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2-Hydroxyethyl acrylate

CAS No.
818-61-1
Chemical Name:
2-Hydroxyethyl acrylate
Synonyms
HEA;Hydroxyethyl acrylate;hydroxyethylacrylate;2-Hydroxyethylacrylat;2-(Acryloyloxy)ethanol;beta-hydroxyethylacrylate;2-Hydroxyethyl acrylate(2-HEA);2-Hydroxyethyl acrylate,Ethylene glycol monoacrylate;bisomer2hea;Bisomer 2HEA
CBNumber:
CB8178916
Molecular Formula:
C5H8O3
Molecular Weight:
116.12
MDL Number:
MFCD00002865
MOL File:
818-61-1.mol
MSDS File:
SDS
Last updated:2025-01-27 09:38:02

2-Hydroxyethyl acrylate Properties

Melting point -60 °C
Boiling point 90-92 °C12 mm Hg(lit.)
Density 1.106 g/mL at 20 °C
vapor density >1 (vs air)
vapor pressure <0.1 mm Hg ( 20 °C)
refractive index n20/D 1.45(lit.)
Flash point 209 °F
storage temp. 2-8°C
form Oily Liquid
pka 13.85±0.10(Predicted)
color Yellow to brown
Viscosity 7.56 cp (15.5C)
Water Solubility soluble
FreezingPoint -35
Sensitive Light Sensitive
BRN 969853
Exposure limits ACGIH: TWA 5 mg/m3
NIOSH: TWA 5 mg/m3
InChIKey OMIGHNLMNHATMP-UHFFFAOYSA-N
LogP -0.17 at 25℃
CAS DataBase Reference 818-61-1(CAS DataBase Reference)
Indirect Additives used in Food Contact Substances 2-HYDROXYETHYL ACRYLATE
FDA 21 CFR 175.105; 176.180
EWG's Food Scores 2
FDA UNII 25GT92NY0C
NIST Chemistry Reference 2-Propenoic acid, 2-hydroxyethyl ester(818-61-1)
EPA Substance Registry System 2-Hydroxyethyl acrylate (818-61-1)
UNSPSC Code 12162002
NACRES NA.23

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS05,GHS06,GHS09
Signal word  Danger
Hazard statements  H302-H311-H314-H317-H410
Precautionary statements  P261-P273-P280-P301+P312-P303+P361+P353-P305+P351+P338
Hazard Codes  T,N
Risk Statements  24-34-43-50-20/22-22
Safety Statements  26-36/39-45-61-36/37/39
RIDADR  UN 2927 6.1/PG 2
WGK Germany  3
RTECS  AT1750000
8
TSCA  Yes
HazardClass  8
PackingGroup  II
HS Code  29161290
Hazardous Substances Data 818-61-1(Hazardous Substances Data)
NFPA 704
1
2 1

2-Hydroxyethyl acrylate price More Price(17)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 292818 2-Hydroxyethyl acrylate 96%, contains 200-650 ppm monomethyl ether hydroquinone as inhibitor 818-61-1 1l $174 2024-03-01 Buy
Sigma-Aldrich 292818 2-Hydroxyethyl acrylate 96%, contains 200-650 ppm monomethyl ether hydroquinone as inhibitor 818-61-1 18l $693 2024-03-01 Buy
TCI Chemical A0743 2-Hydroxyethyl Acrylate (stabilized with MEHQ) >95.0%(GC) 818-61-1 25mL $36 2024-03-01 Buy
TCI Chemical A0743 2-Hydroxyethyl Acrylate (stabilized with MEHQ) >95.0%(GC) 818-61-1 500mL $65 2024-03-01 Buy
Alfa Aesar B24815 2-Hydroxyethyl acrylate, 97%, stab. with 200-300ppm 4-methoxyphenol 818-61-1 250g $56.8 2024-03-01 Buy
Product number Packaging Price Buy
292818 1l $174 Buy
292818 18l $693 Buy
A0743 25mL $36 Buy
A0743 500mL $65 Buy
B24815 250g $56.8 Buy

2-Hydroxyethyl acrylate Chemical Properties,Uses,Production

Description

2-Hydroxyethyl acrylate (HEA) forms homopolymers and copolymers. HEA is used mainly either as a co-monomer in the manufacture of polymers or as a chemical reactant in the manufacture of chemical intermediates. In the manufacture of polymers, HEA can be co-polymerized with acrylic acid, acrylates, methacrylates, vinyl acetate, vinyl chloride, vinylidene chloride, styrene, butadiene, and the like. Co-reactants with HEA include aromatic and aliphatic isocyanates, anhydrides, and epoxides. The polymers and chemical intermediates made with HEA find applications in automotive top coatings, architectural coatings, photocure resins, and adhesives. Globally about half of the HEA produced is used in the production of acrylic enamels for the automotive industry, where a clear topcoat is applied to a pigmented base coat to increase corrosion protection and durability.

