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2-Naphthol-6,8-disulfonic acid

CAS No.
118-32-1
Chemical Name:
2-Naphthol-6,8-disulfonic acid
Synonyms
-Naphthol-disulphonicacid;β-Naphtholdisulfonic acid;2-NAPHTHOL-6,8-DISULFONIC ACID;NAPHTHOL-6,8-DIPOTASSIUMDISUFONATE;7-hydroxy-3-naphthalenedisulfonicacid;7-hydroxynaphthalene-1,3-disulfonicaci;7-Hydroxy-1,3-naphthalenedisulfonicacid;2-Hydroxynaphthalene-6,8-disulfonicacid;7-hydroxynaphthalene-1,3-disulfonic acid;7-hydroxynaphthalene-1,3-disulphonicacid
CBNumber:
CB6838933
Molecular Formula:
C10H8O7S2
Molecular Weight:
304.3
MDL Number:
MFCD00021514
MOL File:
118-32-1.mol
MSDS File:
SDS
Last updated:2024-12-18 14:08:57

2-Naphthol-6,8-disulfonic acid Properties

Boiling point 415.13°C (rough estimate)
Density 1.7421 (rough estimate)
refractive index 1.6000 (estimate)
form solid
pka -0.33±0.40(Predicted)
color Off-white
FDA UNII 5995F5R8Y9
EPA Substance Registry System 1,3-Naphthalenedisulfonic acid, 7-hydroxy- (118-32-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H319-H335-H302+H312+H332-H315
Precautionary statements  P280-P301+P312-P362+P364
HS Code  2904100090

2-Naphthol-6,8-disulfonic acid price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Arctom AS028882 7-Hydroxynaphthalene-1,3-disulfonicacid 96% 118-32-1 250mg $24 2021-12-16 Buy
Arctom AS028882 7-Hydroxynaphthalene-1,3-disulfonicacid 96% 118-32-1 1g $58 2021-12-16 Buy
Arctom AS028882 7-Hydroxynaphthalene-1,3-disulfonicacid 96% 118-32-1 5g $161 2021-12-16 Buy
Chemenu CM140985 7-hydroxynaphthalene-1,3-disulfonicacid 97% 118-32-1 100g $704 2021-12-16 Buy
Crysdot CD44000712 7-Hydroxynaphthalene-1,3-disulfonicacid 97% 118-32-1 100g $753 2021-12-16 Buy
Product number Packaging Price Buy
AS028882 250mg $24 Buy
AS028882 1g $58 Buy
AS028882 5g $161 Buy
CM140985 100g $704 Buy
CD44000712 100g $753 Buy

2-Naphthol-6,8-disulfonic acid Chemical Properties,Uses,Production

Chemical Properties

2-Hydroxynaphthalene-6,8-disulfonic acid [118-32-1]. (7-hydroxynaphthalene-1,3- disulfonic acid), G acid, C10H8O7S2, Mr 304.3: most salts of 55 are more readily soluble in water than those of R acid, with the notable exception of the potassium salt. Sulfonation with 20 % oleum at 100℃ yields 2-hydroxynaphthalene3,6,8-trisulfonic acid. Diazo coupling takes place in the 1-position, although the reaction is sluggish, as in the case of 2-hydroxynaphthalene8-sulfonic acid.

Uses

The G acid is aminated (Bucherer reaction) to give 2-aminonaphthalene-6,8- disulfonic acid and subjected to caustic fusion at 200℃ to yield 2,8-dihydroxynaphthalene-6-sulfonic acid (a precursor of g acid). It is also used as a coupling component for a wide range of azo colorants, e.g., C.I. Acid Orange 10, C.I. Acid Red 187, and C.I. Food Red 7.

Production Methods

2-Naphthol is added to 98 % sulfuric acid at 40℃. Then, 20 % oleum is added over 6 h and the temperature is allowed to rise to 60℃. The reaction is completed by heating for a further 16 h at 60℃ followed by 15 h at 80℃. After the reaction mixture has been poured into water, potassium chloride is added to the hot solution and the batch is cooled slowly to 35℃ before filtering off the crystalline dipotassium salt of G acid and carefully washing out any residual R salt; the yield is 60 %. In addition, R salt can be recovered from the filtrate in 12 % yield after conversion to its sodium salt.

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7-Hydroxy-1,3-naphthalenedisulfonicacid 7-hydroxy-3-naphthalenedisulfonicacid 7-hydroxynaphthalene-1,3-disulphonicacid -Naphthol-disulphonicacid 2-NAPHTHOL-6,8-DISULFONIC ACID 7-hydroxynaphthalene-1,3-disulfonic acid 2-Hydroxynaphthalene-6,8-disulfonicacid NAPHTHOL-6,8-DIPOTASSIUMDISUFONATE β-Naphtholdisulfonic acid 1,3-Naphthalenedisulfonicacid, 7-hydroxy- 7-hydroxynaphthalene-1,3-disulfonic acid hydrate 2-NAPHTHOL-6 8-DISULFONIC ACID ( G SALT ) TIANFUCHEM--High purity 118-32-1 2-Naphthol-6,8-disulfonic acid 7-hydroxynaphthalene-1,3-disulfonicaci 118-32-1 C10H6O7S2K2 Intermediates of Dyes and Pigments