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Styrene Butadiene Rubber

CAS No.
9003-55-8
Chemical Name:
Styrene Butadiene Rubber
Synonyms
sbs;SBR;STYRENE-BUTADIENE RUBBER;STYRENE/BUTADIENE COPOLYMER;dienols;ricon100;styrene-butadienepolymer;styrene-1,3-butadienecopolymer;Polymerized Styrene Butadiene Rubber;Styrene-butadiene rubber,oil-extended
CBNumber:
CB7476376
Molecular Formula:
(C8H8.C4H6)x
Molecular Weight:
158.24
MDL Number:
MFCD00134010
MOL File:
9003-55-8.mol
MSDS File:
SDS
Last updated:2024-08-26 21:07:05

Styrene Butadiene Rubber Properties

Melting point 253 °C
Density 1.04 g/mL at 25 °C
refractive index 1.57
solubility solvents with solubility parameters between 7.7 and 9.4: soluble
form slab/chunk
Viscosity 1.0(Intrinsic viscosity)
Viscosity 4,000cp (25 wt% in toluene @ 25C)(Brookfield viscosity)
Stability Stable. Combustible. Incompatible with strong oxidizing agents.
LogP 2.700 (est)
Substances Added to Food (formerly EAFUS) BUTADIENE-STYRENE RUBBER
FDA 21 CFR 172.615; 175.125; 175.300; 177.1200; 177.2600; 177.2800; 181.30
IARC 3 (Vol. 19, Sup 7) 1987
EPA Substance Registry System Styrene 1,3-butadiene polymer (9003-55-8)

SAFETY

Risk and Safety Statements

WGK Germany  3
RTECS  WL6478000
TSCA  TSCA listed

Styrene Butadiene Rubber price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 430072 Poly(styrene-co-butadiene) butadiene 4 wt. %, melt index 6 g/10 min (200°C/5kg) 9003-55-8 1kg $77.7 2024-03-01 Buy
Sigma-Aldrich 182877 Polystyrene-block-polybutadiene-block-polystyrene styrene 30 wt. %, average Mw ~140,000 by GPC, contains <0.5 wt. % antioxidant 9003-55-8 250g $104 2024-03-01 Buy
scipoly 057 Styrene/butadiene, ABA block copolymer 9003-55-8 250g $30 2024-07-03 Buy
scipoly 057 Styrene/butadiene, ABA block copolymer 9003-55-8 500g $48 2024-07-03 Buy
Sigma-Aldrich 432490 Polystyrene-block-polybutadiene-block-polystyrene styrene 30 wt. % 9003-55-8 250g $64 2024-03-01 Buy
Product number Packaging Price Buy
430072 1kg $77.7 Buy
182877 250g $104 Buy
057 250g $30 Buy
057 500g $48 Buy
432490 250g $64 Buy

Styrene Butadiene Rubber Chemical Properties,Uses,Production

Description

By far the most widely used type of synthetic rubber, its consumption for all applications is four times that of polybutadiene, its nearest competitor, and 1.5 times that of all other elastomers combined. Its manufacture involves copolymerization of three parts butadiene with one part styrene. These materials are suspended in finely divided emulsion form in a large proportion of water, in the presence of a soap or detergent. Also present in small amounts are an initiator or catalyst which is usually a peroxide, and a chain-modifying agent such as dodecyl mercaptan.

Chemical Properties

solid or viscous liquid, depending upon the degree of polymerisation

Uses

Component of hot melt adhesives, sealants, asphalt and oil gels. Modifier for polymers, thermosets and general rubber compounding. Direct molded or extruded auto parts, sporting goods, footware and film.

Uses

Molded or extruded into toys, packaging, appliances, communication cassettes, dinnerware and serviceware.

Definition

ChEBI: Styrene-butadiene copolymer is a polymer.

Production Methods

SBR is prepared mainly by emulsion and solution polymerization in a free-radical process with a mercaptan, such as dodecylmercaptan, which is used as a chain-transfer agent to control molecular weight. In the emulsion process, a soapstabilized water emulsion of styrene and butadiene is polymerized in continuous reactors to form SBR elastomer. “Cold” SBR is produced at a temperature of 5–10°C, and “hot” SBR at about 50°C . Solution SBR is typically made in hydrocarbon solution with an n-butyllithium initiator. The major differences between emulsion and solution styrene–butadiene are in the linearity and molecular-weight distribution of the polymer chains. In nonpolar solvents, the tendency is to produce block copolymer, but random copolymers are formed in polar solvents. SBR can be vulcanized similar to natural rubber but generally requires less sulfur and is more accelerated because of its lowunsaturation.

Hazard

Questionable carcinogen.

