Diethyl acetylenedicarboxylate
- CAS No.
- 762-21-0
- Chemical Name:
- Diethyl acetylenedicarboxylate
- Synonyms
- Diethyl but-2-ynedioate;DIETHYL BUTYNEDIOATE;Diethyl 2-butynedioate;YL2-BUTYNEDIOATE;Diethyl butyrate;Diethyl acetylenedic;diethylbut-2-indioat;Bis(carboethoxy)acetylene;Diethyl but-2-yne-1,4-dioate;Bis-(Ethoxycarbonyl)acetylene
- CBNumber:
- CB8456726
- Molecular Formula:
- C8H10O4
- Molecular Weight:
- 170.16
- MDL Number:
- MFCD00009186
- MOL File:
- 762-21-0.mol
- MSDS File:
- SDS
Melting point | 1-3 °C |
---|---|
Boiling point | 107-110 °C11 mm Hg(lit.) |
Density | 1.063 g/mL at 25 °C(lit.) |
refractive index |
n |
Flash point | 202 °F |
storage temp. | 2-8°C |
form | Liquid |
Specific Gravity | 1.063 |
color | Clear light yellow |
Water Solubility | Soluble in ethanol, ethyl ether, CCl4, Insoluble in water. |
BRN | 743166 |
CAS DataBase Reference | 762-21-0(CAS DataBase Reference) |
NIST Chemistry Reference | Diethylacetylene dicarboxylate(762-21-0) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS05 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H314 | |||||||||
Precautionary statements | P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363-P405 | |||||||||
Hazard Codes | C | |||||||||
Risk Statements | 34 | |||||||||
Safety Statements | 26-36/37/39-45-25 | |||||||||
RIDADR | UN 3265 8/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
F | 8-10 | |||||||||
HazardClass | 8 | |||||||||
PackingGroup | III | |||||||||
HS Code | 29171990 | |||||||||
NFPA 704 |
|
Diethyl acetylenedicarboxylate price More Price(31)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 159441 | Diethyl acetylenedicarboxylate 95% | 762-21-0 | 5g | $49.3 | 2024-03-01 | Buy |
Sigma-Aldrich | 159441 | Diethyl acetylenedicarboxylate 95% | 762-21-0 | 25g | $151 | 2024-03-01 | Buy |
TCI Chemical | A0089 | Diethyl Acetylenedicarboxylate >96.0%(GC) | 762-21-0 | 25mL | $98 | 2024-03-01 | Buy |
TCI Chemical | A0089 | Diethyl Acetylenedicarboxylate >96.0%(GC) | 762-21-0 | 250mL | $734 | 2024-03-01 | Buy |
Alfa Aesar | A11719 | Diethyl acetylenedicarboxylate, 96% | 762-21-0 | 25g | $66.65 | 2024-03-01 | Buy |
Diethyl acetylenedicarboxylate Chemical Properties,Uses,Production
Chemical Properties
Diethyl acetylenedicarboxylate is a clear light yellow liquid which has a disagreeable smell. It is a cheap and readily available material in industry. The triple bond is a critical and useful functional group, and it has extensive applications in organic synthesis. It can react with amines, aldehydes, ketones, etc. Therefore it can be used to form various heterocycles.
Synthesis of diethyl acetylenedicarboxylate
Uses
Diethyl acetylenedicarboxylate was used in the synthesis of:
- 3,4,5-trisubstituted 2(5H)-furanone derivatives
- highly functionalized thiazolidinone derivatives
- novel cyclic peroxide glucosides
- 4,11-dimesitylbisanthene, soluble bisanthene derivative, via Diels-Alder reaction
Uses
Diethyl acetylenedicarboxylate is used as a protein cross-linker. It is also used in the synthesis of 3,4,5-trisubstituted 2(5H)-furanone derivatives, highly functionalized thiazolidinone derivatives, novel cyclic peroxide glucosides and 4,11-dimesitylbisanthene, soluble bisanthene derivative, via Diels-Alder reaction.
General Description
Diethyl acetylenedicarboxylate is a protein cross-linker.
Purification Methods
Dissolve the ester in *C6H6, wash it with NaHCO3, H2O, dry over Na2SO4, filter, evaporate and distil it in a vacuum [IR: Walton & Hughes J Am Chem Soc 79 3985 1957, Truce & Kruse J Am Chem Soc 81 5372 1959]. [Beilstein 2 H 803.]
Diethyl acetylenedicarboxylate Preparation Products And Raw materials
Raw materials
Preparation Products
1of2
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Hebei Weibang Biotechnology Co., Ltd | +8615531157085 | abby@weibangbio.com | China | 8812 | 58 |
Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12840 | 58 |
Hebei Kingfiner Technology Development Co.Ltd | +86-15532196582 +86-15373005021 | lisa@kingfinertech.com | China | 3010 | 58 |
Capot Chemical Co.,Ltd. | +86-(0)57185586718 +86-13336195806 | sales@capot.com | China | 29791 | 60 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21634 | 55 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +8618949832763 | info@tnjchem.com | China | 2986 | 55 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29884 | 58 |
SHANDONG ZHI SHANG CHEMICAL CO.LTD | +86 18953170293 | sales@sdzschem.com | China | 2930 | 58 |
Changzhou Ansciep Chemical Co., Ltd. | +86 519 86305871 | sales@ansciepchem.com | CHINA | 4241 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39894 | 58 |
View Lastest Price from Diethyl acetylenedicarboxylate manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-11-20 | Diethyl acetylenedicarboxylate
762-21-0
|
US $1.00 / kg | 1kg | 99% | 10 mt | Hebei Weibang Biotechnology Co., Ltd | ||
2024-06-18 | Diethyl acetylenedicarboxylate
762-21-0
|
US $0.00-0.00 / kg | 1kg | 0.99 | 50000kg | Hebei Kingfiner Technology Development Co.Ltd | ||
2023-09-01 | Diethyl acetylenedicarboxylate
762-21-0
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mojin Biotechnology Co., Ltd |
- Diethyl acetylenedicarboxylate
762-21-0
- US $1.00 / kg
- 99%
- Hebei Weibang Biotechnology Co., Ltd
- Diethyl acetylenedicarboxylate
762-21-0
- US $0.00-0.00 / kg
- 0.99
- Hebei Kingfiner Technology Development Co.Ltd
- Diethyl acetylenedicarboxylate
762-21-0
- US $0.00 / KG
- 99%
- Hebei Mojin Biotechnology Co., Ltd