Ethyltriphenylphosphonium bromide
- CAS No.
- 1530-32-1
- Chemical Name:
- Ethyltriphenylphosphonium bromide
- Synonyms
- TEP;Ethyl triphenyl phosphine bromide;ethyltriphenylphosphanium bromide;AD182;ETPPB;tbepb;ETPPBR;Ethyl triphenyl pho;TEP (oniuM coMpound);Antioxidants Impurity 15
- CBNumber:
- CB7752854
- Molecular Formula:
- C20H20BrP
- Molecular Weight:
- 371.25
- MDL Number:
- MFCD00011838
- MOL File:
- 1530-32-1.mol
Melting point | 203-205 °C(lit.) |
---|---|
Boiling point | 240℃[at 101 325 Pa] |
Density | 1.38[at 20℃] |
vapor pressure | 0-0.1Pa at 20-25℃ |
Flash point | 200 °C |
storage temp. | Inert atmosphere,Room Temperature |
solubility | 174g/l soluble |
form | Crystalline Powder |
color | White to off-white |
Water Solubility | 120 g/L (23 ºC) |
Sensitive | Hygroscopic |
BRN | 3599630 |
InChIKey | JHYNXXDQQHTCHJ-UHFFFAOYSA-M |
LogP | -0.69--0.446 at 35℃ |
CAS DataBase Reference | 1530-32-1(CAS DataBase Reference) |
FDA UNII | R85V84UL5V |
EPA Substance Registry System | Phosphonium, ethyltriphenyl-, bromide (1530-32-1) |
UNSPSC Code | 12352002 |
NACRES | NA.22 |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() ![]() GHS05,GHS06 |
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Signal word | Danger | |||||||||
Hazard statements | H301-H318-H412 | |||||||||
Precautionary statements | P264-P270-P273-P280-P301+P310-P305+P351+P338 | |||||||||
Hazard Codes | Xn,N,Xi | |||||||||
Risk Statements | 22-51/53-36/37/38-21/22 | |||||||||
Safety Statements | 61-36/37/39-26-36 | |||||||||
RIDADR | UN 3077 9/PG 3 | |||||||||
WGK Germany | 2 | |||||||||
TSCA | Yes | |||||||||
HazardClass | 6.1 | |||||||||
PackingGroup | III | |||||||||
HS Code | 29310095 | |||||||||
NFPA 704 |
|
Ethyltriphenylphosphonium bromide price More Price(35)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | E50604 | Ethyltriphenylphosphonium bromide 99% | 1530-32-1 | 25g | $44.7 | 2024-03-01 | Buy |
Sigma-Aldrich | E50604 | Ethyltriphenylphosphonium bromide 99% | 1530-32-1 | 100g | $133 | 2024-03-01 | Buy |
TCI Chemical | E0382 | Ethyltriphenylphosphonium Bromide >98.0%(HPLC)(T) | 1530-32-1 | 25g | $29 | 2024-03-01 | Buy |
TCI Chemical | E0382 | Ethyltriphenylphosphonium Bromide >98.0%(HPLC)(T) | 1530-32-1 | 100g | $74 | 2024-03-01 | Buy |
Alfa Aesar | B23096 | Ethyltriphenylphosphonium bromide, 98+% | 1530-32-1 | 25g | $31.65 | 2024-03-01 | Buy |
Ethyltriphenylphosphonium bromide Chemical Properties,Uses,Production
Chemical Properties
White to off-white crystalline powder
Uses
suzuki reaction
Uses
Ethyltriphenylphosphonium Bromide (ETPB) is a phase transfer catalyst, used to accelerate the cure of phenolic-based epoxy resins, certain fluoroelastomer resins and thermosetting powder coatings. It is also used as catalysts in the synthesis of certain organic compounds and as a pharmaceutical intermediate.
- Ethyltriphenylphosphonium bromide acts as a reactant in the synthesis of D-amino acids from L-cysteine-derived thiazolidines, Leiodolide A through aldol reactions and Horner-Wadsworth-Emmons olefination.
- It is also used in the preparation of cycloalkanoindolines through diastereoselective intramolecular inimo-ene reactions.
- it is used as a reagent in solid-state metathesis polycondensation to prepare alkyl-dipropenylthiophene monomers.
- Mizoroki-Heck cyclization and cascading Tsuji-Trost cyclization reactions.
Uses
PTC catalyst
Uses
Ethyltriphenylphosphonium Bromide is used as a wittig reagent. Ethyltriphenylphosphonium Bromide and other phosphonium salts show antiviral activity.
Flammability and Explosibility
Not classified
reaction suitability
reaction type: C-C Bond Formation
Purification Methods
Recrystallise it from H2O and dry it in high vacuum at 100o. IR has bands at 1449, 1431 and 997cm-1 . [Wittig & Wittenberg Justus Liebigs Ann Chem 606 1 1957, Bergmann & Dusza J Org Chem 23 1245 1958, Beilstein 16 IV 982.]
Ethyltriphenylphosphonium bromide Preparation Products And Raw materials
Raw materials
Preparation Products
1of2
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
SIMAGCHEM CORP | +86-13806087780 | sale@simagchem.com | China | 17346 | 58 |
Hebei Chuanghai Biotechnology Co., Ltd | +8617732866630 | abby@chuanghaibio.com | China | 8773 | 58 |
Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 | sales1@chuanghaibio.com | China | 5251 | 58 |
Hebei Zhuanglai Chemical Trading Co.,Ltd | +8613343047651 | admin@zlchemi.com | China | 3692 | 58 |
Capot Chemical Co.,Ltd. | +8613336195806 | sales@capot.com | China | 29731 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-2158073036 | info@dakenam.com | China | 12849 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21622 | 55 |
JingJiang Connect Chemical manufacturing Co., Ltd. | 0523-80501690 15252623102 | andy@katchemical.com | CHINA | 59 | 55 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +8618949832763 | info@tnjchem.com | China | 2986 | 55 |
View Lastest Price from Ethyltriphenylphosphonium bromide manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
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2025-07-16 | Ethyltriphenylphosphonium bromide
1530-32-1
|
US $0.00 / KG | 1KG | 98%min | 30tons/month | WUHAN FORTUNA CHEMICAL CO., LTD | |
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2025-06-24 | Ethyltriphenylphosphonium bromide
1530-32-1
|
US $10.00 / KG | 1KG | 99% | 10 mt | Hebei Chuanghai Biotechnology Co., Ltd | |
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2025-06-23 | Ethyltriphenylphosphonium bromide
1530-32-1
|
US $0.00-0.00 / kg | 1kg | 99% | 50000kg | Hebei Kingfiner Technology Development Co.Ltd |
-
- Ethyltriphenylphosphonium bromide
1530-32-1
- US $0.00 / KG
- 98%min
- WUHAN FORTUNA CHEMICAL CO., LTD
-
- Ethyltriphenylphosphonium bromide
1530-32-1
- US $10.00 / KG
- 99%
- Hebei Chuanghai Biotechnology Co., Ltd
-
- Ethyltriphenylphosphonium bromide
1530-32-1
- US $0.00-0.00 / kg
- 99%
- Hebei Kingfiner Technology Development Co.Ltd