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(R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate

(R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate structure

CAS No.: 39648-67-4

Chemical Name:: (R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate

Synonyms: (R)-(-)-BNP ACID;(R)-(-)-BPA;(R)-(-)-BNPA;(R)-(-)-1,1’-BinaphthyL;(R)-(-)-1,1-BINAPHTHYL-2,2-DIYL HYDROGENPHOSPHATE;SF110023;(S)-(+)-BPA;(S)-(+)-BNPA;(S)-(+)-BNP ACID;(R)-(-)-1,1'-Binapht

CBNumber:: CB8107332

Molecular Formula:: C20H13O4P

Molecular Weight:: 348.29

MDL Number:: MFCD00010045

MOL File:: 39648-67-4.mol

MSDS File:: SDS

Last updated:2024-09-10 19:09:04

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(R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Properties

Melting point	≥300 °C
alpha	-607.5 º (c=1.4,MeOH)
Boiling point	619.5±38.0 °C(Predicted)
Density	1.49±0.1 g/cm3(Predicted)
refractive index	-595 ° (C=1, MeOH)
storage temp.	Inert atmosphere,Room Temperature
solubility	Solubility in hot Methanol, almost transparency.
pka	1.14±0.20(Predicted)
form	Powder
color	white
optical activity	[α]20/D 605°, c = 1.35 in methanol
BRN	4713363
InChI	InChI=1S/C20H13O4P/c21-25(22)23-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)24-25/h1-12H,(H,21,22)
InChIKey	JEHUZVBIUCAMRZ-UHFFFAOYSA-N
SMILES	O=P1(OC2C=CC3C=CC=CC=3C=2C2=C3C=CC=CC3=CC=C2O1)O
CAS DataBase Reference	39648-67-4(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315

Precautionary statements

P264-P280-P302+P352-P332+P313-P362+P364

Hazard Codes

Xi,Xn

Risk Statements

36/37/38-20/21/22

Safety Statements

26-36-36/37/39-22

RIDADR

3464

WGK Germany

RTECS

RZ2475100

10-23

HS Code

29199000

NFPA 704

	1
2		0

(R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate price More Price(48)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	248932	(R)-(?)-1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate ≥98%	39648-67-4	1g	$24.7	2024-03-01	Buy
Sigma-Aldrich	248932	(R)-(?)-1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate ≥98%	39648-67-4	5g	$111	2024-03-01	Buy
TCI Chemical	B1143	(R)-(-)-1,1'-Binaphthyl-2,2'-diyl Hydrogen Phosphate >98.0%(T)	39648-67-4	1g	$59	2024-03-01	Buy
TCI Chemical	B1143	(R)-(-)-1,1'-Binaphthyl-2,2'-diyl Hydrogen Phosphate >98.0%(T)	39648-67-4	5g	$146	2024-03-01	Buy
Alfa Aesar	L14149	(R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, 98+%	39648-67-4	250mg	$39.65	2024-03-01	Buy

Product number	Packaging	Price	Buy
248932	1g	$24.7	Buy
248932	5g	$111	Buy
B1143	1g	$59	Buy
B1143	5g	$146	Buy
L14149	250mg	$39.65	Buy

(R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Chemical Properties,Uses,Production

Reaction

Asymmetric hetero Diels-Alder reaction catalyzed by chiral lanthanide(III) complex.
Highly efficient Mannich reaction.
Acidic Resolving agent for certain amine/racemic mixtures.

Chemical Properties

off-white powder

Uses

The R enantiomer of binaphthol derivative as chiral quenching agent.

Uses

A chiral ligand used in hydrocarboxylation reactions. Complexes with rhodium and mediates the asymmetric dipolar cycloaddition of diazo compounds. A number of racemic amines which have proven difficult to separate have been resolved with this chiral acid. Palladium derivatives have been used in asymmetric hydrocarboxylations, and rhodium derivatives have been used in dipolar cycloadditions.