Chemical Properties

Hydroxyethyl acrylate is a clear colorless liquid. miscible with water, soluble in general organic solvents. The commodity generally contains 400ppm of hydroquinone methylether, a polymerization inhibitor. Hydroxyethyl acrylate is a difunctional acrylate monomer with the characteristic high reactivity. Hydroxyethyl acrylate is used in a crylics for coatings, adhesives and UV reacitve oligomers. It can be used for crosslinking with isocyantes or melamines.

Uses

2-Hydroxyethyl acrylate is an acrylic monomer for use in UV inks, adhesives, lacquers, artificial nails, etc.

Uses

As a reactive monomer 2-Hydroxyethyl acrylate is used as a crosslinking agent for resins, plastics and rubber modifiers. Further, it is used in the synthesis of amphilic block copolymers by nitroxide mediated living radical polymerization. In addition to this, it is used to prepare tuned poly(hydroxyethyl acrylate) by atom transfer radical polymerization.

Definition

ChEBI: 2-Hydroxyethyl acrylate is a functional monomer for the manufacture of thermosetting acrylic resins.

Application

2-Hydroxyethyl acrylate (HEA) is a monomer that is widely used in the field of material synthesis for the production of various types of polymers, such as hydrogels, coatings, adhesives, and thermosets. Its versatility lies in its ability to copolymerize with a variety of monomers, resulting in a wide range of polymer properties and applications. Its main use is in the production of hydrogels, which are highly absorbent and can be used in wound dressings, contact lenses, drug delivery systems, and other biomedical applications. Additionally, 2-hydroxyethyl acrylate-based coatings and adhesives are used in various surface modification and bonding applications, owing to their excellent adhesion, flexibility, and chemical resistance properties.

General Description

A clear colorless liquid. Less dense than water. Vapors heavier than air. Corrosive to tissue. Flash point 120°F. May polymerize exothermically if heated or contaminated. If the polymerization takes place inside a container, the container may rupture violently. Used to make plastics.

Air & Water Reactions

Flammable. Slightly soluble in water.

Reactivity Profile

A functional monomer of thermosetting acrylic resins.

Health Hazard

Inhalation causes irritation of nose and throat. Contact with liquid irritates eyes and skin.

Fire Hazard

Behavior in Fire: Containers may explode

Flammability and Explosibility

Non flammable

Potential Exposure

2-Hydroxyethyl acrylate is contained in Lowicryl 4KM and K11M resins. It caused contact dermatitis in workers embedding media for electron microscopy. It may also be contained in ultraviolet-curable nail gel used for photobonded sculptured nails.

Toxics Screening Level

The Initial Threshold Screening Level (ITSL) 2-hydroxyethyl acrylate is 1 μg/m3 with annual averaging time.

75-21-8
79-10-7
818-61-1
Synthesis of 2-Hydroxyethyl acrylate from ETHYLENE OXIDE and Acrylic acid
Global( 544)Suppliers
Supplier Tel Email Country ProdList Advantage
Jinan Qinmu Fine Chemical Co.,Ltd.
+8618660799346 sales@qinmuchem.com China 1009 58
Hebei Chuanghai Biotechnology Co., Ltd
+8615531157085 abby@chuanghaibio.com China 8808 58
Hebei Mujin Biotechnology Co.,Ltd
+86 13288715578 +8613288715578 sales@hbmojin.com China 12809 58
Hebei Chuanghai Biotechnology Co,.LTD
+86-13131129325 sales1@chuanghaibio.com China 5868 58
Hebei Chuanghai Biotechnology Co., Ltd
+8615531151365 mina@chuanghaibio.com China 18137 58
Hebei Zhuanglai Chemical Trading Co.,Ltd
+8613343047651 admin@zlchemi.com China 3692 58
Qingdao RENAS Polymer Material Co., Ltd.
+86-0532-86867058 +86-18562606086 sales@qdrenas.com China 819 58
HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
+8615350851019 admin@86-ss.com China 1001 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21628 55
Shanghai Time Chemicals CO., Ltd.
+86-021-57951555 +8617317452075 jack.li@time-chemicals.com China 1803 55

