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ChemicalBook >> CAS DataBase List >>5,6,8,13-Tetrahydro-2,3-dimethoxy-9,10-(methylenedioxy)-13aH-dibenzo[a,g]quinolizine

5,6,8,13-Tetrahydro-2,3-dimethoxy-9,10-(methylenedioxy)-13aH-dibenzo[a,g]quinolizine

5,6,8,13-Tetrahydro-2,3-dimethoxy-9,10-(methylenedioxy)-13aH-dibenzo[a,g]quinolizine Structure
5,6,8,13-Tetrahydro-2,3-dimethoxy-9,10-(methylenedioxy)-13aH-dibenzo[a,g]quinolizine structure
CAS No.
522-96-3
Chemical Name:
5,6,8,13-Tetrahydro-2,3-dimethoxy-9,10-(methylenedioxy)-13aH-dibenzo[a,g]quinolizine
Synonyms
Sinactine;2,3-Dimethoxy-9,10-methylenedioxy-5,6,13,13a-tetrahydro-8H-dibenzo[a,g]quinolizine;6,6a,11,14-Tetrahydro-8,9-dimethoxy-12H-benzo[a]-1,3-benzodioxolo[4,5-g]quinolizine;5,6,8,13-Tetrahydro-2,3-dimethoxy-9,10-(methylenedioxy)-13aH-dibenzo[a,g]quinolizine
CBNumber:
CB82323479
Molecular Formula:
C20H21/sub>04N
Molecular Weight:
0
MDL Number:
MOL File:
522-96-3.mol
Last updated:2023-05-04 17:34:39
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5,6,8,13-Tetrahydro-2,3-dimethoxy-9,10-(methylenedioxy)-13aH-dibenzo[a,g]quinolizine Properties

Melting point 175°C

5,6,8,13-Tetrahydro-2,3-dimethoxy-9,10-(methylenedioxy)-13aH-dibenzo[a,g]quinolizine Chemical Properties,Uses,Production

Description

A berberine type alkaloid, first isolated from Sinorneniurn acuturn Rehd. and Wits and also present in both the (-)- and (±)-forms in Fagara officinalis L., crystallizes from EtOH in colourless prisms. It has [α]D - 312° (CHC13 ) and yields a sparingly soluble hydrochloride, m.p. 272°C (dec.) and a platinichloride, m.p. 245-7°C. On oxidation with iodine in EtOH it forms an iodide as orangeyellow needles, m.p. 300°C (dec.) which, on treatment with silver chloride in H2 0 gives dehydrosinactine chloride, identical with epiberberinium chloride.

Definition

ChEBI: Sinactine is an alkaloid.

References

Goto, Sudzuki., Bull. Chern. Soc., Japan, 4, 220 (1929)
Goto, Kitasato., J. Chern. Soc., 1234 (1930)

5,6,8,13-Tetrahydro-2,3-dimethoxy-9,10-(methylenedioxy)-13aH-dibenzo[a,g]quinolizine Preparation Products And Raw materials

Raw materials

Preparation Products

2,3-Dimethoxy-9,10-methylenedioxy-5,6,13,13a-tetrahydro-8H-dibenzo[a,g]quinolizine 5,6,8,13-Tetrahydro-2,3-dimethoxy-9,10-(methylenedioxy)-13aH-dibenzo[a,g]quinolizine 6,6a,11,14-Tetrahydro-8,9-dimethoxy-12H-benzo[a]-1,3-benzodioxolo[4,5-g]quinolizine Sinactine 522-96-3 Csub20subHsub21sub0sub4subN