Uses

chiral ligand for hydroxycarboxylations, complexes rhodium

Purification Methods

Recrystallise it from EtOH. Reflux for 3hours in N NaOH is required to hydrolyse the cyclic phosphate. [Jacques et al. Tetrahedron Lett 4617 1971, Arnold et al. Tetrahedron 24, 343 1983.]

(R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Suppliers

Global( 333)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hangzhou ICH Biofarm Co., Ltd	+86-0571-28186870; +undefined8613073685410	sales@ichemie.com	China	998	58
XINXIANG RUNYU MATERIAL CO., LTD.	+86-13592593621; +8613592593621	sales@runvmat.com	China	443	58
Shanghai UCHEM Inc.	+862156762820 +86-13564624040	sales@myuchem.com	China	7514	58
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	18774	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21634	55
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32957	60
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29881	58
Jinan Carbotang Biotech Co.,Ltd.	+8615866703830	figo.gao@foxmail.com	China	8497	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28172	58
Chongqing Chemdad Co., Ltd	+86-023-6139-8061 +86-86-13650506873	sales@chemdad.com	China	39894	58

Supplier	Advantage
Hangzhou ICH Biofarm Co., Ltd	58
XINXIANG RUNYU MATERIAL CO., LTD.	58
Shanghai UCHEM Inc.	58
Shanghai Daken Advanced Materials Co.,Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
ATK CHEMICAL COMPANY LIMITED	60
career henan chemical co	58
Jinan Carbotang Biotech Co.,Ltd.	58
Hubei Jusheng Technology Co.,Ltd.	58
Chongqing Chemdad Co., Ltd	58

View Lastest Price from (R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-11-01	1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate 39648-67-4	US $24.00-213.00 / g	5g	0.99	25kg	Shanghai UCHEM Inc.
2024-09-10	(R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate 39648-67-4	US $200.00 / KG	1KG	99%	20 tons	Chongqing Chemdad Co., Ltd
2024-02-21	(R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate 39648-67-4	US $0.00-0.00 / KG	1KG	99	500	XINXIANG RUNYU MATERIAL CO., LTD.

1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
39648-67-4
US $24.00-213.00 / g
0.99
Shanghai UCHEM Inc.

(R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
39648-67-4
US $200.00 / KG
99%
Chongqing Chemdad Co., Ltd

(R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
39648-67-4
US $0.00-0.00 / KG
99
XINXIANG RUNYU MATERIAL CO., LTD.

(R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Spectrum

(R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate(39648-67-4)MS (R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate(39648-67-4)IR1 (R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate(39648-67-4)IR2 (R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate(39648-67-4)Raman

39648-67-4((R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate)Related Search:

R- 4-oxide-4-hydroxy-2,6-bis([1,1':3',1''-terphenyl]-5'-yl)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin S-3,3'-Bis(9-anthracenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate S-4-oxide-4-hydroxy-2,6-bis(4-nitrophenyl)- Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin R-3,3'-Bis(4-(1,1-diMethylethyl)phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate SULPHOSUCCINIC ACID ESTER

1,1'-Bi-2-naphthol Clindamycin phosphate (S)-(+)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PHENYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate, min. 98%,(S)-(+)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE,S-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE (+/-)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE,1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE,(+/-)-1,1''-BINAPHTHYL-2,2''-DIYL HYDROGENPHOSPHATE 99%

Water treatment agent POE 1,1'-BINAPHTHYL (R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% (R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate (R)-3,3'-BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE