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2-Hydroxyethyl acrylate pictures 2025-04-26 2-Hydroxyethyl acrylate
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US $0.00 / Kg/Drum 1KG 99% 5000mt/year Jinan Finer Chemical Co., Ltd
2-Hydroxyethyl acrylate pictures 2025-04-23 2-Hydroxyethyl acrylate
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US $1.00 / kg 1kg 99% 10 mt Hebei Chuanghai Biotechnology Co., Ltd
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US $99.00-66.00 / kg 0.0010000000474974513kg 99% 5000 HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
2-Hydroxyethylester kyseliny akrylove 2-hydroxyethylesterkyselinyakrylove 2-Propenoicacid,2-hydroxyethylester beta-Hydroxyethyl acrylate Bisomer 2HEA bisomer2hea 2-HYDROXYETHYL ACRYLATE, STAB. 2-Hydroxyethyl acrylate, stabilized, 97% ACRYLIC ACID 2-HYDROXYETHYL ESTER 2-Hydroxy Ethyl Acrylate (HEA) ACRYLICACID,HYDROXYETHYLESTER ethylene glycol, monoacrylate acrylic acid 2-hydroxy-ethyl ester 2-hydroxyethyl prop-2-enoate 2-Hydroxyethyl acrylate, 97%, stab. with 200-300ppm 4-methoxyphenol 2-Hydroxyethyl Acrylate (stabilized with MEHQ) Hexabis(methoxymethyl)melamine, 2-hydroxyethyl acrylate polymer Hexamethoxymethylmelamine, 2-hydroxyethyl acrylate polymer N2,N2,N4,N4,N6,N6-hexakis(methoxymethyl)-1,3,5-triazine-2,4,6-triamine 2-Hydroxyethyl acrylate, 97%, stabilized 2-Hydroxyethyl acrylate, 97%, stab. Propenoic acid 2-hydroxyethyl ester 2-Hydroxyethyl acryl 2-Hydroxyethyl Acrylate  Glycolmonoacrylate ETHYLENE GLYCOL MONOACRYLATE ETHYLENE GLYCOL ACRYLATE 2-HYDROXYETHYL ACRYLATE 2-Hydroxyethyl acrylate, stabilized, 97% 1LT 2-Hydroxyethyl acrylate, stabilized, 97% 250ML 2-Hydroxyethyl acrylate, stabilized, 97% 5ML Acrylic Acid 2-Hydroxyethyl Ester Ethylene Glycol Monoacrylate 2-Hydroxyethyl acrylate, stabilized with 200 - 300 ppM MEHQ 2-Hydroxyethyl acrylate 96%, contains 200-650 ppM MonoMethyl ether hydroquinone as inhibitor 2-Hydroxyethyl acrylate, stabilized with 200 to 300ppm 4-methoxyphenol 2-hydroxyethyl acrylate E:candyli(at)speedgainpharma(dot)com 2-Hydroxyethyl acrylate, 97%, stabilized with 200 - 300 ppm MEHQ 2-Hydroxyethyl Acrylate (stabilized with MEHQ)> 2-Hydroxyethyl acrylate,97.5% 2-Hydroxyethyl acrylate, 96%+ 2-(Acryloyloxy)ethanol beta-hydroxyethylacrylate 2-Hydroxyethylacrylat 2-Hydroxyethyl acrylate,Ethylene glycol monoacrylate Hydroxyethyl acrylate hydroxyethylacrylate HEA 2-Hydroxyethyl acrylate(2-HEA) 2-Hydroxyethyl acrylate,98% (stabilized with MEHQ) 818-61-1 CH2CHCOOCH2CH2OH CH2CHCO2CH2CH2OH C20H38N6O9 Organic Building Blocks Esters Carbonyl Compounds C2 to C5 Ethylene Glycols & Monofunctional Ethylene Glycols Monofunctional Ethylene Glycols