ChemicalBook >> CAS DataBase List >>Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos] 

Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos] 

CAS No.
944450-49-1
Chemical Name:
Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos] 
Synonyms
Ru(OAc)2((R)-dm-segphos);(R)-Rutheniumdiacetate-(DM-SEGPHOS);Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos;Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos] ;Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos(R)];Ruthenium, bis(acetato-κO,κO')[1,1'-(4R)-[4,4'-bi-1,3-benzodioxole]-5,5'-diylbis[1,1-bis(3,5-dimethylphenyl)phosphine-κP]]-, (OC-6-22)-;Ruthenium DiacetateQ: What is Ruthenium Diacetate Q: What is the CAS Number of Ruthenium Diacetate Q: What is the storage condition of Ruthenium Diacetate
CBNumber:
CB72512470
Molecular Formula:
C50H52O8P2Ru
Molecular Weight:
943.98
MDL Number:
MFCD09753025
MOL File:
944450-49-1.mol
Last updated:2023-05-04 15:14:50

Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos]  Properties

Melting point >100°C
form solid
color yellow to brownish-red to dark green
Sensitive air sensitive

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H335-H319
Precautionary statements  P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P

Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos]  price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Strem Chemicals 44-0174 Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos(R)] 944450-49-1 250mg $64 2024-03-01 Buy
Strem Chemicals 44-0174 Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos(R)] 944450-49-1 1g $190 2024-03-01 Buy
Strem Chemicals 44-0174 Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos(R)] 944450-49-1 5g $436 2024-03-01 Buy
TRC R701850 (R)-Rutheniumdiacetate-(DM-SEGPHOS) 944450-49-1 100mg $165 2021-12-16 Buy
Medical Isotopes, Inc. 66980 (R)-Rutheniumdiacetate-(DM-SEGPHOS) 944450-49-1 100mg $650 2021-12-16 Buy
Product number Packaging Price Buy
44-0174 250mg $64 Buy
44-0174 1g $190 Buy
44-0174 5g $436 Buy
R701850 100mg $165 Buy
66980 100mg $650 Buy

Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos]  Chemical Properties,Uses,Production

Reaction

  1. Biaryl bisphosphine ligand with narrow dihedral angle. The DM-SEGPHOS ligand, as the ruthenium complex, gives superior enantioselectivity and diastereoselectivity in the asymmetric hydrogenation of α-substituted-β-ketoesters. 
  2. Ruthenium catalyzed enantioselective synthesis of β amino acids by hydrogenation.
  3. Ruthenium catalyzed asymmetric hydrogenation of 3-quinuclidinone. 
Reactions of 944450-49-1

Uses

(R)-Rutheniumdiacetate-(DM-SEGPHOS) is a coordination compound used for the direct asymmetric reductive amination.

Uses

Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos] is a coordination compound used for the direct asymmetric reductive amination.

Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos]  Preparation Products And Raw materials

Raw materials

Preparation Products

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Energy Chemical 021-58432009 400-005-6266 marketing@energy-chemical.com China 44918 58
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Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos]  (R)-Rutheniumdiacetate-(DM-SEGPHOS) Ru(OAc)2((R)-dm-segphos) Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos(R)] Ruthenium, bis(acetato-κO,κO')[1,1'-(4R)-[4,4'-bi-1,3-benzodioxole]-5,5'-diylbis[1,1-bis(3,5-dimethylphenyl)phosphine-κP]]-, (OC-6-22)- Ruthenium DiacetateQ: What is Ruthenium Diacetate Q: What is the CAS Number of Ruthenium Diacetate Q: What is the storage condition of Ruthenium Diacetate Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos 944450-49-1