1-METHYLPHENANTHRENE
- CAS No.
- 832-69-9
- Chemical Name:
- 1-METHYLPHENANTHRENE
- Synonyms
- NSC 146583;1-methyl-phenanthren;1-METHYLPHENANTHRENE;PHENANTHRENE,1-METHYL-;1-Methylphenanthrene in Cyclohexane;1-Methylphenanthrene 100mg [832-69-9];1-MethylphenanthreneSolution,50mg/L,1ml;1-Methylphenanthrene @50 μg/mL in Toluene;1-MethylphenanthreneSolution,5,000mg/L,1ml;1-MethylphenanthreneSolution,2,000mg/L,1ml
- CBNumber:
- CB8339474
- Molecular Formula:
- C15H12
- Molecular Weight:
- 192.26
- MDL Number:
- MFCD00058942
- MOL File:
- 832-69-9.mol
| Melting point | 123°C |
|---|---|
| Boiling point | 353.25°C (rough estimate) |
| Density | 1.0561 (estimate) |
| refractive index | 1.6031 (estimate) |
| storage temp. | Room Temperature |
| solubility | Soluble in alcohol (Weast, 1986) |
| form | Solid |
| color | White powder or solid. |
| Water Solubility | 269ug/L(25 ºC) |
| Henry's Law Constant | 1.56, 2.33, 3.42, 4.93, and 6.68 x 10-5 atm?m3/mol at 4.1, 11.0, 18.0, 25.0, and 31.0 °C, respectively (Bamford et al., 1998) |
| FDA UNII | 44IY90KLCE |
| IARC | 3 (Vol. Sup 7, 92) 2010 |
| EPA Substance Registry System | 1-Methylphenanthrene (832-69-9) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS08,GHS07,GHS09 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302-H351-H410 |
| Precautionary statements | P201-P202-P281-P308+P313-P405-P501-P264-P270-P301+P312-P330-P501-P273-P391-P501 |
1-METHYLPHENANTHRENE price More Price(6)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TRC | M325415 | 1-Methylphenanthrene | 832-69-9 | 50mg | $185 | 2021-12-16 | Buy |
| TRC | M325415 | 1-Methylphenanthrene | 832-69-9 | 500mg | $1455 | 2021-12-16 | Buy |
| American Custom Chemicals Corporation | CHM0238012 | 1-METHYLPHENANTHRENE 98.00% | 832-69-9 | 25G | $2021.25 | 2021-12-16 | Buy |
| Medical Isotopes, Inc. | 52320 | 1-Methylphenanthrene | 832-69-9 | 500mg | $2200 | 2021-12-16 | Buy |
| American Custom Chemicals Corporation | CHM0238012 | 1-METHYLPHENANTHRENE 98.00% | 832-69-9 | 1G | $1212.75 | 2021-12-16 | Buy |
1-METHYLPHENANTHRENE Chemical Properties,Uses,Production
Uses
1-Methylphenanthrene is a polycyclic aromatic hydrocarbon that has been found in particulate matter from small-scale biomass combustion from old and modern technologies and that has caused acute systemic and lung inflammation in mice after intratracheal aspiration.
Definition
ChEBI: A member of the class of phenanthrenes that is phenanthrene substituted by a methyl group at position 1.
Synthesis Reference(s)
The Journal of Organic Chemistry, 45, p. 2009, 1980 DOI: 10.1021/jo01298a054
Tetrahedron Letters, 6, p. 359, 1965
General Description
White crystalline powder.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
Vigorous reactions, sometimes amounting to explosions, can result from the contact between aromatic hydrocarbons, such as 1-METHYLPHENANTHRENE, and strong oxidizing agents. They can react exothermically with bases and with diazo compounds. Substitution at the benzene nucleus occurs by halogenation (acid catalyst), nitration, sulfonation, and the Friedel-Crafts reaction. 1-METHYLPHENANTHRENE is sensitive to excessive heat and light.
Fire Hazard
Flash point data for 1-METHYLPHENANTHRENE are not available. 1-METHYLPHENANTHRENE is probably combustible.
Source
Detected in 8 diesel fuels at concentrations ranging from 0.10 to 210 mg/L with a mean
value of 44.33 mg/L (Westerholm and Li, 1994). Identified in a South Louisiana crude oil at a
concentration of 111 ppm (Pancirov and Brown, 1975). Schauer et al. (1999) reported 1-
methylphenanthrene in diesel fuel at a concentration of 28 μg/g and in a diesel-powered mediumduty
truck exhaust at an emission rate of 17.0 μg/km.
California Phase II reformulated gasoline contained 1-methylphenathrene at a concentration of
3.91 g/kg. Gas-phase tailpipe emission rates from gasoline-powered automobiles with and without
catalytic converters were approximately 1.63 and 122 μg/km, respectively (Schauer et al., 2002).
Schauer et al. (2001) measured organic compound emission rates for volatile organic
compounds, gas-phase semi-volatile organic compounds, and particle-phase organic compounds
from the residential (fireplace) combustion of pine, oak, and eucalyptus. The respective gas-phase
and particle-phase emission rates of 1-methylphenanthrene were 2.22 and 0.579 mg/kg of pine
burned and 1.04 and 0.050 mg/kg of oak burned. The gas-phase emission rate was 0.720 mg/kg of
eucalyptus burned.
1-METHYLPHENANTHRENE Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shaanxi Didu New Materials Co. Ltd | +86-89586680 +86-13289823923 | 1026@dideu.com | China | 8670 | 58 |
| Hu Bei Jiutian Bio-medical Technology CO.,Ltd | 027-88013699 17354350817 | Ryan@jiutian-bio.com | China | 6001 | 58 |
| LEAPCHEM CO., LTD. | +86-852-30606658 | market18@leapchem.com | China | 43340 | 58 |
| J & K SCIENTIFIC LTD. | 010-82848833 400-666-7788 | jkinfo@jkchemical.com | China | 94657 | 76 |
| Spectrum Chemical Manufacturing Corp. | 021-021-021-67601398-809-809-809 15221380277 | marketing_china@spectrumchemical.com | China | 9658 | 60 |
| Hangzhou Sage Chemical Co., Ltd. | +86057186818502 13588463833 | info@sagechem.com | China | 10266 | 58 |
| Shanghai BeiZhuo Biotech Co., Ltd. | 021-61119791,13386096464 | bzswkf@foxmail.com | China | 3921 | 50 |
| Beijing YiboYuntian Technology Co., Ltd. | 13811826434 | lichen13811826434@126.com | China | 559 | 58 |
| Shenzhen Polymeri Biochemical Technology Co., Ltd. | +86-400-002-6226 +86-13028896684; | sales@rrkchem.com | China | 57423 | 58 |
| Amel Pharmatech Corporation | 888-4366503 | sales@amelpharmatech.com | China | 4607 | 58 |