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2,4-Dimethyl aniline

CAS No.
95-68-1
Chemical Name:
2,4-Dimethyl aniline
Synonyms
2,4-DIMETHYLANILINE;2,4-XYLIDINE;Benzenamine, 2,4-dimethyl-;M-XYLIDINE;m-4-Xylidine;meta-xylidine;2,4-Xylylamine;2.4-DiMethylan;ASYM-M-XYLIDINE;4-AMINO-M-XYLENE
CBNumber:
CB7278882
Molecular Formula:
C8H11N
Molecular Weight:
121.18
MDL Number:
MFCD00007738
MOL File:
95-68-1.mol
MSDS File:
SDS
Last updated:2023-11-28 16:31:44

2,4-Dimethyl aniline Properties

Melting point 16 °C
Boiling point 218 °C(lit.)
Density 0.98 g/mL at 25 °C(lit.)
vapor density 4.2 (vs air)
vapor pressure 0.16 mm Hg ( 25 °C)
refractive index n20/D 1.558(lit.)
Flash point 195 °F
storage temp. room temp
solubility 5g/l
form Liquid
pka pK1:4.89(+1) (25°C)
color Clear yellow to red-brown
Odor Amine like
PH 7 (22g/l, H2O, 20℃)
explosive limit 1.1-7.0%(V)
Water Solubility 5 g/L (20 ºC)
Merck 14,10084
BRN 636243
Dielectric constant 4.9000000000000004
Stability Stable. Combustible. Incompatible with strong oxidizing agents, acids, acid anhydrides, acid chlorides, chloroformates, halogens.
LogP 2.02 at 23℃ and pH8
CAS DataBase Reference 95-68-1(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 367R1L22C9
IARC 3 (Vol. 16, Sup 7) 1987
NIST Chemistry Reference Benzenamine, 2,4-dimethyl-(95-68-1)
EPA Substance Registry System 2,4-Dimethylaniline (95-68-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H301+H311+H331-H373-H411
Precautionary statements  P273-P280-P301+P310-P302+P352+P312-P304+P340+P311-P314
Hazard Codes  T,N
Risk Statements  23/24/25-33-51/53
Safety Statements  28-36/37-45-61-28A
RIDADR  UN 1711 6.1/PG 2
WGK Germany  2
RTECS  ZE8925000
8
Autoignition Temperature 860 °F
TSCA  Yes
HazardClass  6.1
PackingGroup  II
HS Code  29214910
NFPA 704
1
3 0

2,4-Dimethyl aniline price More Price(19)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 442315 2,4-Dimethylaniline analytical standard 95-68-1 1000mg $27.6 2024-03-01 Buy
Sigma-Aldrich 240915 2,4-Dimethylaniline ≥99% 95-68-1 50g $87.7 2024-03-01 Buy
TCI Chemical D0667 2,4-Dimethylaniline >98.0%(GC)(T) 95-68-1 25mL $32 2024-03-01 Buy
TCI Chemical D0667 2,4-Dimethylaniline >98.0%(GC)(T) 95-68-1 500mL $212 2024-03-01 Buy
TRC X749690 2,​4-​Dimethylaniline(2,4-Xylidine) 95-68-1 10g $55 2021-12-16 Buy
Product number Packaging Price Buy
442315 1000mg $27.6 Buy
240915 50g $87.7 Buy
D0667 25mL $32 Buy
D0667 500mL $212 Buy
X749690 10g $55 Buy

2,4-Dimethyl aniline Chemical Properties,Uses,Production

Chemical Properties

colourless to yellow or dark brown liquid

Uses

2,4-Xylidine, as part of the commercial mixture, has the same uses as xylidine.

Definition

ChEBI: A primary arylamine that is aniline in which the hydrogens at the 2- and 4-positions are replaced by methyl groups. A clear to yellow liquid, it is used in production of certain dyes, pesticides and other chemicals.

General Description

Dark brown liquid.

Air & Water Reactions

2,4-Dimethyl aniline may be sensitive to prolonged exposure to air. Slightly soluble in water.

Reactivity Profile

2,4-Dimethyl aniline ignites on contact with fuming nitric acid . Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Fire Hazard

2,4-Dimethyl aniline is combustible.

Safety Profile

Suspected carcinogen. Poison by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also other xylidine entries.

