ChemicalBook >> CAS DataBase List >>Dicarbonylacetylacetonato rhodium(I)
Dicarbonylacetylacetonato rhodium(I)
- CAS No.
- 14874-82-9
- Chemical Name:
- Dicarbonylacetylacetonato rhodium(I)
- Synonyms
- Dicarbonylacetylacet;acetonato)dicarbonyL;Rhodium (Acac)Carbonyl - CARAC;Dicarbonylacetylacetonatorhodium;Acetylacetonatodicarbonylrhodium;Rhodium dicarbonylacetylacetonate;Dicarbonylrhodium acetylacetonate;Acetylacetonatorhodium dicarbonyl;Rhodium bis(carbonyl)acetyl acetone;Dicarbonyl-(2,4-pentandione)-rhodium
- CBNumber:
- CB8698018
- Molecular Formula:
- C7H7O4Rh
- Molecular Weight:
- 258.03
- MDL Number:
- MFCD00009884
- MOL File:
- 14874-82-9.mol
- MSDS File:
- SDS
Last updated:2023-04-23 13:52:06
| Melting point | 154-156 °C (lit.) |
|---|---|
| Density | 1.96[at 20℃] |
| vapor pressure | 0.13Pa at 25℃ |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Soluble in acetone |
| form | Needles or Flakes |
| color | Greenish-red |
| Water Solubility | insoluble |
| Exposure limits |
ACGIH: TWA 1 mg/m3 NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3 |
| LogP | 0.4 at 20℃ |
| FDA UNII | H77Y3D36FX |
| NIST Chemistry Reference | Rhodium, dicarbonyl(2,4-pentanedionato-o,o')-, (sp-4-2)-(14874-82-9) |
| EPA Substance Registry System | Rhodium, dicarbonyl(2,4-pentanedionato-.kappa.O2,.kappa.O4)-, (SP-4-2)- (14874-82-9) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS02,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H228-H317-H319 | |||||||||
| Precautionary statements | P210-P240-P241-P280-P302+P352-P305+P351+P338 | |||||||||
| Hazard Codes | Xi,F,T | |||||||||
| Risk Statements | 36/37/38-44-43-25 | |||||||||
| Safety Statements | 26-37/39-45-36/37/39-24/25 | |||||||||
| RIDADR | 3282 | |||||||||
| WGK Germany | 3 | |||||||||
| TSCA | No | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 28439000 | |||||||||
| NFPA 704 |
|
Dicarbonylacetylacetonato rhodium(I) price More Price(33)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 683183 | (Acetylacetonato)dicarbonylrhodium(I) 98% | 14874-82-9 | 2g | $1180 | 2024-03-01 | Buy |
| Sigma-Aldrich | 288101 | (Acetylacetonato)dicarbonylrhodium(I) 98% | 14874-82-9 | 1g | $597 | 2024-03-01 | Buy |
| Alfa Aesar | 039295 | Dicarbonyl(2,4-pentanedionato)rhodium(I), 99% | 14874-82-9 | 250mg | $234 | 2023-06-20 | Buy |
| Alfa Aesar | 039295 | Dicarbonyl(2,4-pentanedionato)rhodium(I), 99% | 14874-82-9 | 1g | $919 | 2023-06-20 | Buy |
| Strem Chemicals | 45-0700 | Dicarbonylacetylacetonato rhodium(I), 99% | 14874-82-9 | 250mg | $215 | 2024-03-01 | Buy |
Dicarbonylacetylacetonato rhodium(I) Chemical Properties,Uses,Production
Reaction
- Precatalyst for hydroformylation of olefins.
- Precatalyst for silylformylation of olefins.
- Precatalyst for carbonylative silylcarbo-cyclization in the syntheses of isodomoic acids.
- Precatalyst for the conjugate addition of aryl- and alkenylboronic acids to enones.
Chemical Properties
Red/Green Crystalline Powder
Uses
Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis
Catalyst for various carbonylation reactions, silylcarbocyclizations,conjugate additions to enones, carbamoylstannation,and reduction of aromatic nitro compounds
Uses
Employed in in situ formation of a fluorous-soluble hydroformylation catalyst of interest in molecular engineering.
Uses
(Acetylacetonato)dicarbonylrhodium(I) is used in in situ formation of a floors-soluble hydroformylation catalyst of interest in molecular engineering. It is also used as a catalyst for various carbonylation reactions, silylcarbocyclizations, conjugate additions to eons, carbamoylstannation, and reduction of aromatic nitro compounds. It is also used in Hydroformylation reaction.
