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2-Methylbenzenethiol

CAS No.
137-06-4
Chemical Name:
2-Methylbenzenethiol
Synonyms
O-TOLUENETHIOL;2-METHYLTHIOPHENOL;2-THIOCRESOL;O-THIOCRESOL;FEMA 3240;uenethioL;usafek-2676;USAF ek-2676;2-THIOCRESOLE;Toluol-2-thiol
CBNumber:
CB8330729
Molecular Formula:
C7H8S
Molecular Weight:
124.2
MDL Number:
MFCD00004838
MOL File:
137-06-4.mol
MSDS File:
SDS
Last updated:2023-05-25 18:01:19

2-Methylbenzenethiol Properties

Melting point 10-12 °C(lit.)
Boiling point 195 °C(lit.)
Density 1.054 g/mL at 25 °C(lit.)
FEMA 3240 | O-TOLUENETHIOL
refractive index n20/D 1.578(lit.)
Flash point 147 °F
storage temp. Store below +30°C.
form Liquid
pka pK1:6.64 (25°C)
color Clear colorless to pale yellow
Specific Gravity 1.055
Odor at 0.10 % in propylene glycol. meaty sulfurous onion garlic egg rubber
Odor Type meaty
explosive limit 1.1%(V)
Water Solubility insoluble
Sensitive Stench
Merck 14,9325
JECFA Number 528
BRN 774068
LogP 2.98
CAS DataBase Reference 137-06-4(CAS DataBase Reference)
Substances Added to Food (formerly EAFUS) O-TOLUENETHIOL
EWG's Food Scores 1
FDA UNII 6FU2EGI4VS
NIST Chemistry Reference Benzenethiol, 2-methyl-(137-06-4)
EPA Substance Registry System Benzenethiol, 2-methyl- (137-06-4)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi,Xn
Risk Statements  37/38-41-36/37/38-20/21/22
Safety Statements  26-39-36/37/39-23
RIDADR  2810
WGK Germany  3
RTECS  XT8750000
Hazard Note  Harmful/Irritant/Stench
TSCA  Yes
HazardClass  6.1
PackingGroup  III
HS Code  29309090
Toxicity mouse,LD50,intraperitoneal,100mg/kg (100mg/kg),National Technical Information Service. Vol. AD277-689,
NFPA 704
2
2 1

2-Methylbenzenethiol price More Price(20)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich W324000 o-Toluenethiol ≥97%, FG 137-06-4 sample-k $54.6 2024-03-01 Buy
Sigma-Aldrich W324000 o-Toluenethiol ≥97%, FG 137-06-4 100g $381 2024-03-01 Buy
Sigma-Aldrich W324000 o-Toluenethiol ≥97%, FG 137-06-4 500g $1110 2024-03-01 Buy
Sigma-Aldrich W324000 o-Toluenethiol ≥97%, FG 137-06-4 1kg $1470 2024-03-01 Buy
Sigma-Aldrich T28509 2-Methylbenzenethiol 95% 137-06-4 5g $60.5 2024-03-01 Buy
Product number Packaging Price Buy
W324000 sample-k $54.6 Buy
W324000 100g $381 Buy
W324000 500g $1110 Buy
W324000 1kg $1470 Buy
T28509 5g $60.5 Buy

2-Methylbenzenethiol Chemical Properties,Uses,Production

Chemical Properties

CLEAR COLOURLESS TO SLIGHTY YELLOW-BROWN LIQUID

Chemical Properties

2-Methylthiophenol has a disagreeable odor. This compound is erroneously called o-toluenethiol.

Occurrence

Reported found in coffee

Uses

2-Thiocresol performs a fungicidal and inhibitory activity against Histoplasma capsulatum. Reagent for molecular modeling and preparation of 4-hydroxy-5,6-dihydropyrones as inhibitors of HIV protease.

Definition

ChEBI: 2-Methylbenzenethiol is a thiol.

Taste threshold values

Taste characteristics at 4 ppm: meaty, onion, garlic, chemical and metallic.

Safety Profile

Poison by intraperitoneal route. A flammable liquid. When heated to decomposition it emits toxic fumes of SOx. See also a- TOLUENETHIOL and MERCAPTANS.

95-46-5
137-06-4
Synthesis of 2-Methylbenzenethiol from 2-Bromotoluene
Global( 186)Suppliers
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Shanghai Daken Advanced Materials Co.,Ltd
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View Lastest Price from 2-Methylbenzenethiol manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
o-Thiocresol pictures 2023-02-13 o-Thiocresol
137-06-4
US $80.00 / kg 1kg 99% 100MT Hebei baicao biology science and technology co., ltd
2-Methylbenzenethiol  pictures 2020-02-26 2-Methylbenzenethiol
137-06-4
US $0.00-0.00 / KG 100g 99.0%+ 100 tons Shaanxi Dideu Medichem Co. Ltd
2-Methylbenzenethiol pictures 2019-07-06 2-Methylbenzenethiol
137-06-4
US $1.00 / KG 1KG 98% 1 Career Henan Chemical Co
  • o-Thiocresol pictures
  • o-Thiocresol
    137-06-4
  • US $80.00 / kg
  • 99%
  • Hebei baicao biology science and technology co., ltd
FEMA 3240 2-MERCAPTOTOLUENE 2-Tolyl mercaptan 2-Methylbenzenethiol, o-Thiocresol 2-Thiocresol ,98% 2-Methylbenzenethiol, 2-Thiocresol, 2-Thiotoluene ORTHO(2-)THIOCRESOL 2-METHYLTHIOPHENOL / 2-MERCAPTOTOLUENE 2-THIOCRESOLE 2-THIOCRESOL (2-METHYLBENZENETHIOL) O-Toluenethiol(PM) 2-METHYLBENZENETHIOL toluene-2-thiol O-TOLUENETHIOL 97+% 2-METHYLBENZENETHIOL,95% 2-Tolyl metcaptan 2-Methylbenzenethiol, 2-Thiocresol 2-METHYLTHIOPHENOL(2-THIOCRESOL) ORTHO-TOLUENETHIOL Toluol-2-thiol 2-Mercaptotoluene o-Thiocresol o-Tolyl Mercaptan 2-Methylbenzenethiol 2-METHYLTHIOPHENOL FOR SYNTHESIS o-methylphenylthiol ortho-thiocresol USAF ek-2676 usafek-2676 O-METHYLBENZENETHIOL O-TOLYL MERCAPTAN 2-mercapto-toluen 2-Methybenzenethiol 2-methyl-benzenethio 2-methylmercaptobenzene 2-methylphenylmercaptan 2-Toluenethiol Benzenethiol,2-methyl- o-Mercaptotoluene 2-Methylbenzenethiol USP/EP/BP uenethioL 2-THIOCRESOL 2-METHYLTHIOPHENOL O-THIOCRESOL O-TOLUENETHIOL Vortioxetine Impurity 40 Haloxyfop Impurity 9 137-06-4 0137-06-04 CH3C6H4SH Building Blocks Sulfur Compounds Thiols/Mercaptans Organic Building Blocks thiol Flavor Phenol&Thiophenol&Mercaptan