ChemicalBook >> CAS DataBase List >>2,2'-DIBROMO-1,1'-BINAPHTHYL
2,2'-DIBROMO-1,1'-BINAPHTHYL
- CAS No.
- 74866-28-7
- Chemical Name:
- 2,2'-DIBROMO-1,1'-BINAPHTHYL
- Synonyms
- SKL192;JACS-74866-28-7;Binaphthalene dibromide;2,2'-diboromo-binaphthyl;2,2`-DibroMo-1,1`-Binaphtyl;1,1'-Bi(2-bromonaphthalene);2,2'-Dibromo-1,1'-binapthyl;2,2'-DIBROMO-1,1'-DINAPHTHYL;2,2'-DIBROMO-1,1'-BINAPHTHYL;2,2'-Dibromo-1,1'-binaphthyl
- CBNumber:
- CB8270540
- Molecular Formula:
- C20H12Br2
- Molecular Weight:
- 412.12
- MDL Number:
- MFCD00188005
- MOL File:
- 74866-28-7.mol
- MSDS File:
- SDS
Last updated:2023-06-08 17:06:35
Melting point | 178-183 °C |
---|---|
Boiling point | 178-183°C |
Density | 1.614±0.06 g/cm3(Predicted) |
Flash point | 178-183°C |
storage temp. | Sealed in dry,Room Temperature |
solubility | soluble in Toluene |
form | Powder |
color | white to off-white |
Water Solubility | Sparingly Soluble in water. |
CAS DataBase Reference | 74866-28-7(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
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Signal word | Warning | |||||||||
Hazard statements | H302-H413 | |||||||||
Precautionary statements | P273-P301+P312+P330 | |||||||||
Hazard Codes | Xn | |||||||||
Risk Statements | 36/37/38-22 | |||||||||
Safety Statements | 26-36/37/39 | |||||||||
WGK Germany | 3 | |||||||||
HS Code | 2903.99.8001 | |||||||||
NFPA 704 |
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2,2'-DIBROMO-1,1'-BINAPHTHYL price More Price(19)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 676438 | 2,2′-Dibromo-1,1′-binaphthyl 96% | 74866-28-7 | 1g | $78.7 | 2024-03-01 | Buy |
TCI Chemical | D4221 | 2,2'-Dibromo-1,1'-binaphthyl >96.0%(GC) | 74866-28-7 | 1g | $59 | 2024-03-01 | Buy |
TCI Chemical | D4221 | 2,2'-Dibromo-1,1'-binaphthyl >96.0%(GC) | 74866-28-7 | 5g | $216 | 2024-03-01 | Buy |
Alfa Aesar | H26987 | (±)-2,2'-Dibromo-1,1'-binaphthyl, 96% | 74866-28-7 | 1g | $72.65 | 2024-03-01 | Buy |
Alfa Aesar | H26987 | (±)-2,2'-Dibromo-1,1'-binaphthyl, 96% | 74866-28-7 | 5g | $234.65 | 2024-03-01 | Buy |
2,2'-DIBROMO-1,1'-BINAPHTHYL Chemical Properties,Uses,Production
Uses
The synthesis of this class of compounds relies on the lithiation of racemic 2,2'-dibromo-1,1'-binaphthyl with t-BuLi followed by addition of Ph 2 PCl.
Purification Methods
Purify the binaphthyl by chromatography through a silica gel column (70-230mesh) using hexane as eluent. It gives pale yellow crystals from EtOH with m 187.3-187.9o. The R-(+)-enantiomer [86688-08-6] crystallises from hexane with m 157-157.5o and [] D +32.9o (c 1, pyridine) [Brown et al. J Org Chem 50 4345 1985]. [Okamoto et al. J Am Chem Soc 103 69711981, Beilstein 5 III 2465.]
2,2'-DIBROMO-1,1'-BINAPHTHYL Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
Global( 131)Suppliers
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20290 | 58 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32835 | 60 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29890 | 58 |
Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22968 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39916 | 58 |
Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63711 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49392 | 58 |
Antai Fine Chemical Technology Co.,Limited | 18503026267 | info@antaichem.com | CHINA | 9641 | 58 |
Zhengzhou Alfa Chemical Co.,Ltd | +8618530059196 | sale04@alfachem.cn | China | 13402 | 58 |
Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | info@dycnchem.com | China | 52861 | 58 |
View Lastest Price from 2,2'-DIBROMO-1,1'-BINAPHTHYL manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-01-14 | (+/-)-2,2-Dibromo-1,1-Binaphthyl
74866-28-7
|
US $5.00-0.50 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | ||
2019-07-06 | 2,2'-DIBROMO-1,1'-BINAPHTHYL
74866-28-7
|
US $8.80 / KG | 1KG | 97%-99% | 100kg | Career Henan Chemical Co |
- (+/-)-2,2-Dibromo-1,1-Binaphthyl
74866-28-7
- US $5.00-0.50 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
- 2,2'-DIBROMO-1,1'-BINAPHTHYL
74866-28-7
- US $8.80 / KG
- 97%-99%
- Career Henan Chemical Co
74866-28-7(2,2'-DIBROMO-1,1'-BINAPHTHYL)Related Search:
2,2'-DIBROMO-1,1'-BINAPHTHYL
2,2'-DIBROMO-1,1'-DINAPHTHYL
RACEMIC-2,2'-DIBROMO-1,1'-BINAPHTHYL
2,2'-Dibromo-1,1'-binapthyl
racemic-2,2'-Dibromo-1,1'-binaphthyl,99%
1,1'-Bi(2-bromonaphthalene)
2,2'-Dibromo-1,1'-binaphthalene
rac-2,2'-Dibromo-1,1'-binaphthyl,
rac-2,2'-Dibromo-1,1'-binaphthyl,99%
racemic-2,2'-Dibromo-1,1'-binaphthyl, min. 96%
2,2`-DibroMo-1,1`-Binaphtyl
2-broMo-1-(2-broMonaphthalen-1-yl)naphthalene
2,2'-Dibromo-1,1'-binaphthyl 96%
2,2'-diboromo-binaphthyl
JACS-74866-28-7
2,2'-Dibromo-1,1'-binaphthyl>
1,1'-Binaphthalene, 2,2'-dibromo-
()-2,2-Dibromo-1,1-binaphthyl
2,2'-Dibromo-1,1'-binaphthyl (rac)
SKL192
(+/-)-2,2-Dibromo-1,1-Binaphthyl
(+/-)-2,2-Dibromo-l,l-Binaphthyl
Binaphthalene dibromide
2,2'-Dibromo-1,1'-binaphthyl
2-bromo-1-(2-bromo-1-naphthyl)naphthalene
74866-28-7
燙20H12Br2
C20H12Br2
Aryl
C13 to C37+
Halogenated Hydrocarbons