Health Hazard

Styrene Butadiene Rubber is prepared in large quantities for tire treads and other, similar uses. The properties, molecular weight, and percentage of monomer can all be controlled in the polymerization process. Hazards of the SBR industry have been identified and related mostly to the monomers and additives. Contact dermatitis and leukemia have been associated with solvent and additive use but not with the actual polymer itself (Checkoway et al., 1984; Kilpikari, 1982). Epidemiological studies in the industry have not revealed a significant increase in disease or causes of death (Matanoski and Schwartz, 1987; Meinhardt et al., 1982). The hazards of the butadiene and styrene monomers were discussed previously.

Safety Profile

An eye irritant. Questionable carcinogen. When heated to decomposition it emits acrid smoke and irritating fumes. See also POLYMERS, INSOLUBLE.

Solubility in organics

Chloroform, dichloromethane, hexane, MEK, toluene

Global( 153)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Fengda Chemical Co., Ltd
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airuikechemical co., ltd.
+undefined86-15315557071 sales02@sdzhonghuimaterial.com China 983 58
Hebei Zhuanglai Chemical Trading Co.,Ltd
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Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21634 55
career henan chemical co
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Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28172 58
Hubei xin bonus chemical co. LTD
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Shandong chuangyingchemical Co., Ltd.
18853181302 sale@chuangyingchem.com CHINA 5906 58
Chongqing Chemdad Co., Ltd
+86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39894 58
Shaanxi Dideu Medichem Co. Ltd
18192627656 1012@dideu.com China 3002 58

View Lastest Price from Styrene Butadiene Rubber manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Styrene Butadiene Rubber pictures 2024-11-25 Styrene Butadiene Rubber
9003-55-8
US $120.00 / kg 1kg 99% 20ton Hebei Zhuanglai Chemical Trading Co.,Ltd
pOlystyrene-b-pOlybutadiene-b-pOlystyrene pictures 2024-10-15 pOlystyrene-b-pOlybutadiene-b-pOlystyrene
9003-55-8
US $0.00-0.00 / Kg 1Kg 99.9% 200tons airuikechemical co., ltd.
Styrene Butadiene Rubber pictures 2023-12-23 Styrene Butadiene Rubber
9003-55-8
US $50.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
solprene300 solprene303 styrene-butadienecopolymers Styrene-butadienerubber1500 styrenepolymerwith1,3-butadiene synpol1500 thermoplastic125 tr201 POLY(STYRENE-B-BUTADIENE-B-STYRENE), 30 WT. STYRENE, AVE MW CA. 140,000 (GP POLY(STYRENE-CO-BUTADIENE), 45 WT. % STY RENE BUTADIENE-STYRENE75:25RUBBER BUTADIENESTYRENERUBBER STYRENE-BUTADIENELATEX BUTADIENE-STYRENE50:50RUBBER Styrene-butadiene rubber 1712 POLYSTYRENE-BLOCK-POLYBUTADIENE-BLOCK-P SBR-1502 STYRENE-BUTADIENE RUBBER Styrene-butadiene rubber 1502 492L 620A 631M 638A 76RES4100 76RES4402 76RES4470 780F A 7269 ABR 60 BUTADIENE-STYRENE LATEX BUTADIENE-STYRENE RESIN PLIOLITE S-6B PLIOLITE S-6H POLY(STYRENE-CO-BUTADIENE) POLY(STYRENE/BUTADIENE) POLYSTYRENE-B-POLYBUTADIENE(1,2 ADDITION) POLYSTYRENE-B-POLYBUTADIENE(1,4 ADDITION) POLYSTYRENE-B-POLYBUTADIENE-B-POLYSTYRENE POLYSTYRENE-BLOCK-POLYBUTADIENE POLYSTYRENE-BLOCK-POLYBUTADIENE-BLOCK-POLYSTYRENE POLYSTYRENE-BLOCK-POLYBUTADIENE-BLOCK-POLYSTYRENE, BRANCHED POLYBUTADIENE-B-POLYSTYRENE-B-POLYBUTADIENE POLYBUTADIENE(1,4 AND 1,2 ADDITION)-B-POLYSTYRENE-B-POLYBUTADIENE(1,4 AND 1,2 ADDITION) TAPERED BLOCK COPOLYMER POLYSTYRENE-B-POLYBUTADIENE STYRENE/BUTADIENE, ABA BLOCK COPOLYMER STYRENE BUTADIENE LATEX, WATER BASED Butadienestyrenecopolymer butadiene-styrenecopolymer butadiene-styrenepolymer butadiene-styreneresins butakon85-71 copolymeresdustyreneetdubutadiene-1,3 diarex600 dow209 dow234 dow460 dow620 dow680 dow816