924297099

TERT-BUTYL 4-BROMOBENZYLCARBAMATE price More Price(38)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC B694555 tert-Butyl4-Bromobenzylcarbamate 68819-84-1 100mg $60 2021-12-16 Buy
Biosynth Carbosynth FB155794 tert-Butyl 4-bromobenzylcarbamate 68819-84-1 1g $80 2021-12-16 Buy
ChemScene CS-W005364 tert-Butyl4-bromobenzylcarbamate 99.98% 68819-84-1 10g $110 2021-12-16 Buy
Biosynth Carbosynth FB155794 tert-Butyl 4-bromobenzylcarbamate 68819-84-1 2g $130 2021-12-16 Buy
Apolloscientific OR315540 tert-Butyl4-bromobenzylcarbamate 98% 68819-84-1 5g $166 2021-12-16 Buy
Product number Packaging Price Buy
B694555 100mg $60 Buy
FB155794 1g $80 Buy
CS-W005364 10g $110 Buy
FB155794 2g $130 Buy
OR315540 5g $166 Buy

TERT-BUTYL 4-BROMOBENZYLCARBAMATE Chemical Properties,Uses,Production

Synthesis

Tert-Butyl 4-bromobenzylcarbamate is prepared by the reaction of di-tert-butyl dicarbonate and 4-bromobenzylamine hydrochloride. The specific synthesis steps are as follows:
To a stirred suspension of 4-bromo-benzylamine hydrochloride (968mg, 4.35mmol) and triethylamine (0.666ml, 4.79mmol) in chloroform (15ml) was added di-tert-butyldicarbonate (949mg, 4.35mmol). The resulting solution was stirred at ambient temperature for 2h and then diluted with DCM (40ml). The organic solution was washed sequentially with 10% aqueous citric acid (40ml) and brine (40ml). The organic phase was dried over anhydrous magnesium sulfate and the filtrate evaporated at reduced pressure to afford Tert-Butyl 4-bromobenzylcarbamate (1.23g, 99%). 1H NMR 7.48-7.43 (2H, m), 7.18 (2H, d, 8.4), 4.84 (1H, br s), 4.27 (2H, d, 5.7), 1.46 (9H, s).
TERT-BUTYL 4-BROMOBENZYLCARBAMATE synthesis

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View Lastest Price from TERT-BUTYL 4-BROMOBENZYLCARBAMATE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
TERT-BUTYL 4-BROMOBENZYLCARBAMATE pictures 2020-01-03 TERT-BUTYL 4-BROMOBENZYLCARBAMATE
68819-84-1
US $1.00 / KG 1KG 99% 100KG Career Henan Chemical Co
TERT-BUTYL 4-BROMOBENZYLCARBAMATE Carbamic acid, (4-bromophenyl)methyl-, 1,1-dimethylethyl ester (4-BROMO-BENZYL)-CARBAMIC ACID TERT-BUTYL ESTER 4-Bromo-N-BOC-benzylamine N-(4-Bromobenzyl)carbamic acid tert-butyl ester tert-Butyl N-(4-bromobenzyl)carbamate Carbamic acid, N-[(4-bromophenyl)methyl]-, 1,1-dimethylethyl ester tert-Butyl 4-bromobenzylcarbamate 98% tert-butyl N-[(4-bromophenyl)methyl]carbamate N-BOC-4-broMobenzylaMine N-[(4-Bromophenyl)methyl]-carbamic acid 1,1-dimethylethyl ester 68819-84-1 amine|alkyl bromide| carboxylic ester