ChemicalBook >> CAS DataBase List >>Bis(triphenylphosphine)nickel(II)chloride
Bis(triphenylphosphine)nickel(II)chloride
- CAS No.
- 14264-16-5
- Chemical Name:
- Bis(triphenylphosphine)nickel(II)chloride
- Synonyms
- NiCl2(PPh3)2;Bis(triphenylphosphine)nickel dichloride;BIS(TRIPHENYLPHOSPHINE)NICKEL(II) CHLORIDE;DICHLOROBIS(TRIPHENYLPHOSPHINE)NICKEL(II);BIS(TRIPHENYLPHOSPHINE)NICKEL(II) DICHLORIDE;NSC 137147;(II) dichL;(PPh3)2NiCl2;phosphine)nickeL;Bis(triphenylphosphine)nick
- CBNumber:
- CB8433158
- Molecular Formula:
- C36H30Cl2NiP2
- Molecular Weight:
- 654.17
- MDL Number:
- MFCD00009592
- MOL File:
- 14264-16-5.mol
- MSDS File:
- SDS
Last updated:2023-08-23 14:20:09
| Melting point | 250 °C (dec.)(lit.) |
|---|---|
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | DMSO (Slightly), Methanol (Slightly) |
| form | Crystals or Powder |
| color | Dark green to dark gray |
| Water Solubility | insoluble |
| Sensitive | Hygroscopic |
| Exposure limits | NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3 |
| CAS DataBase Reference | 14264-16-5(CAS DataBase Reference) |
| EWG's Food Scores | 1 |
| NIST Chemistry Reference | dichlorobis(triphenylphosphine)nickel(14264-16-5) |
| EPA Substance Registry System | Nickel, dichlorobis(triphenylphosphine)- (14264-16-5) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS07,GHS08 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H317-H350-H412 | |||||||||
| Precautionary statements | P201-P273-P280-P302+P352-P308+P313 | |||||||||
| Hazard Codes | T | |||||||||
| Risk Statements | 45-43-52/53-34-20/21/22 | |||||||||
| Safety Statements | 53-36/37-45-60-36/37/39-26 | |||||||||
| RIDADR | 3260 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | QR6170000 | |||||||||
| F | 21 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 6.1(b) | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29310095 | |||||||||
| NFPA 704 |
|
Bis(triphenylphosphine)nickel(II)chloride price More Price(44)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 237116 | Bis(triphenylphosphine)nickel(II) dichloride synthesis grade | 14264-16-5 | 10g | $56.8 | 2024-03-01 | Buy |
| Sigma-Aldrich | 237116 | Bis(triphenylphosphine)nickel(II) dichloride synthesis grade | 14264-16-5 | 50g | $106.8 | 2024-03-01 | Buy |
| TCI Chemical | B1571 | Bis(triphenylphosphine)nickel(II) Dichloride >96.0%(T) | 14264-16-5 | 10g | $43 | 2024-03-01 | Buy |
| TCI Chemical | B1571 | Bis(triphenylphosphine)nickel(II) Dichloride >96.0%(T) | 14264-16-5 | 100g | $200 | 2024-03-01 | Buy |
| Alfa Aesar | 013930 | Dichlorobis(triphenylphosphine)nickel(II), 98% | 14264-16-5 | 10g | $43.65 | 2024-03-01 | Buy |
Bis(triphenylphosphine)nickel(II)chloride Chemical Properties,Uses,Production
Reaction
- Catalyst for hydrosilylation of styrene with diphenysilane
- Catalyst for carboxylation of various aryl chlorides and other derivatives
- Catalyst for C–P cross-coupling reactions of diphenylphosphine oxide with aryl chloride
- Catalyst for N?Heterocyclic carbene-assisted cross-coupling reactions of diarylborinic acids with aryl chlorides,tosylates, and sulfamates.
- Catalyst for Negishi biaryl ketone synthesis by cross-coupling of amides with aryl zinc halides via carbon-nitrogen bond cleavage.
Chemical Properties
dark green to dark grey crystals or powder
Uses
Coordination compund.
Uses
Dichlorobis(triphenylphosphine)nickel(II) is used as a catalyst for cross-coupling of Grignard reagents, hydrosilylations, hydrogenation and polymerization.
Uses
suzuki reaction
Purification Methods
Wash it with glacial AcOH and dry it in a vacuum over H2SO4 and KOH until AcOH is removed. [Venanzi J Chem Soc 719 1958, Kocienski et al. J Org Chem 54 1215 1989, Beilstein 16 IV 953.]
