ChemicalBook >> CAS DataBase List >>2-BUTYL-1,3,2-DIOXABOROLANE-4S,5S-DICARBOXYLIC ACID BIS(DIMETHYLAMIDE)

2-BUTYL-1,3,2-DIOXABOROLANE-4S,5S-DICARBOXYLIC ACID BIS(DIMETHYLAMIDE)

CAS No.
161344-84-9
Chemical Name:
2-BUTYL-1,3,2-DIOXABOROLANE-4S,5S-DICARBOXYLIC ACID BIS(DIMETHYLAMIDE)
Synonyms
2-Butyl-1;2-dioxaborolane-4S;5S-dicarboxylicacid bis(diMethylaMide);Butylboronic acid N,N,N',N'-tetrameth;2-Butyl-1,3,2-dioxaborolane-4S,5S-dicarboxylic;2-BUTYL-1,3,2-DIOXABOROLANE-4S,5S-DICARBOXYLIC ACID BIS(DIMETHYLAMIDE);2-BUTYL-N,N,N',N'-TETRAMETHYL-1,3,2-DIOXABOROLANE-(4S,5S)-DICARBOXAMIDE;2-Butyl-N,N,N',N'-tetramethyl-1,3,2-dioxaborolane-(4S,5S)-dicarboxamide;Butylboronic acid N,N,N',N'-tetraMethyl-D-tartaric acid diaMide ester 97%;Butylboronic acid N,N,N',N'-tetramethyl-D-tartaric acid diamide ester, 97%
CBNumber:
CB8208116
Molecular Formula:
C12H23BN2O4
Molecular Weight:
270.13
MDL Number:
MFCD05663838
MOL File:
161344-84-9.mol
MSDS File:
SDS
Last updated:2022-12-30 16:20:48

2-BUTYL-1,3,2-DIOXABOROLANE-4S,5S-DICARBOXYLIC ACID BIS(DIMETHYLAMIDE) Properties

Boiling point 305-306 °C (lit.)
Density 1.096 g/mL at 25 °C (lit.)
refractive index n20/D 1.4780(lit.)
Flash point >230 °F
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
pka -0.81±0.40(Predicted)
optical activity [α]20/D +106°, c = 1% in chloroform

SAFETY

Risk and Safety Statements

WGK Germany  3
HazardClass  IRRITANT
HS Code  2933998090

2-BUTYL-1,3,2-DIOXABOROLANE-4S,5S-DICARBOXYLIC ACID BIS(DIMETHYLAMIDE) price More Price(24)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 594806 Butylboronic acid N,N,N′,N′-tetramethyl-D-tartaric acid diamide ester 97% 161344-84-9 5g $141.2 2024-03-01 Buy
Sigma-Aldrich 594806 Butylboronic acid N,N,N′,N′-tetramethyl-D-tartaric acid diamide ester 97% 161344-84-9 1g $118 2023-06-20 Buy
TRC B695245 2-Butyl-1,3,2-dioxaborolane-4S,5S-dicarboxylicAcidBis(dimethylamide) 161344-84-9 50mg $60 2021-12-16 Buy
AK Scientific Z0242 2-Butyl-N,N,N',N'-tetramethyl-1,3,2-dioxaborolane-(4S,5S)-dicarboxamide 161344-84-9 1g $113 2021-12-16 Buy
Oakwood 037207 2-Butyl-1,3,2-dioxaborolane-4S,5S-dicarboxylicacidbis(dimethylamide) 97% 161344-84-9 250mg $25 2021-12-16 Buy
Product number Packaging Price Buy
594806 5g $141.2 Buy
594806 1g $118 Buy
B695245 50mg $60 Buy
Z0242 1g $113 Buy
037207 250mg $25 Buy

2-BUTYL-1,3,2-DIOXABOROLANE-4S,5S-DICARBOXYLIC ACID BIS(DIMETHYLAMIDE) Chemical Properties,Uses,Production

Uses

Butylboronic acid N,N,N′,N′-tetramethyl-D-tartaric acid diamide is a dioxaborolane ligand that can be used to prepare:

  • Enantioenriched spiropentanes via zinc catalyzed cyclopropanation of corresponding hydroxymethylallenes.
  • 1,2,3-trisubstituted cyclopropane derivatives by asymmetric cyclopropanation of allylic alcohols in the presence of zinc reagents.
  • Glycolipids plakosides A, B, and their derivatives by Sharpless asymmetric dihydroxylation and cyclopropanation reaction.

92527-13-4
63126-52-3
161344-84-9
Synthesis of 2-BUTYL-1,3,2-DIOXABOROLANE-4S,5S-DICARBOXYLIC ACID BIS(DIMETHYLAMIDE) from 2-(BUT-1-YL)-TETRAHYDRO-4-H-1,3,6,2-DIOXAZABOROCINE and (S,S)-(-)-2,3-DIHYDROXY-N,N,N',N'-TETRAMETHYLSUCCINAMIDE

2-BUTYL-1,3,2-DIOXABOROLANE-4S,5S-DICARBOXYLIC ACID BIS(DIMETHYLAMIDE) Preparation Products And Raw materials

2-BUTYL-1,3,2-DIOXABOROLANE-4S,5S-DICARBOXYLIC ACID BIS(DIMETHYLAMIDE) Suppliers

Global( 54)Suppliers
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Chongqing Chemdad Co., Ltd
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CONIER CHEM AND PHARMA LIMITED
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Aladdin Scientific
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J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 021-61259108 18621169109 market03@meryer.com China 40228 62
Wuhan Chemwish Technology Co., Ltd 86-027-67849912 sales@chemwish.com China 35896 56
Pure Chemistry Scientific Inc. 001-857-928-2050 or 1-888-588-9418 sales@chemreagents.com United States 10186 62
2-BUTYL-N,N,N',N'-TETRAMETHYL-1,3,2-DIOXABOROLANE-(4S,5S)-DICARBOXAMIDE 2-BUTYL-1,3,2-DIOXABOROLANE-4S,5S-DICARBOXYLIC ACID BIS(DIMETHYLAMIDE) (4S,5S)-2-BUTYL-N,N,N'N'-TETRAMETHYL-1,3,2-DIOXABOROLANE-4,5-DICARBOXAMIDE Butylboronic acid N,N,N',N'-tetramethyl-D-tartaric acid diamide ester, 97% 2-Butyl-1,3,2-dioxaborolane-4S,5S-dicarboxylic (4S,5S)-2-Butyl-N4,N4,N5,N5-tetraMethyl-1,3,2-dioxaborolane-4,5-dicarboxaMide Butylboronic acid N,N,N',N'-tetraMethyl-D-tartaric acid diaMide ester 97% Butylboronic acid N,N,N',N'-tetrameth 2-Butyl-1 2-dioxaborolane-4S 5S-dicarboxylicacid bis(diMethylaMide) 1,3,2-Dioxaborolane-4,5-dicarboxamide, 2-butyl-N4,N4,N5,N5-tetramethyl-, (4S,5S)- (4S,5S)-2-butyl-4-N,4-N,5-N,5-N-tetramethyl-1,3,2-dioxaborolane-4,5-dicarboxamide 2-Butyl-N,N,N',N'-tetramethyl-1,3,2-dioxaborolane-(4S,5S)-dicarboxamide 161344-84-9 Organometallic Reagents Alkyl Boronic Acids and Derivatives Boronate Esters