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ChemicalBook >> CAS DataBase List >>(R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole

(R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole

(R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole Structure
(R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole structure
CAS No.
1456816-37-7
Chemical Name:
(R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole
Synonyms
ZJ-0026;(R)-AntPhos;99％ee）[（R）-AntPhos];99% ee) [(R)-AntPhos];(3R)-4-(9-anthryl)-3-tert-butyl-2H-1,3-benzoxaphosphole;(R)-4-(9-Anthracenyl)-3-(tert-butyl)-2,3-dihydro-1,3-benzoxaphosphole;(R)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole;(R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole;(R)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole,98+% (>1,3-Benzoxaphosphole, 4-(9-anthracenyl)-3-(1,1-dimethylethyl)-2,3-dihydro-, (3R)-
CBNumber:
CB73340391
Molecular Formula:
C25H23OP
Molecular Weight:
370.42
MDL Number:
MFCD31630705
MOL File:
1456816-37-7.mol
Last updated:2025-01-27 09:38:02
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(R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole Properties

Boiling point 525.7±50.0 °C(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form crystal
color light yellow
Sensitive air sensitive, store cold
UNSPSC Code 12352200
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352-P305+P351+P338
HS Code  2931499090

(R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole price More Price(19)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 913456 (R)-AntPhos ≥97% 1456816-37-7 100MG $106 2024-03-01 Buy
Sigma-Aldrich 913456 (R)-AntPhos ≥97% 1456816-37-7 250MG $217 2024-03-01 Buy
Strem Chemicals 15-1963 (R)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole,98+% (>99% ee) [(R)-AntPhos] 1456816-37-7 100mg $77 2024-03-01 Buy
Strem Chemicals 15-1963 (R)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole,98+% (>99% ee) [(R)-AntPhos] 1456816-37-7 500mg $309 2024-03-01 Buy
Strem Chemicals 15-1963 (R)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole,98+% (>99% ee) [(R)-AntPhos] 98+% (>99% ee) [(R)-AntPhos] 1456816-37-7 2g $925 2024-03-01 Buy
Product number Packaging Price Buy
913456 100MG $106 Buy
913456 250MG $217 Buy
15-1963 100mg $77 Buy
15-1963 500mg $309 Buy
15-1963 2g $925 Buy

(R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole Chemical Properties,Uses,Production

Reaction

  1. Ligand/palladium catalyst for general Miyaura borylation reactions.
  2. Ligand/palladium catalyst for general and sterically demanding Suzuki-Miyaura cross-coupling reactions.
  3. Ligand/palladium catalyst for aryl-alkyl Suzuki-Miyaura cross-coupling reactions.
  4. Ligand/nickel catalyst for intramolecular reductive cyclization.
  5. Ligand/palladium catalyst for Dearomative cyclization.
Reactions of 1456816-37-7

Uses

(R)-AntPhos is a P-chiral monophosphorus ligand used for the asymmetric Suzuki-Miyaura and Miyaura borylation reactions. This ligand is uniquely effective for sterically hindered cross-coupling reactions.

reaction suitability

reagent type: ligand

(R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole Suppliers

Global( 28)Suppliers
Supplier Tel Email Country ProdList Advantage
Aladdin Scientific 		+1-+1(833)-552-7181 sales@aladdinsci.com United States 57505 58
Wuhan Fortuna Chemical Co.,Ltd 		+8618007136271 hk@fortunachem.com China 5998 58
Watson Biotechnology Co.,Ltd 		+86-18186686046 +86-18186686046 sales01@watsonbiotech.cn China 5853 58
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44689 61
Daicel Chiral Technologies (China)CO.,LTD 021-50460086-9 15921403865 han_yajun@dctc.daicel.com China 6791 65
Bide Pharmatech Ltd. 400-164-7117 13681763483 product02@bidepharm.com China 41462 60
LaaJoo 021-60702684 18516024827 huang.jiayi@sinocompound.com China 2309 58
Greenherbs Science and Technology Development Co., Ltd. 010-61136123 pub02@greenherbs.com.cn China 4049 58
Aikon International Limited 025-66028182 18112977050 cfzhang@aikonchem.com China 15818 58
Rhawn Reagent 400-400-1332688 18019345275 amy@rhawn.cn China 15497 58
Supplier Advantage
Aladdin Scientific 		58
Wuhan Fortuna Chemical Co.,Ltd 		58
Watson Biotechnology Co.,Ltd 		58
Energy Chemical 61
Daicel Chiral Technologies (China)CO.,LTD 65
Bide Pharmatech Ltd. 60
LaaJoo 58
Greenherbs Science and Technology Development Co., Ltd. 58
Aikon International Limited 58
Rhawn Reagent 58

1456816-37-7((R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole)Related Search:

(2R,3R)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-iso propyl-2,3-dihydrobenzo[d ][1,3]oxaphosphole (2S,3S)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-iso propyl-2,3-dihydrobenzo[d ][1,3]oxaphosphole (2R,2'R,3R,3'R)-3,3'-di-tert-butyl-4,4'-bis(2,6-dimethoxyphenyl)-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole (2R,3R)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-met hyl-2,3-dihydrobenzo[d][1, 3]oxaphosphole (2S,3S)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-met hyl-2,3-dihydrobenzo[d][1, 3]oxaphosphole
(R)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole (2R,2'R,3R,3'R)-4,4'-di(ant hracen-9-yl)-3,3'-di-tert-bu tyl-2,2',3,3'-tetrahydro-2,2' -bibenzo[d][1,3]oxaphosp hole 4-(anthracen-9-yl)-3-(tertbutyl)-2,3-dihydrobenzo[d] [1,3]oxaphosphole (2S,2'S,3S,3'S)-4,4'-di(anth racen-9-yl)-3,3'-di-tert-but yl-2,2',3,3'-tetrahydro-2,2'- bibenzo[d][1,3]oxaphosph ole (S)-4-(anthracen-9-yl)-3-(te rt-butyl)-2,3-dihydrobenzo [d][1,3]oxaphosphole
(S)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole

1of3

(R)-4-(ANTHRACEN-9-YL)-3-(T-BUTYL-2,3-DIHYDROBENZO[D][1,3]OXAPHOSPHOLE,98+%(>99%EE)[(R)-ANTPHOS] (R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole (R)-4-(9-Anthracenyl)-3-(tert-butyl)-2,3-dihydro-1,3-benzoxaphosphole (R)-AntPhos ZJ-0026 99％ee）[（R）-AntPhos] (R)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole,98+% (> 99% ee) [(R)-AntPhos] 1,3-Benzoxaphosphole, 4-(9-anthracenyl)-3-(1,1-dimethylethyl)-2,3-dihydro-, (3R)- ZJ-0026/(R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole (R)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole (3R)-4-(9-anthryl)-3-tert-butyl-2H-1,3-benzoxaphosphole 1456816-37-7 Chiral Phosphine