Bis(triphenylphosphine)nickel(II)chloride Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 374)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12840 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29791 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18779 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21634 | 55 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32957 | 60 |
| AB PharmaTech,LLC | 323-480-4688 | sales@acrospharmatech.com | United States | 989 | 55 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29884 | 58 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28172 | 58 |
| Hebei Weibang Biotechnology Co., Ltd | +8615531157085 | abby@weibangbio.com | China | 8812 | 58 |
| Wuhan Pengo Technology.,Ltd. | +86-27-81330736 +86-13628634921 | sunny.w@boronicgroup.com | CHINA | 171 | 58 |
View Lastest Price from Bis(triphenylphosphine)nickel(II)chloride manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2023-08-23 | Bis(triphenylphosphine)nickel(II)chloride
14264-16-5
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mojin Biotechnology Co., Ltd | |
 |
2023-04-17 | Bis(triphenylphosphine)nickel(II)chloride
14264-16-5
|
US $200.00 / KG | 1KG | 99% | 500t | Shanghai Yunao International Trade Co., Ltd | |
 |
2022-09-24 | Bis(triphenylphosphine)nickel(II)chloride
14264-16-5
|
US $0.00 / kg | 1kg | 99% | 1000kg | henan kanbei chemical co.,ltd |
-
- Bis(triphenylphosphine)nickel(II)chloride
14264-16-5
- US $0.00 / KG
- 99%
- Hebei Mojin Biotechnology Co., Ltd
-
- Bis(triphenylphosphine)nickel(II)chloride
14264-16-5
- US $200.00 / KG
- 99%
- Shanghai Yunao International Trade Co., Ltd
-
- Bis(triphenylphosphine)nickel(II)chloride
14264-16-5
- US $0.00 / kg
- 99%
- henan kanbei chemical co.,ltd
14264-16-5(Bis(triphenylphosphine)nickel(II)chloride)Related Search:
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Choline chloride
1of4
Dichlorobis(triphenyIphosphine)-nickel
tributyl-phosphin compd. with nickelchloride
Nickel(II) chloride bis(triphenylphosphine)
Dichlorobis(triphenylphosphine)nickel(II), Nickel(II)bis(triphenylphosphine) dichloride
Phosphine, tributyl-, compound with nickel chloride (2:1)
Dichlorobis(triphenylphosphine)nickel(Ⅱ)
Dichlorobis(triphenylphosphine)nickel(II), 98+%
Dichlorobis(triphehylphosphine)nickel(II) ,98%
Bis(triphenylphosphine)nickel(II)chloride, 98% 10GR
Bis(triphenylphosphine)nickel(II) chloride,98% (PPh3)2NiCl2
NSC 137147
BIS(TRIPHENYLPHOSPHINE)NICKEL(II) CHLORI
Bis (triphenylphosphine) nickel chloride
Bis(triphenylphosphine)nickel(II) dichloride 99.99% trace metals basis
Bis(triphenylphosphine)nickel(II) dichloride synthesis grade
Bis(triphenylphosphine)nickel(II)chloride,(PPh3)2NiCl2
NICKEL(II)-BIS(TRIPHENYLPHOSPHINE) DICHLORIDE
NICKEL BIS(TRIPHENYLPHOSPHINE)DICHLORIDE
DICHLOROBIS(TRIPHENYLPHOSPHINE)NICKEL
BIS(TRIPHENYLPHOSPHINO)NICKEL(II) CHLORIDE
BIS(TRIPHENYLPHOSPHINE)NICKEL(2) DICHLORIDE
Bis(tri-N-butylphosphine)dichloronickel
bis(triphenylphosphine)dichloro-nicke
Bis(triphenylphosphine)dichloronickel
Dichlorobis(triphenyIphosphine)-nickel(II)
dichlorobis(triphenylphosphine)-nicke
Nickel, bis(triphenylphosphine)dichloro-
Nickel, dichlorobis(triphenylphosphine)-
Phosphine, tributyl-, compd. with nickelchloride (2:1)
bis(triphenylphosphine)nickle(II)
Bis-(triphenylphosphino)-nickel chloride
tributyl-phosphincompd.withnickelchloride(2:1)
Bis(triphenylphosphine)nickel(II) chloride for synthesis
TRIPHENYLPHOSPHINE NICKEL (II) CHLORIDE
Bis(triphenylphosphine)nickel(II) chloride, 98+%
Bis(triphenylphosphine)dichloronickel(II)~Dichlorobis(triphenylphosphine)nickel(II)
Bis(triphenylphosphine)nickel(II)chloride,99%
Dichloro bis (Triphenyl phosphine) Nickel catalyst
Bis(triphenylphosphine)nick
Bis(triphenylphosphine)nickel(II)chloride,NiCl2(PPh3)2
Dichlorobis(triphenylphosphine)nickel(II), 98%, for synthesis
Bis(triphenylphosphine)nickel(II) Dichloride >
(II) dichL
phosphine)nickeL
Bis(triphenylphosphine)nickel(II)chloride ISO 9001：2015 REACH
NiCl2(PPh3)2
DICHLOROBIS(TRIPHENYLPHOSPHINE)NICKEL(II)
BIS(TRIPHENYLPHOSPHINE)NICKEL(II) CHLORIDE
BIS(TRIPHENYLPHOSPHINE)NICKEL(II) DICHLORIDE
Bis(triphenylphosphine)nickel dichloride
Bis(triphenylphosphin)nickel(II)chlorid
dichloronickel triphenylphosphane
is(triphenylphosphine)nickel(II)chloride
(PPh3)2NiCl2
NICKEL(2+) ION BIS(TRIPHENYLPHOSPHINE) DICHLORIDE
Bis(Triphenylphosphoranyl)nickel(iv) chloride
14264-16-5
14262-16-5