ChemicalBook >> CAS DataBase List >>5-Bromo-2-methylpyridine
5-Bromo-2-methylpyridine
- CAS No.
- 3430-13-5
- Chemical Name:
- 5-Bromo-2-methylpyridine
- Synonyms
- 5-BROMO-2-PICOLINE;5-BROMOPICOLINE;3-BROMO-6-PICOLINE;2-Methyl-5-bromopyrid;5-Bromo-2-picoline,99%;5-BROMO-2-METHYLPYRIDINE;3-BROMO-6-METHYLPYRIDINE;2-METHYL-5-BROMOPYRIDINE;5-broMo-1-Methylpyridine;5-bormo-2-methylpyridine
- CBNumber:
- CB7327298
- Molecular Formula:
- C6H6BrN
- Molecular Weight:
- 172.02
- MDL Number:
- MFCD00661170
- MOL File:
- 3430-13-5.mol
- MSDS File:
- SDS
Last updated:2024-11-12 15:22:20
| Melting point | 32-36 °C |
|---|---|
| Boiling point | 74 °C / 17mmHg |
| Density | 1.494±0.06 g/cm3(Predicted) |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Chloroform (Slightly), Ethyl Acetate (Slightly) |
| form | Solid |
| pka | 3.59±0.10(Predicted) |
| color | Off-White to Light Yellow |
| BRN | 107324 |
| InChI | InChI=1S/C6H6BrN/c1-5-2-3-6(7)4-8-5/h2-4H,1H3 |
| InChIKey | OFKWIQJLYCKDNY-UHFFFAOYSA-N |
| SMILES | C1(C)=NC=C(Br)C=C1 |
| CAS DataBase Reference | 3430-13-5(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS07,GHS06 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335-H301-H311-H332 | |||||||||
| Precautionary statements | P261-P305+P351+P338-P301+P310a-P405-P501a-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313 | |||||||||
| Hazard Codes | Xi,Xn | |||||||||
| Risk Statements | 36/37/38-20/21/22 | |||||||||
| Safety Statements | 26-36-36/37/39 | |||||||||
| WGK Germany | 3 | |||||||||
| HazardClass | IRRITANT | |||||||||
| HS Code | 29333990 | |||||||||
| NFPA 704 |
|
5-Bromo-2-methylpyridine price More Price(31)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | B2572 | 5-Bromo-2-methylpyridine >98.0%(GC) | 3430-13-5 | 1g | $19 | 2024-03-01 | Buy |
| TCI Chemical | B2572 | 5-Bromo-2-methylpyridine >98.0%(GC) | 3430-13-5 | 5g | $58 | 2024-03-01 | Buy |
| Alfa Aesar | H27085 | 5-Bromo-2-methylpyridine, 98% | 3430-13-5 | 250mg | $44.3 | 2023-06-20 | Buy |
| Alfa Aesar | H27085 | 5-Bromo-2-methylpyridine, 98% | 3430-13-5 | 1g | $84.4 | 2023-06-20 | Buy |
| TRC | B685590 | 5-Bromo-2-picoline | 3430-13-5 | 50g | $1390 | 2021-12-16 | Buy |
5-Bromo-2-methylpyridine Chemical Properties,Uses,Production
Description
It is an important intermediate in the organic synthesis, which has many applications, such as pharmaceutical intermediate, organic synthesis, organic solvent, production of dyes, pesticide, and spice. Specifically, this chemical can act as the raw material to prepare 2:2’-dipyridyl and its derivatives.1 Moreover, this compound may be involved in the synthesis of biaryls through a one-pot tandem borylation/Suzuki-Miyaura cross-coupling reaction catalyzed by a palladacycle.2 In addition, 5-bromo-2-methylpyridine has been demonstrated to function as the substrate in a general palladium-catalyzed coupling of aryl bromides/triflates and thiols.3 Besides, this substance can facilitate the synthesis of 5-arylamino-2-picolines via displacement of bromide by anthranilic acid and decarboxylation.4
Referrence
- Willink, H. D. T.; Wibaut, J. P., The preparation of 2 : 2'-dipyridyl and some of its derivatives. Recueil Des Travaux Chimiques Des Pays-Bas 1935, 54, 275-283.
