ChemicalBook >> CAS DataBase List >>O-(2,3,4,5,6-PENTAFLUOROBENZYL)HYDROXYLAMINE HYDROCHLORIDE

O-(2,3,4,5,6-PENTAFLUOROBENZYL)HYDROXYLAMINE HYDROCHLORIDE

CAS No.
57981-02-9
Chemical Name:
O-(2,3,4,5,6-PENTAFLUOROBENZYL)HYDROXYLAMINE HYDROCHLORIDE
Synonyms
PFBHA;O-(2,3,4,5,6-Pentafluorobenzyl)hydroxylamine;Nsc153392;PFBHA HCL;FLOROX REAGENT;FLOROX(TM) REAGENT;TIMTEC-BB SBB003152;Pentafluorobenzylhydroxylamine;PENTAFLUOROBENZYLHYDROXYLAMINE HCL;(2,3,4,5,6-Pentafluorobenzyl)oxyamine
CBNumber:
CB8307815
Molecular Formula:
C7H5ClF5NO
Molecular Weight:
249.57
MDL Number:
MFCD00012953
MOL File:
57981-02-9.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

O-(2,3,4,5,6-PENTAFLUOROBENZYL)HYDROXYLAMINE HYDROCHLORIDE Properties

Melting point 227 °C (subl.)(lit.)
storage temp. Inert atmosphere,Room Temperature
solubility H2O: 5%, clear
form powder to crystal
color White
PH pH(5g/l, 25℃) : 2.0~3.0
Water Solubility Soluble in water.
BRN 4031190
CAS DataBase Reference 57981-02-9(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P271-P280
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  22-24/25
WGK Germany  3
10
HazardClass  IRRITANT
HS Code  29280000
NFPA 704
1
2 1

O-(2,3,4,5,6-PENTAFLUOROBENZYL)HYDROXYLAMINE HYDROCHLORIDE price More Price(30)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 194484 O-(2,3,4,5,6-Pentafluorobenzyl)hydroxylamine hydrochloride ≥98% 57981-02-9 250mg $58.7 2024-03-01 Buy
Sigma-Aldrich 194484 O-(2,3,4,5,6-Pentafluorobenzyl)hydroxylamine hydrochloride ≥98% 57981-02-9 1g $159 2024-03-01 Buy
TCI Chemical P0822 O-(2,3,4,5,6-Pentafluorobenzyl)hydroxylamine Hydrochloride [for Oxime Preparation] >98.0%(HPLC)(N) 57981-02-9 1g $123 2024-03-01 Buy
TCI Chemical P0822 O-(2,3,4,5,6-Pentafluorobenzyl)hydroxylamine Hydrochloride [for Oxime Preparation] >98.0%(HPLC)(N) 57981-02-9 5g $465 2024-03-01 Buy
Alfa Aesar A18368 O-(2,3,4,5,6-Pentafluorobenzyl)hydroxylamine hydrochloride, 99+% 57981-02-9 0.25g $53.65 2024-03-01 Buy
Product number Packaging Price Buy
194484 250mg $58.7 Buy
194484 1g $159 Buy
P0822 1g $123 Buy
P0822 5g $465 Buy
A18368 0.25g $53.65 Buy

O-(2,3,4,5,6-PENTAFLUOROBENZYL)HYDROXYLAMINE HYDROCHLORIDE Chemical Properties,Uses,Production

Chemical Properties

White powder

Uses

PFBHA.HCl has been used for derivatization of metabolites with carbonyl groups followed by analysis via GC-MS. It has also been used in aldehyde derivatization followed by aldehydic hydrolysis using GC/MS.

Uses

O-(2,3,4,5,6-Pentafluorobenzyl)hydroxylamine hydrochloride is used in the preparation of oximes of steroids having keto group. It is used as a derivatization reagent in the determination of thromboxane B2, prostaglandins, amygdalin and a variety of aldehydes, ketones and acids. It is a versatile reagent utilized for the detection of carbonyl-containing compounds by gas chromatography (GC), gas chromatography mass spectrometry (GC-MS) and other methods. As a derivatization reagent, it is also used for EC/LC analysis of keto-steroids and carbohydrates.

Uses

O-(2,3,4,5,6-Pentafluorobenzyl)hydroxylamine hydrochloride is used:

  • In the preparation of oximes of steroids-bearing keto group.
  • As a derivatization reagent in the determination of thromboxane B2, prostaglandins, amygdalin, and a variety of aldehydes, ketones, and acids.
It is a versatile reagent used for the detection of carbonyl-containing compounds by GC, GC-MS, and other methods.

General Description

O-(2,3,4,5,6-Pentafluorobenzyl)hydroxylamine hydrochloride (PFBHA.HCl) is a derivatizing agent.