Flammability and Explosibility
Flammable
Dicarbonylacetylacetonato rhodium(I) Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 197)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18774 | 58 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32957 | 60 |
| AB PharmaTech,LLC | 323-480-4688 | sales@acrospharmatech.com | United States | 989 | 55 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29881 | 58 |
| Accela ChemBio Inc. | +1-858-6993322 | info@accelachem.com | United States | 17453 | 58 |
| Xi'an Kono chem co., Ltd., | 029-86107037 13289246953 | info@konochemical.com | China | 2993 | 58 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22963 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39894 | 58 |
| Antai Fine Chemical Technology Co.,Limited | 18503026267 | info@antaichem.com | CHINA | 9636 | 58 |
| SHANGHAI T&W PHARMACEUTICAL CO., LTD. | +86-021-61551413 +8618813727289 | contact@trustwe.com | China | 5738 | 58 |
View Lastest Price from Dicarbonylacetylacetonato rhodium(I) manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2021-07-02 | Dicarbonylacetylacetonato rhodium(I)
14874-82-9
|
US $15.00-10.00 / KG | 1KG | 99%+ HPLC | Monthly supply of 1 ton | Zhuozhou Wenxi import and Export Co., Ltd | |
 |
2019-07-06 | Dicarbonylacetylacetonato rhodium(I)
14874-82-9
|
US $1.00 / KG | 1KG | 99% | 200kg | Career Henan Chemical Co |
-
- Dicarbonylacetylacetonato rhodium(I)
14874-82-9
- US $15.00-10.00 / KG
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
-
- Dicarbonylacetylacetonato rhodium(I)
14874-82-9
- US $1.00 / KG
- 99%
- Career Henan Chemical Co
14874-82-9(Dicarbonylacetylacetonato rhodium(I))Related Search:
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1of4
DICARBONYLACETYLACETONATO RHODIUM(I)
DICARBONYLRHODIUM(I) 2,4-PENTANEDIONATE
Acetylacetonatorhodium(I) dicarbonyl~Dicarbonyl(2,4-pentanedionato)rhodium(I)
Dicarbonyl-(2,4-pentandione)-rhodium
Dicarbonyl(2,4-pentanedionato)rhodium
Dicarbonylacetylacetonatorhodium
Dicarbonylrhodium acetylacetonate
Rhodium dicarbonylacetylacetonate
Rhodium, dicarbonyl(2,4-pentanedionato)-
Rhodium, dicarbonyl(2,4-pentanedionato-O,O')-
RHODIUM I DICARBONYL 2,4-PENTANEDIONATE
RHODIUM(I) DICARBONYL ACETYLACETONATE
RHODIUM DICARBONYL-2,4-PENTANEDIONATE
(ACETYLACETONATO)DICARBONYLRHODIUM(I)
dicarbonyl(pentane-2,4-dionato-O,O')rhodium
Dicarbonylacetylacet
Acetylacetonatodicarbonylrhodium
Acetylacetonatorhodium dicarbonyl
Dicarbonylacetylacetonato rhodiuM(I),98%
(Acetylacetonato)dicarbonylrhodium(Ⅰ)
(Acetylacetonato)dicarbonylrhodiuM(Ⅰ), 40% Rh, Product of UMicore
(Acetylacetonate group) two carbon-based iridiuM (I)
Dicarbonylacetylacetonatorhodium(I),99%
dicarbonyl-2,4-pentanedionatorhodium(i)
(ACETYLACETONATO)DICARBONYLRHODIUM(I), 9 8%
2,4-Pentanedionatodicarbonyl rhodium
(Actylacetatonato) dicarbonylrhodium (I)
(Acetylacetonato)dicarbonylrhodium (I), min. 99% (Rh-50, #209050)
Dicarbonyl-acetylacetonato-rhodium(I), Dicarbonylrhodium(I) 2,4-pentanedionate, Rhodium(I) dicarbonyl acetylacetonate
Dicarbonylrhodium(I) 2,4-pentanedionate, Rhodium(I) dicarbonyl acetylacetonate
Acetylacetonatodicarbonylrhodium(I) Dichroic green-red crystals sublm. 144-147
(Acetylacetonato)dicarbonylrhodium(I), 40% Rh, Product of Umicore
acetonato)dicarbonyL
(Acetylacetonato)dicarbonylrhodium(I) “CARAC”
Dicarbonylacetylacetonato rhodium(I) ISO 9001：2015 REACH
Rhodium (Acac)Carbonyl - CARAC
Rhodium bis(carbonyl)acetyl acetone
14874-82-9
C7H7RhO4
C7H7O4Rh
RhC5H7O2CO2
RhCO2C5H7O2
RhCO2acac
C7H11O4Rh
Catalysis and Inorganic Chemistry
Rh
metal carbonyl complexes
chemical reaction,pharm,electronic,materials