- Wang, L. H.; Cui, X. L.; Li, J. Y.; Wu, Y. S.; Zhu, Z. W.; Wu, Y. J., Synthesis of Biaryls through a One-Pot Tandem Borylation/Suzuki-Miyaura Cross-Coupling Reaction Catalyzed by a Palladacycle. Eur. J. Org. Chem. 2012, 595-603.
- Itoh, T.; Mase, T., A general palladium-catalyzed coupling of aryl bromides/triflates and thiols. Org. Lett. 2004, 6, 4587-4590.
- Louis H. Peterson; Tolman, R. L., Reinvestigation of the synthesis of 5-arylamino-2-picolines J. Heterocycl. Chem. 1977.
Chemical Properties
Light yellow Cryst
Uses
5-Bromo-2-picoline is a halogenated pyridine derivative used is a building block in the preparation of nitrogen containing heterocyclic compounds.
5-Bromo-2-methylpyridine Preparation Products And Raw materials
Raw materials
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Preparation Products
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Global( 543)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Terma Medicare India Pvt.,Ltd | +8613916485955 | shivshanghai@yahoo.com | India | 150 | 58 |
| Hebei Weibang Biotechnology Co., Ltd | +8615531157085 | abby@weibangbio.com | China | 8812 | 58 |
| Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 | sales1@chuanghaibio.com | China | 5893 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20287 | 58 |
| Frapp's ChemicalNFTZ Co., Ltd. | +86 (576) 8169-6106 | sales@frappschem.com | China | 880 | 50 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29791 | 60 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21634 | 55 |
| Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3009 | 60 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32957 | 60 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29882 | 58 |
View Lastest Price from 5-Bromo-2-methylpyridine manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-11-22 | 5-Bromo-2-methylpyridine
3430-13-5
|
US $0.00 / KG | 1KG | 98%min | 30tons/month | WUHAN FORTUNA CHEMICAL CO., LTD | |
 |
2024-11-12 | 5-Bromo-2-methylpyridine
3430-13-5
|
US $10.00 / KG | 1KG | 99% | 10 mt | Hebei Weibang Biotechnology Co., Ltd | |
 |
2024-10-11 | 5-Bromo-2-methylpyridine
3430-13-5
|
US $9.00 / KG | 1KG | 99.9 | 1 ton | Hebei Chuanghai Biotechnology Co,.LTD |
-
- 5-Bromo-2-methylpyridine
3430-13-5
- US $0.00 / KG
- 98%min
- WUHAN FORTUNA CHEMICAL CO., LTD
-
- 5-Bromo-2-methylpyridine
3430-13-5
- US $10.00 / KG
- 99%
- Hebei Weibang Biotechnology Co., Ltd
-
- 5-Bromo-2-methylpyridine
3430-13-5
- US $9.00 / KG
- 99.9
- Hebei Chuanghai Biotechnology Co,.LTD
3430-13-5(5-Bromo-2-methylpyridine)Related Search:
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5-Bromo-2-methylpyridine 98%
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5-Bromo-2-picoline,99%
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5-Bromo-2-methylpyridine ,99%
5-BROMO-2-METHYLPYRIDINE (5-BROMO-2-PICOLINE)
5-BROMO-2-PICOLINE5-BROMO-2-METHYLPYRIDINE
5-BroMo-2-picoline, 99% 1GR
5-Bromo-2-methylpyridine >
5-Bromo-2-methylpyridine ISO 9001：2015 REACH
5-BROMO-2-PICOLINE
3430-13-5
3430-18-5
340-13-5
1074-98-7
Building Blocks
Heterocyclic Building Blocks
Bromopyridines
Halopyridines
Pyridines
Halogenated Heterocycles
Pyridines derivates
Bromopyridines
Halopyridines
Pyridine series
blocks
Bromides
Pyridines
Pyridine
Pyridines, Pyrimidines, Purines and Pteredines
alkyl bromide
Building Blocks
C6
Chemical Synthesis
Halogenated Heterocycles
Heterocyclic Building Blocks
3430-13-5