Metabolic pathway

The major urinary metabolite of 2,4-dimethylaniline (2,4-DMA) in rats is N-acetyl-4-amino-3-methylbenzoic acid, while in dogs, it is 6-hydroxy-2,4-dimethylaniline. Dogs also produce a smaller amount of unacetylated 4-amino-3-methylbenzoic acid and its glycine conjugate. 2,6-Dimethylaniline (2,6-DMA) is metabolized principally to 4-hydroxy-2,6- dimethylaniline in both species, but dogs also produce a significant quantity of 2-amino-3-methylbenzoic acid along with a trace amount of the glycine conjugate of the latter metabolite and 2,6-dimethylnitrosobenzene. Trace levels of an unknown postulated to be 3,5- dimethyl-4-iminoquinone are found in dog urine.

Purification Methods

Convert uns-xylidine to a derivative (see below) which, after recrystallisation, is decomposed with alkali to give the free base. Dry it over KOH and fractionally distil. The acetyl derivative has m 130o, the benzoyl derivative has m 192o, and the picrate has m 209o. [Beilstein 12 H 1111, 12 IV 2545.]

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View Lastest Price from 2,4-Dimethyl aniline manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2,4-Dimethyl aniline pictures 2024-11-25 2,4-Dimethyl aniline
95-68-1
US $0.00 / Kg/Drum 1Kg/Drum 99% 2000mt/year Jinan Finer Chemical Co., Ltd
2,4-Dimethyl aniline pictures 2024-10-25 2,4-Dimethyl aniline
95-68-1
US $0.00-0.00 / kg 1kg 99% 20 tons Hebei Yanxi Chemical Co., Ltd.
2,4-Dimethylaniline pictures 2024-10-25 2,4-Dimethylaniline
95-68-1
US $1.00 / Kg/Drum 5T 99% 1000tons/month Hebei Yanxi Chemical Co., Ltd.
2,4-dimethyl-anilin 2,4-dimethyl-benzenamin 2,4-Dimethylbenzenamine 2,4-dimethyl-Benzenamine 2,4-Dimethylbenzeneamine 2,4-Dimethylphenylamine 2,4-Xylylamine 4-Amino-1,3-xylene Aniline, 2,4-dimethyl- m-4-Xylidine meta-xylidine 2-METHYL-P-TOLUIDINE AKOS BBS-00003656 LABOTEST-BB LTBB000473 ASYM-M-XYLIDINE M-XYLIDINE 2,4-DIMETHYLAMINOBENZENE 1-AMINO-2,4-DIMETHYLBENZENE 4-METHYL-O-TOLUIDINE 4-AMINO-3-METHYLTOLUENE 4-AMINO-1,3-DIMETHYLBENZENE 4-AMINO-M-XYLENE 2,4-Xylidine (NH2=1) 2,4-DIMETHYLANILINE, 1000MG, NEAT 2,4-DIMETHYLANILINE, 99+% 2,4-dimethylanilione 2,4-DIMETHYLENZAMINE 2-methyl-p-toluidin 2,4-Dimethylaniline,1-Amino-2,4-dimethylbenzene, 2,4-Xylidine, 4-Amino-m-xylene 2,4-DiMethylaniline, 99% 100GR 2,4-DIMETHYLANILINE pure 1-Amino-2,4-dimethylbenzene, 2,4-Xylidine, 4-Amino-m-xylene 2,4-Xylidine m-Xylidine 2,4-two Methyl aniline 2.4-DiMethylan 2,4-Dimethylaniline Solution, 100ppm 4-Amino-m-xylene, 2,4-Xylidine 2,4-Dimethylaniline Solution, 1000ppm 2,4-Dimethylaniline > 2,4-DimethylanilineSolution,2000mg/L,1ml 2,4-DimethylanilineSolution,100mg/L,5x1ml 2,4-DimethylanilineSolution(SecondSource),2000mg/L,1ml 2,4-DimethylanilineSolution,100mg/L,1ml 2,4-Dimethyl aniline ISO 9001:2015 REACH TIANFU-CHEM -2,4-Dimethyl aniline 2,4 -XYLIDINE Extra Pure 2,4-DIMETHYLANILINE 2,4-XYLIDINE Benzenamine, 2,4-dimethyl- Amitraz Impurity A Amitraz EP Impurity A Vortioxetine Impurity 66 Zeatin Impurity 7 2,4-Dimethylaniline 100 μg/ml Acetonitrile 2,4-Dimethylaniline 100 μg/ml Methanol L12724500CY 2,4-DimethylanilinE10μg/mLin Cyc C12724500 2,4-Dimethylaniline XA12724500AL2,4-DimethylanilinE100μg/mLin Ac