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ChemicalBook >> CAS DataBase List >>(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny

(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny

(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny Structure
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny structure
CAS No.
352655-61-9
Chemical Name:
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny
Synonyms
(R)-3,5-t-Bu-4-MeO-MeOBIPHEP;SL-A109-1;-diyl)bis[bis(3，5-di-tert-butyl-4-methoxyphenyl)phosphine;(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny;(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny;(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine;(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl;(R)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine];(S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine];(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl
CBNumber:
CB6972437
Molecular Formula:
C74H104O6P2
Molecular Weight:
1151.56
MDL Number:
MFCD09265029
MOL File:
352655-61-9.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06
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(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny Properties

Boiling point 951.5±65.0 °C(Predicted)
form crystal
color white

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352-P305+P351+P338
WGK Germany  3
HS Code  29319090

(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny price More Price(18)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Strem Chemicals 15-0042 (R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97% 352655-61-9 100mg $74 2021-12-16 Buy
Strem Chemicals 15-0042 (R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97% 352655-61-9 500mg $278 2021-12-16 Buy
Strem Chemicals 15-0042 (R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97% 352655-61-9 2g $946 2021-12-16 Buy
Strem Chemicals 15-0042 (R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97% 352655-61-9 10g $3784 2021-12-16 Buy
American Custom Chemicals Corporation ING0001277 (R)-(-)-2,2'-BIS[DI(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL 95.00% 352655-61-9 500MG $914.17 2021-12-16 Buy
Product number Packaging Price Buy
15-0042 100mg $74 Buy
15-0042 500mg $278 Buy
15-0042 2g $946 Buy
15-0042 10g $3784 Buy
ING0001277 500MG $914.17 Buy

(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny Chemical Properties,Uses,Production

Reaction

  1. Rh-catalyzed reductive coupling of acetylene to aldehydes and ketones.
  2. Pt-catalyzed intramolecular hydroarylation of unactivated alkenes with indoles.
  3. Enantioselective C-C bond activation of allenyl cyclobutanes.
  4. Enantioselective ring-opening of rac-ethynyl epoxides.
  5. Enantioselective Au-catalyzed allylic alkylation of indoles with alcohols.
  6. Enantioselective Rh-catalyzed conjugate alkynylation with TMS-acetylene.
  7. Enantioselective Rh-catalyzed [3+2] annulation of aromatic ketimines.
  8. Asymmetric Rh-catalyzed Pausan-Khand reaction. 
Reactions of 352655-61-9_1
Reactions of 352655-61-9_2
Reactions of 352655-61-9_3

Chemical Properties

Off-white powder

Uses

Atropisomeric MeOBIPHEP ligands

  • Asymmetrical conjugate addition of arylboronic acids to maleimides and enones catalyzed by rhodium complexes
  • Intramolecular ketone hydroacylation
  • Desymmetrization through enantioselective C-C bond activation and ring expansion of allenyl cyclobutanols
  • Hydroamination of bicyclic alkenes and dienes with anilines
  • 1,4-addition/asymmetric protonation of amino acrylates

General Description

sold in collaboration with Solvias AG

(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny Suppliers

Global( 27)Suppliers
Supplier Tel Email Country ProdList Advantage
Zhengzhou Alfa Chemical Co.,Ltd 		+8618530059196 sale04@alfachem.cn China 13482 58
Aladdin Scientific 		+1-+1(833)-552-7181 sales@aladdinsci.com United States 57505 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44689 61
Bide Pharmatech Ltd. 400-164-7117 13681763483 product02@bidepharm.com China 41462 60
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51456 80
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. 0371-65511006 18625597674 sales@kingorgchem.com China 953 55
LaaJoo 021-60702684 18516024827 huang.jiayi@sinocompound.com China 2603 58
Aikon International Limited 025-66113011 18112977050 sales01@aikonchem.com China 16027 58
Tianjin heowns Biochemical Technology Co., Ltd. 400-6387771-6038 18902104717 sales@heowns.com China 21085 60
Supplier Advantage
Zhengzhou Alfa Chemical Co.,Ltd 		58
Aladdin Scientific 		58
J & K SCIENTIFIC LTD. 76
Energy Chemical 61
Bide Pharmatech Ltd. 60
Sigma-Aldrich 80
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. 55
LaaJoo 58
Aikon International Limited 58
Tianjin heowns Biochemical Technology Co., Ltd. 60

352655-61-9((R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny)Related Search:

(S)-H8-BINAP (R)-DM-BINAP (R)-DIFLUORPHOS(TM) (S)-SunPhos (S)-(+)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
(R)-(+)-TolBINAP R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (R)-SEGPHOS
(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% (S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS (R)-H8-BINAP (R)-DIFLUORPHOS(TM) (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
(S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(S)-DTBM-SEGPHOS (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny Chloro[(R)-(-)5,5μ-bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-4,4μ-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride

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(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny (R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% (R)-(-)-2,2''-BIS[DI(3,5-DI-T-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97% (S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine] (S)-3,5-t-Bu-4-MeO-MeOBIPHEP, SL-A109-2, (S)-[6,6μ-Dimethoxy(1,1μ-biphenyl)-2,2μ-diyl]bis{bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]phosphine} (R)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine] (R)-3,5-t-Bu-4-MeO-MeOBIPHEP, SL-A109-1, (R)-[6,6μ-Dimethoxy(1,1μ-biphenyl)-2,2μ-diyl]bis{bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]phosphine} (R)-(-)-2,2'-Bis[di-(3,5-di-tert-butyl-4-methoxy-phenyl)phosphino]-(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl SL-A109-1 (R)-(-)-2,2'-Bis[di-(3,5-di-t-butyl-4-methoxy- phenyl)phosphino]-(diphenylphosphino)-6,6'- dimethoxy-1,1'-biphenyl (R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl (R)-(6,6'-DiMethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-Methoxyphenyl)phosphine] >=97%, optical purity ee: >=99% Phosphine, 1,1'-[(1R)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]- (R)-2,2'-Bis[bis(3,5-di-tert-butyl-4-methoxyphenyl) phosphino]-6,6'-dimethoxy-1,1'-biphenyl (R)-3,5-t-Bu-4-MeO-MeOBIPHEP -diyl)bis[bis(3，5-di-tert-butyl-4-methoxyphenyl)phosphine (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny (R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine 352655-61-9 C74H104O6P2 Chiral Phosphine MeOBIPHEP Series