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(R)-(-)-1,1'-Biphthyl-2,2'-diyl hydrogenphosphate (R)-1,1'-Binaphthalene-2,2'-diyl Hydrogen Phosphate,99%e.e. (R)-(-)-1,1'-Binaphthalene-2,2'-diyl-phosphate for synthesis R-(-)-1,1'-Binaphthyl-2,2'-diyl 2-HYDROXY-2LAMBDA5-DINAPHTHO[2,1-D:1,2-F][1,3,2]DIOXAPHOSPHEPIN-2-ONE (R)-(-)-1,1'-Binaphthyl-2,2'-d (R)-(-)-1,1'-Binaphthyl-2,2'-diylhydrogenphosphate,min.98% Dinaphtho2,1-d:1,2-f1,3,2dioxaphosphepin, 4-hydroxy-, 4-oxide, (11bR)- R-(-)BNP ACID/ S-(+)-1,1''-BINAPHTHALENE-2,2''-DIYL HYDROGENPHOSPHATE (11bR)-4-Hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin 4-Oxide (R)-BNPPA(R)-(-)-BNDHP (R)-4-Hydroxydinaphtho[2,1-d:1μ,2μ-f][1,3,2]dioxaphosphepin-4-oxide, (R)-(-)-1,1μ-Binaphthalene-2,2μ-diyl hydrogen phosphate (R)-(-)1,1'-BINAPHTHYL-2,2'-DIYL HYDROGEN PHOSPHATE,99% (R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate, min. 98% [aR,(-)]-2,2'-Phosphinicobisoxy-1,1'-binaphthalene (R)-(-)-1,1'-Binapht (+/-)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE (S)-4-HYDROXY DINAPHTHO[2,1-D:1',2'-F][1,3,2]-DIOXAPHOPHEPIN-4-OXID (S)-4-HYDROXYDINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-OXIDE (S)-(+)-BPA (S)-(+)-BNPA (S)-(+)-BNP ACID (R)-(-)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROG ENPHOSPHATE, 98+% (R)-4-HYDROXYDINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-OXIDE:(R)-(-)-BNP ACID R-(-)-1,1Binaphthalene-2,2Dihydrogen Phosphate (R)-(-)-1,1'-Binaphthyl-2,2'-diylhydrogenephosphate (R)-(-)-1,1-Binaphthyl-2,2'-dihydrogen phosphate (R)-(-)-1,1'-binaphthyl-2 (R)-(-)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE (R)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGEN PHOSPHATE (R)-(-)-1,1'-BINAPHTHALENE-2,2'-DIYL HYDROGEN PHOSPHATE (R)-(-)-1,1'-BINAPHTHALENE-2,2'-DIYL-PHOSPHATE R(-)-1,1'-BI-2-NAPHTHYL-2,2'-DIYL HYDROGEN PHOSPHATE (R)-(-)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE (R)-4-HYDROXY DINAPHTHO[2,1-D:1',2'-F][1,3,2]-DIOXAPHOSPHEPIN-4-OXID (R)-4-HYDROXYDINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-OXIDE (S)-(+)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE S(+)-1,1'-BI-2-NAPHTHYL-2,2'-DIYL HYDROGEN PHOSPHATE (S)-(-)-1,1'-BINAPHTHALENE-2,2'-DIYL HYDROGEN PHOSPHATE S(+)-1,1'-BINAPHTHALENE-2,2'-DIYL HYDROGEN PHOSPHATE (S)-(+)-1,1'-BINAPHTHELENE-2,2'-DIYL-PHOSPHATE Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin,4-hydroxy-, 4-oxi (R)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate (R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate (R)-4-Hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide (R)-(-)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGEN PHOSPHONATE (R)-(-)-1,1'-Binaphthyl-2,2'-diyl Hydrogen Phosphate, (R)-(-)-BNDHP (11bR)-4-Hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin R-(-)-1,1'-Binaphthyl-2,2'-diy SF110023 (R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate, 98%, for synthesis (R)-(-)-1,1'-Binaphthyl-2,2'-diyl Hydrogen Phosphate > (R)-BINAPHTHYL DIYLHYDROGEPHOSPHATE TIANFU-CHEM - (R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate 13-oxo-12,14-dioxa-13λ-phosphapentacyclo[13.8.0.02,11.03,.01,23]tricosa-1(23),2,4,6,8,10,15,17,19,21-decaen-13-olate (R)-(-)-BPA (R)-(-)-BNPA (R)-(-)-BNP ACID