Purification Methods

Recrystallise the salt from EtOH to form colourless leaflets. Drying the compound at high vacuum and elevated temperature will result in losses by sublimation. [Youngdale J Pharm Sci 65 625 1976, Wehner & Handke J Chromatog 177 237 1979, Nambara et al. give incorrect m as 115-116o J Chromatogr 114 81 1975.]

Global( 182)Suppliers
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View Lastest Price from O-(2,3,4,5,6-PENTAFLUOROBENZYL)HYDROXYLAMINE HYDROCHLORIDE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
O-(2,3,4,5,6-PENTAFLUOROBENZYL)HYDROXYLAMINE HYDROCHLORIDE pictures 2019-07-06 O-(2,3,4,5,6-PENTAFLUOROBENZYL)HYDROXYLAMINE HYDROCHLORIDE
57981-02-9
US $1.00 / kg 1kg 98% 100KG Career Henan Chemical Co
O-(PENTAFLUOROBENZYL)HYDROXYLAMINE HYDROCHLORIDE O-PENTAFLUOROBENZYLHYDROXYLAMINE HYDROCHLORIDE IN PYRIDINE O-(2,3,4,5,6-PENTAFLUOROBENZYL)HYDROXYLAMINE HYDROCHLORIDE TIMTEC-BB SBB003152 0-(2,3,4,5,6-Pentafluorobenzyl) Hydroxylamine Hydrochloride O-(Pentafluorobenzyl)hydroxylamine hydrochloride 97% O-(2,3,4,5,6-pentafluorobenzyl)*hydroxylamine hyd O-(2,3,4,5,6-PENTAFLUOROBENZYL)HYDROXYL- AMINE HYDROCHLORIDE, 99+% O-(2,3,4,5,6-PENTAFLUOROBENZYL)*HYDROXYL AMINE HYDRO O-(2,3,4,5,6-Pentafluorobenzyl)hydroxylamineHCl O-(Pentafluorobenzyl)hydroxylaminehydrochloride97% O-(2,3,4,5,6-Pentafluorobenzyl)hydroxylamine Hydrochloride [for Oxime Preparation] (2,3,4,5,6-Pentafluorobenzyl)oxyamine [(2,3,4,5,6-Pentafluorobenzyl)oxy]amine O-(Pentafluorophenylmethyl)hydroxylamine Pentafluorobenzylhydroxylamine O-(2,3,4,5,6-Pentafluorobenzyl)hydroxylamine·hydrochloric acid Pentafluorobenzylhydroxylamine·hydrochloride 1-[(Aminooxy)methyl]-2,3,4,5,6-pentafluorobenzene hydrochloride 2,3,4,5,6-Pentafluorobenzyloxyamine hydrochloride N-[(2,3,4,5,6-Pentafluorobenzyl)oxy]amine hydrochloride Nsc153392 O-[(2,3,4,5,6-Pentafluorophenyl)methyl]hydroxylamine hydrochloride O-(2,3,4,5,6-Pentafluorobenzyl)hydroxylaMine hydrochloride >=98% O-(2,3,4,5,6-Pentafluorobenzyl)hydroxylaMine hydrochloride, derivatization grade Hydroxylamine, O-[(2,3,4,5,6-pentafluorophenyl)methyl]-, hydrochloride (1:1) 2-(2,3,4,5,6-PENTAFLUOROBENZYL)HYDROXYLAMINE HYDROCHLORIDE FLOROX REAGENT FLOROX(TM) REAGENT PFBHA HCL PENTAFLUOROBENZYLHYDROXYLAMINE HCL O-(PENTAFLUOROBENZYL)HYDROXYAMINE HYDROCHLORIDE O-(2,3,4,5,6-Pentafluorobenzyl)hydroxylamine hydrochloride 97% 6-PENTAFLUOROBENZYL)HYDROXYLAMINE HYDROCHLORIDE O-(2,3,4,5,6-Pentafluorobenzyl)hydroxylamine hydrochloride, 99%, derivatization grade Method 556 PFBHA Reagent@15.0 mg/mL in Water O-(2,3,4,5,6-Pentafluorobenzyl)hydroxylamineHydrochloride[forOximePreparation]> O-(2,3,4,5,6-Pentafluorobenzyl)hydroxylamine hydrochloride for GC derivatization O-[(2,3,4,5,6-pentafluorophenyl)methyl]hydroxylamine O-(2,3,4,5,6-Pentafluorobenzyl)hydroxylamine PFBHA 57981-02-9 C7H5ClF5NO C7H4F5NO C6F5CH2ONH2HCl C7H4F5NOHCl C7H4F5NOClH Biochemicals and Reagents Building Blocks BioChemical Nitrogen Compounds Luminescent Compounds/Detection Organic Building Blocks Derivatization agents Boronic Acid, etc. (GC Derivatizing Reagents) GC Derivatizing Reagents Hydroxylamines (O-Substituted) Hydroxylamines